f3D2 energetics and interaction with V,v´=8 & f3D1 energetics and interaction with V,v´=9 Shifts of levels and peaks(?) agust,www,....january09/PPT ak.ppt

agust,heima,...january09/Term values for triplet paper kmak.xls f3D2, f / P,R state; i.e.  - (see ;2) J´(higher)

 E(e) f 3  2, e / O,Q,S state; i.e.  + (see ;2)  E(e))

f3D2,v´=0DE(f3D2) av. terms 82079, ,1565, ,2686, ,08106, ,63127, ,74148,1048 J´ agust, heima,...january09/Term values for triplet paper kmak.xls  E J´,J´-1 J´(higher) DE(DE) 20, , , ,55592

V1S+,v´= parities f3D2 (e) (f  + )(see ;2) To be expected:

 Hence observations are not according to expectations IF anything it seems to be the opposite effect, i.e. the gap between J´= 4 & 5 decreases instead of increses Large fluctuations in DE(DE) are observed suggesting that uncertainty is too large and That insignificant shifts of levels are endeed observed Let´s now see what shifts the W12 values obtained for f3D2 V,v´=8 interaction will correspond to

agust,heima,...january09/Term values for triplet paper kmak.xls f3D1, f / P,R state; i.e.  - (see ;2) J´(higher)

agust,heima,...january09/Term values for triplet paper kmak.xls f3D1, e / O,Q,S state; i.e.  + (see ;2) J´(higher)  E(e)  E(e))

f3D1,v´=1DE(f3D1) av. Terms: 82544, ,4841, ,2961, ,8482, ,47102, ,29124, ,74143,4541 J´ agust, heima,...january09/Term values for triplet paper kmak.xls  E J´,J´-1 J´(higher) DE(DE) 20, , , , ,6369

f3D1 (e) (f  + )(see ;2) V1S+,v´=9 6 6  E(e)  E(e)) To be expected: parities

 Hence observations are not according to expectations IF anything it seems to be the opposite effect, i.e. the gap between J´= 5 & 6 increases (see slide 8) instead of decreases Large fluctuations in DE(DE) are observed suggesting that uncertainty is too large and That insignificant shifts of levels are endeed observed NB: according to agust,heima,.... january09/Term values for triplet paper kmak.xls The same seems to hold for the “New State”, i.e. IF anything it seems to be the opposite effect, i.e. the gap between J´= 5 & 6 increases (see slide 12) instead of decreases g3S+(1) V,v´=9 See next pages: agust, heima,...january09/Term values for triplet paper kmak.xls

g3S+(1) (e) V1S+,v´=9 6 6  E(e)  E(e)) To be expected: parities

i.e. from D(DE) should be about 3.86 ~ 4 From above it looks as is the absolut maximum deviations of DE´s (i.e. D(DE)´s) are Something like: D(DE) f3D2: 0.5 f3D1 1 g3S+(1) 2 If i try using D(DE) = 0.5 I obtain: Now I go back to and calculate corresponding W12´: W12(5)5,48 DE17,48 DE013,61722 DE-DE03, (DE-DE0)/21, agust,heima,...january09/Term values for triplet paper kmak.xls Let´s now see what shifts the W12 values obtained for f3D2 V,v´=8 interaction will correspond to (DE-DE0)max0,5 W122, W12 ca2 agust,heima,...january09/Term values for triplet paper kmak.xls av. Terms DE(f3D2-V f3D2,v´=0abs(DE(f3D2-Vv´=8))from KMW12= C12=0.5+sqr t(DE**2 - 4*W12**2)/( 2*DE) 82225,8 v´=8) av. termsW12max 0.37*(J´(J´+1))1/ , ,75-164, ,9164,855582, ,90, , ,67-118, ,15118,526159, ,71, , ,14-57, ,2657, , ,71, , ,6117, ,0817,474268, ,12, , ,43107, ,63107,198253, ,49392, , alfa =4,232 beta=1 W12´=0,37 n0,5 shift, de0 f1 abs(35)0, agust,heima,...january09/f3D2&Vv ak:

Exp. Calc. J´ I( 35 Cl + )/I(H 35 Cl + ) Now let´s make a model including the Gateway mechanism.

Ry0Ry1 V t3S

Compaired to before