Infinite Square Well “Particle in a Box”: Hydrogen (like) Atom Bohr Model: eV Bohr radius: a 0 = 0.0529 nm Orbital angular momentum.

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Presentation transcript:

Infinite Square Well “Particle in a Box”: Hydrogen (like) Atom Bohr Model: eV Bohr radius: a 0 = nm Orbital angular momentum

Schroedinger Equation: Time Independent S. E. in 1D: T. I. S. E. in 3D: T. I. S. E. in spherical coordinates: See Eq Spherical Coordinates

ConcepTest #77

NameSymbolValuesCommentsPhysical Quantity Principal quantum number Relates to energy Orbital quantum number Relates to orbital angular momentum Magnetic quantum number Relates to z-component of orbital angular momentum Typo in eq ?

ConcepTest #78

Orbital angular momentum and z-component: Take case

ConcepTest #79

Transitions and Selection Rules: Some transitions are forbidden by radiative processes… Figure 36-7

Hydrogen Atom Wave Functions and Probability Densities ConcepTest #80

Radial Probability Densities Hydrogen Atom Probability

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