CH3Br, )“New” C atomic lines 2)Summary of C atomic line observations and “nonobservations” agust,heima,....Dec09/CH3BR-Overall (C) km agust,www,...Dec09/PPT aak.ppt agust,heima,...Dec09/XLS ak.xls

New 3 peaks New ?? artifact ATH?

Configuration Term J Level (cm -1 ) 2s22p2 2s22p2 3 P s22p2 2s22p2 1 D s22p2 2s22p2 1 S s2p3 2s2p3 5 S° s 2 2p( 2 P°)3s 3 P° s 2 2p( 2 P°)3s 1 P° s2p3 2s2p3 3 D° s 2 2p( 2 P°)3p 1 P s 2 2p( 2 P°)3p 3 D s 2 2p( 2 P°)3p 3 S s 2 2p( 2 P°)3p 3 P s 2 2p( 2 P°)3p 1 D s 2 2p( 2 P°)3p 1 S J GS0 0 3P s22p(2Po)3p P agust,heima,...Dec09/XLS ak.xls: :

Check / To be copaierd with lines in PPT ak.ppt:

Configurati on Term J Level (cm -1 ) 2s22p2 2s22p2 3 P s22p2 2s22p2 1 D s22p2 2s22p2 1 S s2p3 2s2p3 5 S° s 2 2p( 2 P°)3 s 3 P° s 2 2p( 2 P°)3 s 1 P° s2p3 2s2p3 3 D° s 2 2p( 2 P°)3 p 1 P s 2 2p( 2 P°)3 p 3 D s 2 2p( 2 P°)3 p 3 S s 2 2p( 2 P°)3 p 3 P C I D REMPI for C + Measurements seem to have got lost Exp. Values:

~ J’’=2 ->-> J´= ~ ; J’’= 1 ->-> J´= ~ ; J’’=0 ->-> J´=0 Ergo: The lines are: 2s22p2 (3P) ->-> 2s22p(2P°)3p(3P),  J =0:

Does not seem to be C atomic line. (see: agust,heima,...Dec09/XLS ak.xls ) Could this be Br atomic line? NO, not according to....PPT aak.ppt

Now lets check C atomic lines for 2p 2 ->-> np transitions 1) 3 P ->> 3 X 2) 1 D ->-> 1 X :

Configuration Term J Level (cm -1 ) 2s22p2 2s22p2 3 P s22p2 2s22p2 1 D s22p2 2s22p2 1 S s2p3 2s2p3 5 S° s 2 2p( 2 P°)3s 3 P° s 2 2p( 2 P°)3s 1 P° s2p3 2s2p3 3 D° s 2 2p( 2 P°)3p 1 P s 2 2p( 2 P°)3p 3 D s 2 2p( 2 P°)3p 3 S s 2 2p( 2 P°)3p 3 P s 2 2p( 2 P°)3p 1 D s 2 2p( 2 P°)3p 1 S s2p3 2s2p3 3 P° s 2 2p( 2 P°)3d 1 D° s 2 2p( 2 P°)4s 3 P° s 2 2p( 2 P°)3d 3 F° s 2 2p( 2 P°)3d 3 D° s 2 2p( 2 P°)4s 1 P° s 2 2p( 2 P°)3d 1 F° s 2 2p( 2 P°)3d 1 P° s 2 2p( 2 P°)3d 3 P° s 2 2p( 2 P°)4p 1 P s 2 2p( 2 P°)4p 3 D Observed New (101209) Not observed observed Not observed(?) Not observed limit

2s 2 2p( 2 P°)4p 3 S s 2 2p( 2 P°)4p 3 P s 2 2p( 2 P°)4p 1 D s 2 2p( 2 P°)4p 1 S s 2 2p( 2 P°)4d 1 D° s 2 2p( 2 P°)5s 3 P° s 2 2p( 2 P°)4d 3 F° s 2 2p( 2 P°)4d 3 D° s 2 2p( 2 P°)5s 1 P° s 2 2p( 2 P° 1/2 )4f 2 [ 5 / 2 ] s 2 2p( 2 P° 1/2 )4f 2 [ 7 / 2 ] s 2 2p( 2 P°)4d 1 F° s 2 2p( 2 P° 3/2 )4f 2 [ 7 / 2 ] s 2 2p( 2 P° 3/2 )4f 2 [ 5 / 2 ] s 2 2p( 2 P° 3/2 )4f 2 [ 9 / 2 ] s 2 2p( 2 P°)4d 1 P° s 2 2p( 2 P° 3/2 )4f 2 [ 3 / 2 ] s 2 2p( 2 P°)4d 3 P° s 2 2p( 2 P°)5p 1 P s 2 2p( 2 P°)5p 3 D s 2 2p( 2 P°)5p 3 P s 2 2p( 2 P°)5p 1 D s 2 2p( 2 P°)5p 1 S s 2 2p( 2 P°)5d 1 D° s 2 2p( 2 P°)5d 3 F° s 2 2p( 2 P°)6s 3 P° s 2 2p( 2 P°)5d 3 D° s 2 2p( 2 P°)6s 1 P° s 2 2p( 2 P°)5d 1 F° Not observed observed Weak but Observable See below 1)

2s 2 2p( 2 P° 3/2 )5f 2 [ 7 / 2 ] s 2 2p( 2 P° 3/2 )5f 2 [ 5 / 2 ] s 2 2p( 2 P°)5d 1 P° s 2 2p( 2 P° 3/2 )5f 2 [ 3 / 2 ] s 2 2p( 2 P°)5d 3 P° s 2 2p( 2 P°)6p 1 P s 2 2p( 2 P°)6p 3 D s 2 2p( 2 P°)6p 3 P s 2 2p( 2 P°)6p 1 D s 2 2p( 2 P°)6p 1 S s 2 2p( 2 P°)6d 1 D° s 2 2p( 2 P°)6d 3 F° s 2 2p( 2 P°)7s 3 P° s 2 2p( 2 P°)6d 3 D° s 2 2p( 2 P° 1/2 )6f 2 [ 7 / 2 ] s 2 2p( 2 P°)7s 1 P° s 2 2p( 2 P°)6d 1 F° s 2 2p( 2 P° 3/2 )6f 2 [ 5 / 2 ] s 2 2p( 2 P°)6d 1 P° s 2 2p( 2 P°)6d 3 P° [ ] [] 2s 2 2p( 2 P° 3/2 )6f 2 [ 3 / 2 ] s 2 2p( 2 P°)7p 1 P s 2 2p( 2 P°)7p 3 D s 2 2p( 2 P°)7p 3 P s 2 2p( 2 P°)7p 1 D s 2 2p( 2 P°)7p 1 S s 2 2p( 2 P°)7d 1 D° Not observed observed Not observed

2s 2 2p( 2 P°)7d 3 F° 2 [ ] [] 3 [ ] [] 4 [ ] [] 2s 2 2p( 2 P°)8s 3 P° s 2 2p( 2 P°)7d 3 D° 1 [ ] [] [ ] [] 2s 2 2p( 2 P° 1/2 )7f 2 [ 5 / 2 ] s 2 2p( 2 P°)8s 1 P° s 2 2p( 2 P°)7d 1 F° s 2 2p( 2 P° 3/2 )7f 2 [ 7 / 2 ] s 2 2p( 2 P°)7d 3 P° 2 [ ] [] 1 [ ] [] 0 [ ] [] 2s 2 2p( 2 P° 3/2 )7f 2 [ 5 / 2 ] s 2 2p( 2 P°)7d 1 P° s 2 2p( 2 P° 3/2 )7f 2 [ 3 / 2 ] s 2 2p( 2 P°)8p 1 P s 2 2p( 2 P°)8p 3 D [ ] [] s 2 2p( 2 P°)8p 3 P s 2 2p( 2 P°)8p 1 D s 2 2p( 2 P°)8p 1 S s 2 2p( 2 P°)8d 1 D° s 2 2p( 2 P°)8d 3 F° 2 [ ] [] 3 [ ] [] 4 [ ] [] 2s 2 2p( 2 P°)9s 3 P° s 2 2p( 2 P°)8d 3 D° 1 [ ] [] [ ] [] 2s 2 2p( 2 P° 1/2 )8f 2 [ 5 / 2 ] s 2 2p( 2 P°)9s 1 P° s 2 2p( 2 P°)8d 1 F° s 2 2p( 2 P° 3/2 )8f 2 [ 7 / 2 ] s 2 2p( 2 P°)8d 3 P° 0 [ ] [] 1 [ ] [] 2 [ ] [] 2s 2 2p( 2 P°)8d 1 P° s 2 2p( 2 P°)9p 1 P s 2 2p( 2 P°)9p 3 D s 2 2p( 2 P°)9p 1 D s 2 2p( 2 P°)9p 1 S : Not observed 91193:limit

(obs.) vs (predicted) (obs.) vs (predicted) 1)

Agust,heima,...Dec09/AFSTODUMYND hrh ak.pxp

/2 3 P-> 3 D J´´=0 ->>J´=1 H 2 + C( 3 P) +HBr /2 3 P-> 3 D J’´=0 ->>J´= H 2 + C*( 1 D) +HBr H 2 + C**( 3 D) +HBr H 2 + C**( 3 P) +HBr (H 2 + C**(4p, 1 D) +HBr) (H 2 + C**(4p, 1 S) +HBr) H 2 + C**(5p, 1 D) +HBr H 2 + C**(5p, 1 S) +HBr H 2 + C**(6p, 1 D) +HBr H 2 + C**(6p, 1 S) +HBragust,heima,...Dec09/AFSTODUMYND hrh ak.pxp

/2 3 P-> 3 P J’´=0 ->>J´=0 H 2 + C +HBr /2 3 P-> 3 P J’´=0 ->>J´=0 H 2 + C*(1D) +HBr H 2 + C**( 3 D) +HBr H 2 + C**( 3 P) +HBr (H 2 + C**(4p, 1 D) +HBr) (H 2 + C**(4p, 1 S) +HBr) H 2 + C**(5p, 1 D) +HBr H 2 + C**(5p, 1 S) +HBr H 2 + C**(6p, 1 D) +HBr H 2 + C**(6p, 1 S) +HBragust,heima,...Dec09/AFSTODUMYND hrh ak.pxp

/2 1 D->->4p, 1 D H 2 + C +HBr H 2 + C*( 1 D) +HBr /2 1 D->->4p, 1 D Very week H 2 + C**( 3 D) +HBr H 2 + C**( 3 P) +HBr (H 2 + C**(4p, 1 D) +HBr) (H 2 + C**(4p, 1 S) +HBr) H 2 + C**(5p, 1 D) +HBr H 2 + C**(5p, 1 S) +HBr H 2 + C**(6p, 1 D) +HBr H 2 + C**(6p, 1 S) +HBragust,heima,...Dec09/AFSTODUMYND hrh ak.pxp

/2 1 D->->5p, 1 D H 2 + C +HBr H 2 + C*( 1 D) +HBr /2 1 D->->5p, 1 D H 2 + C**( 3 D) +HBr H 2 + C**( 3 P) +HBr (H 2 + C**(4p, 1 D) +HBr) (H 2 + C**(4p, 1 S) +HBr) H 2 + C**(5p, 1 D) +HBr H 2 + C**(5p, 1 S) +HBr H 2 + C**(6p, 1 D) +HBr H 2 + C**(6p, 1 S) +HBragust,heima,...Dec09/AFSTODUMYND hrh ak.pxp

/2 1 D->->6p, 1 D H 2 + C +HBr H 2 + C*( 1 D) +HBr /2 1 D->->6p, 1 D 7504 H 2 + C**( 3 D) +HBr H 2 + C**( 3 P) +HBr (H 2 + C**(4p, 1 D) +HBr) (H 2 + C**(4p, 1 S) +HBr) H 2 + C**(5p, 1 D) +HBr H 2 + C**(5p, 1 S) +HBr H 2 + C**(6p, 1 D) +HBr H 2 + C**(6p, 1 S) +HBragust,heima,...Dec09/AFSTODUMYND hrh ak.pxp