Cave Chemistry. What cave formation needs: 1. Make a hole in the ground 2. Partially fill it with cool formations.

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Presentation transcript:

Cave Chemistry

What cave formation needs: 1. Make a hole in the ground 2. Partially fill it with cool formations

Cave Chemistry CaCO 3 (s)  Ca 2+ (aq) + CO 3 2- (aq) K sp (CaCO 3 ) = 4.8 x Calculate solubility in mg/L: Actual solubility: 80 mg/L Why???

Effect of [CO 2 ]. What should happen as [CO 2 ] increases? CaCO 3 (s)  Ca 2+ (aq) + CO 3 2- (aq) CO 2 + H 2 O  H 2 CO 3 H 2 CO 3  HCO H + Ka 1 (H 2 CO 3 ) = 4.2 x HCO 3 -  CO H + Ka 2 (HCO 3 - ) = 4.8 x

CaCO 3 (s)  Ca 2+ (aq) + CO 3 2- (aq) CO 2 + H 2 O  H 2 CO 3 H 2 CO 3  HCO H + Ka 1 (H 2 CO 3 ) = 4.2 x HCO 3 -  CO H + Ka 2 (HCO 3 - ) = 4.8 x The Key Reaction is:

So: 1. Formation of the big hole

So: 2. Making those formations