agust,www,...january09/PPT ak.ppt Model used on 1)“New system data” (g 3 + (1) <- X 1 + ) vs V,v´=9 2) f3D1 <-<-X vs Vv´=9 W 12 (W 12 ´) max based on shift analysis and from intensity ratio analysis
Compaired to before “New” Model: “Old” Model:
W12(6)5.48 DE36.5 DE DE-DE (DE-DE0)/ (DE-DE0)max2 W W12 ca6W12´*sqrt(J´*(J´+1)) W12´ J´=6W12´= W12/(sqrt(J´(J´+1))) J´6 Agust,heima,....january09/Term values for triplet paper kmak.xls g 3 + (1)
gamma alfa = beta=1 W12´=1 n0.5 shift, de0 f1 abs(35) exp calc agust,heima,....january09/Model calc ak.xls J´ I( 35 Cl + )/I(H 35 Cl + ) g 3 + (1)
agust,heima,....january09/Model calc ak.xls I( 35 Cl + )/I(H 35 Cl + ) J´ Exp.Calc. g 3 + (1)
agust,heima,....january09/Model calc ak.xls J´ 35Cl+/ H35Cl+ exp ratio calc- new Calc Delta E observed g 3 + (1)
(DE- DE0)max1 W W12 ca4W12´*sqrt(J´*(J´+1)) W12´ J´=6W12´= W12/(sqrt(J´(J´+1))) J´6 f31f31
agust,heima,....january09/Model calc ak.xls gamma alfa =0.51 beta=1 W12´=0.65 n0.5 shift, de0 f1 abs(35) f31f31 I( 35 Cl + )/I(H 35 Cl + ) J´ Exp.Calc.
agust,heima,....january09/Model calc ak.xls J´ 35Cl+/H3 5Cl+ exp Delta E observed ratio calc-new calc f31f31