Reactions in Aqueous Solution Chapter 4 Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

2 A solution is a homogenous mixture of 2 or more substances The solute is(are) the substance(s) present in the smaller amount(s) The solvent is the substance present in the larger amount SolutionSolventSolute Soft drink (l) Air (g) Soft Solder (s) H2OH2O N2N2 Pb Sugar, CO 2 O 2, Ar, CH 4 Sn aqueous solutions of KMnO 4

3 An electrolyte is a substance that, when dissolved in water, results in a solution that can conduct electricity. A nonelectrolyte is a substance that, when dissolved, results in a solution that does not conduct electricity. nonelectrolyte weak electrolyte strong electrolyte

4 Strong Electrolyte – 100% dissociation NaCl (s) Na + (aq) + Cl - (aq) H2OH2O Weak Electrolyte – not completely dissociated CH 3 COOH CH 3 COO - (aq) + H + (aq) Conduct electricity in solution? Cations (+) and Anions (-)

5 Ionization of acetic acid CH 3 COOH CH 3 COO - (aq) + H + (aq) A reversible reaction. The reaction can occur in both directions. Acetic acid is a weak electrolyte because its ionization in water is incomplete.

6 Hydration is the process in which an ion is surrounded by water molecules arranged in a specific manner.   H2OH2O

7 Nonelectrolyte does not conduct electricity? No cations (+) and anions (-) in solution C 6 H 12 O 6 (s) C 6 H 12 O 6 (aq) H2OH2O

8 Precipitation Reactions Precipitate – insoluble solid that separates from solution molecular equation ionic equation net ionic equation Pb NO Na + + 2I - PbI 2 (s) + 2Na + + 2NO 3 - Na + and NO 3 - are spectator ions PbI 2 Pb(NO 3 ) 2 (aq) + 2NaI (aq) PbI 2 (s) + 2NaNO 3 (aq) precipitate Pb I - PbI 2 (s)

9 Precipitation of Lead Iodide PbI 2 Pb I - PbI 2 (s)

10 Solubility is the maximum amount of solute that will dissolve in a given quantity of solvent at a specific temperature.

11 Examples of Insoluble Compounds CdS PbSNi(OH) 2 Al(OH) 3

12 Writing Net Ionic Equations 1.Write the balanced molecular equation. 2.Write the ionic equation showing the strong electrolytes completely dissociated into cations and anions. 3.Cancel the spectator ions on both sides of the ionic equation 4.Check that charges and number of atoms are balanced in the net ionic equation AgNO 3 (aq) + NaCl (aq) AgCl (s) + NaNO 3 (aq) Ag + + NO Na + + Cl - AgCl (s) + Na + + NO 3 - Ag + + Cl - AgCl (s) Write the net ionic equation for the reaction of silver nitrate with sodium chloride.

13 Chemistry In Action: CO 2 (aq) CO 2 (g) Ca 2+ (aq) + 2HCO - 3 (aq) CaCO 3 (s) + CO 2 (aq) + H 2 O (l) - An Undesirable Precipitation Reaction