1 “Programmed” Self-Assembly Hierarchical assembly- molecules to mammals.

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Presentation transcript:

1 “Programmed” Self-Assembly Hierarchical assembly- molecules to mammals

2 Routes to Nanoassembly Sean A. Davis, Michael Breulmann, Katja H. Rhodes, Baojian Zhang, and Stephen Mann “Template-Directed Assembly Using Nanoparticle Building Blocks: A Nanotectonic Approach to Organized Materials” Chem. Mater., 13 (10), , 2001.

3 Matrix Confinement Diatoms – natural matrix confinement assembly

4 Status Report on Hierarchical, “Programmed” Assembly Murali Sastry, Mala Rao, and Krishna N. Ganesh “Electrostatic Assembly of Nanoparticles and Biomacromolecules” Acc. Chem. Res., 35 (10), , 2002.

5 Programmed Assembly Chad A. Mirkin “Programming the Assembly of Two- and Three-Dimensional Architectures with DNA and Nanoscale Inorganic Building Blocks” Inorg. Chem., 39 (11), , 2000.

6 Programmed Assembly Chad A. Mirkin “Programming the Assembly of Two- and Three-Dimensional Architectures with DNA and Nanoscale Inorganic Building Blocks” Inorg. Chem., 39 (11), , 2000.

7 Programmed Assembly Alexander Kulak, Sean A. Davis, Erik Dujardin, and Stephen Mann “Controlled Assembly of Nanoparticle-Containing Gold and Silica Microspheres and Silica/Gold Nanocomposite Spheroids with Complex Form” Chem. Mater., 15 (2), , 2003.

8 Programmed Assembly Alexander Kulak, Sean A. Davis, Erik Dujardin, and Stephen Mann “Controlled Assembly of Nanoparticle-Containing Gold and Silica Microspheres and Silica/Gold Nanocomposite Spheroids with Complex Form” Chem. Mater., 15 (2), , 2003.

9 Programmed Assembly Alexander Kulak, Sean A. Davis, Erik Dujardin, and Stephen Mann “Controlled Assembly of Nanoparticle- Containing Gold and Silica Microspheres and Silica/Gold Nanocomposite Spheroids with Complex Form” Chem. Mater., 15 (2), , 2003.

10 Programmed Assembly Kensuke Naka, Hideaki Itoh, and Yoshiki Chujo “Temperature-Dependent Reversible Self- Assembly of Gold Nanoparticles into Spherical Aggregates by Molecular Recognition between Pyrenyl and Dinitrophenyl Units” Langmuir, 19 (13), , 2003.

11 Programmed Assembly Hannes Spillmann, Alexandre Dmitriev, Nian Lin, Paolo Messina, Johannes V. Barth, and Klaus Kern “Hierarchical Assembly of Two-Dimensional Homochiral Nanocavity Arrays” J. Am. Chem. Soc., 125 (35), , 2003.

12 Programmed Assembly Stephen Fullam, S. Nagaraja Rao, and Donald Fitzmaurice “Noncovalent Self-Assembly of Silver Nanocrystal Aggregates in Solution” J.Phys. Chem. B, 104 (26), , 2000.

13 Programmed Assembly Stephen Fullam, Hakan Rensmo, S. Nagaraja Rao, and Donald Fitzmaurice “Noncovalent Self-Assembly of Silver and Gold Nanocrystal Aggregates in Solution” Chem. Mater., 14 (9), , 2002.

14 “Programmed” Self-Assembly How do we get to these levels of complexity?