Lecture 3411/30/05. Vapor pressure vs. boiling point?

Slides:



Advertisements
Similar presentations
Latent & Sensible Heat To help you understand the refrigerant phases (changes) in a vapour compression system, let us first consider the basic properties.
Advertisements

Vapor Pressure 1atm = 760 mmHg = 101.3kPa B is a Gas B is Liquid Normal Boiling Point for B.
Phase Changes Matter can change from one form to another. As this occurs, energy also changes.
Section 12.4: Phase Changes
Clausius – Clapeyron Equation This equation is a relation between  H vap and pressure at a certain Temperature.
Water and Its Phase Changes Wednesday, February 20, 2008 Homework: Due Thursday Page 514, #9, 19, 21, 22, 23.
How is boiling point related to pressure? …it’s more than you think!
CHANGES OF STATE Design: Metro Color: Office 10.4.
The pressure exerted by evaporated liquid particles on the surface of the liquid is called:
Topic B Work, Calorimetry, and Conservation of Energy
Chapter 13: States of Matter Kinetic-Molecular Theory: Explains the motions and behavior of a gas. The theory has three components: 1. Particle Size: Gas.
Aim: How to measure energy absorbed during a phase change
1 Boyle’s Law (T and n constant) Charles’ Law (p and n constant) Combined Gas Law (n constant) Summary of Gas Laws p 1 ×V 1 = p 2 ×V 2.
Lecture 3211/21/05 2 seminars left. London Dispersion Forces: Induced dipole / Induced dipole Non-polar / non-polar interaction 0.05 – 40 KJ/mol.
Phase Changes Melting Vaporization Condensation Freezing Sublimation.
PHASE CHANGES Matter can change from one state to another. This is known as a Phase Change. All Phase Changes are Physical Changes… The Identity of the.
Barometer Vacuum Height of column in. (76 cm) Air pressure Mercury.
Chapter 4 States of Matter.
The Ideal Gas Law and Stoichiometry Chemistry 142 B Autumn Quarter, 2004 J. B. Callis, Instructor Lecture #14.
LATENT HEAT Changes in State. E NERGY AND S TATES OF M ATTER  The energy and organization of the particles in a sample of matter determine the physical.
FINAL EXAM Wednesday,December 11, at 10:15 a.m. – 12:15 p.m. in the IC building, Room 421.
The phase of a substance depends upon two parameters: Temperature Pressure Gives the particles more energy to overcome attractive forces. Raises the vapor.
Pressure and Gases. Pressure Force per unit area P = F/ A.
1 Partial Pressure Pressure of individual gases in a mixture.
Phase Changes (i.e., changes of state) -- energy changes required are related to IMFs -- melting, freezing, boiling (vaporization), condensation, sublimation,
Calculating Heat. Specific Heat Amount of heat energy needed to raise the temp of 1 ml of a substance 1°C For water the specific heat is 4.19 J/g °C,
Aim: How does pressure affect matter? Do Now: 1.Take out your reference tables and a calculator. 2.Look at Table H on your reference tables. If the pressure.
Chapter 10 - Review States of Matter Milbank High School.
1. 2 Characteristics of Gases Vapor – substance ordinarily a liquid or solid but in its gaseous phase Gas expands to fill its container Highly compressible.
1 Suppose that 1 gram (g) of Material A, initially a liquid, is kept in a cylinder fitted with a piston at a constant pressure of 1 atmosphere (atm).
Vapor Pressure and Boiling Vapor Pressure – the pressure exerted by a vapor in equilibrium with its liquid state. Vapor Pressure – the pressure exerted.
Chapter 12 Changes in Temperature and Phases. Goals Perform calculations with specific heat capacity. Interpret the various sections of a heating curve.
THERMOCHEMISTRY: HEAT and CHANGE. When a material is heated (or cooled), it can undergo one of these changes: Its temperature changes OR Its physical.
10.4  Phase – any part of a system with uniform composition and properties.  Condensation – gas changes to a liquid  Molecules of liquid can evaporate.
Water phase changes constant Temperature remains __________
Warmup: 3 minutes 1. List 3 reasons why this astronaut is wearing a space suit. What happens if his space suit is torn? 2. What is ‘volume’? The amount.
Heat Diagram of H2O.
Temp ( o C) Phase Change Diagram Practice Use the following graph of Temperature vs. Heat for 10 g of compound “X” to answer the questions: 500.
UNIT 5 THERMOCHEMISTRY 1 A study of the energy produced by Chemical Reactions Chemical Reactions.
Earth Science States of Matter. Four states of matter Solids Liquids Gases Plasma Kinetic energy determines which state an element or compound is in.
Properties of Liquids Kinetic-Molecular theory …The phase of any substance is determined by the inter and intramolecular forces present and the KE of the.
Evaporation and Vapor Pressure
Phase Changes.
Problems Dr. Kagan ERYURUK.
Thermochemical Calculations
Matter and Energy Chapter 12.4 Chapter
Heating and Cooling Curves
Solid, Liquid, and Gas Day 1. Curriculum Big Idea: Changes in matter are accompanied by changes in energy. Big Idea: Changes in matter are accompanied.
Energy and Phase Changes. Energy Requirements for State Changes To change the state of matter, energy must be added or removed.
B. Heating Curves Melting - PE  Solid - KE  Liquid - KE  Boiling - PE  Gas - KE 
Ch. 09: Liquids & Solids Vapor Pressure. Vapor = the gaseous state of a substance that has escaped from the liquid phase e.g., ½-filled cup of coffee:
Aim: What are the States of Matter. Nature of Gases Gases: ◦No definite shape or volume ◦Particles are very far apart and move all over ◦Total disorder-
Vapor Pressure. Evaporation u When fastest particles in a sample of liquid escape from the surface of the liquid u During evaporation the slower particles.
Gas Laws Review. A sample of carbon dioxide occupies a volume of 3.5 L at 125 kPa pressure. What pressure would the gas exert if the volume was lowered.
Phase Diagrams & Heating Curves
Vocabulary Set #1. Condensation the process of changing from a gas to a liquid.
1. 2 Partial Pressure Pressure of individual gases in a mixture.
Aim: How to measure energy absorbed during a phase change DO NOW: 1. A g piece of iron absorbs joules of heat energy, and its temperature.
Sections 11.1 – 11.3 Properties of Liquids. Properties of Liquids In these sections… a.Phases of Matter b.Phase Changes c.Properties of Liquids: 1.Enthalpy.
Chapter 23: Change of Phase Review and Study Guide.
The Properties of Gases Chapter 12. Properties of Gases (not in Notes) Gases are fluids… Fluid: (not just to describe liquids)  can describe substances.
Properties of Matter General (Physical) Properties  Physical properties may be observed without changing the nature of the matter.
Topics 5 and 15. Hess’s Law Calorimetry Enthalpy Enthalpy of Formation Bond Energy.
Tuesday, March 29th Take out your Intermolecular forces practice
Thermochemical Calculations
Phase Diagrams: Solid, Liquid & Gas Roadmaps
Lesson 3 LT: I can predict how temperature and pressure affect the volume of a gas.
Which type of intermolecular force is the strongest?
Section 5 Water Chapter 10 Ice and Water.
Boiling is a liquid-to-vapor phase change process just like evaporation, but there are significant differences between the two. Evaporation occurs at.
Presentation transcript:

Lecture 3411/30/05

Vapor pressure vs. boiling point?

1. What phase is xenon at room temperature? 2. If the pressure exerted on a sample of xenon is 0.75 atm and the temperature is -114 °C, in what phase does it exist? 3. If the vapor pressure of a sample of liquid xenon is 375 mm Hg, what is the temperature of the liquid phase? 4. What is the vapor pressure of solid xenon at -122 °C? 5. Which is the denser phase, solid or liquid?

11-88 Liquid ammonia, NH 3 (l) was used as a refrigerant fluid before the discovery of chlorofluorocarbons and is still widely used today. Its normal boiling point is °C, and its heat of vaporization is 23.5 kJ/mol. The gas and the liquid have specific heat capacities of 2.2 J/g-K and 4.7 J/g-K, respectively. How much heat must be supplied to 10.0 kg of liquid ammonia to raise its temperature from -50 °C to 0°C?

Given that the specific heat capacity of air is 1.0 × 10 3 J kg -1 K -1, calculate how much energy must be removed from a refrigerator containing 0.15 m 3 of air to lower the temperature of the air from 20 °C to 4 °C (assume density of air = 1.2 kg m -3 ).