Symmetry Motif: the fundamental part of a symmetric design that, when repeated, creates the whole pattern Operation: some act that reproduces the.

Slides:



Advertisements
Similar presentations
Equivalent Positions in 3-D
Advertisements

Three-Dimensional Symmetry
1 We are now ready to move to the orthorhombic system. There are 59 orthorhombic space groups. Orthorhombic crystals belong to crystal classes 222, mm2.
1 We are now ready to move to the monoclinic system. There are 13 monoclinic space groups. Monoclinic crystals belong to crystal classes 2, m or 2/m. In.
Lesson 12—Working with Space Groups How to convert a space group to a point group Adding the translational elements Calculating the coordinates of the.
The 10 two-dimensional crystallographic point groups Interactive exercise Eugen Libowitzky Institute of Mineralogy and Crystallography 2012.
1 Watkins/Fronczek - Space Groups Translational + Rotational Symmetry Introduction to Space Groups.
Vocabulary:  Transformation – a one-to-one correspondence between two sets of points  Pre-image – the original figure  Image – figure after transformation.
Crystals and Symmetry. Why Is Symmetry Important? Identification of Materials Prediction of Atomic Structure Relation to Physical Properties –Optical.
Symmetry Elements II.
Symmetry Elements Lecture 5. Symmetry Motif: the fundamental part of a symmetric design that, when repeated, creates the whole pattern Operation: some.
Mineralogy Carleton College Winter Lattice and its properties Lattice: An imaginary 3-D framework, that can be referenced to a network of regularly.
IT’S TIME FOR... CRYSTALLOGRAPHY TRIVIA!!
Crystal Chem  Crystallography Chemistry behind minerals and how they are assembled –Bonding properties and ideas governing how atoms go together –Mineral.
CRYSTALLOGRAPHY TRIVIA FINAL ROUND!. Round 3 – Question 1 Twins are said to add another level of symmetry to a crystal. Why is this?
Lecture 8 (10/09/2006) Crystallography Part 1: Symmetry Operations
Crystallography Gypsum Monoclinic Dolomite Triclinic Emerald Hexagonal
Symmetry Translations (Lattices) A property at the atomic level, not of crystal shapes Symmetric translations involve repeat distances The origin is arbitrary.
Crystallography Motif: the fundamental part of a symmetric design that, when repeated, creates the whole pattern In 3-D, translation defines operations.
PH0101 UNIT 4 LECTURE 3 CRYSTAL SYMMETRY CENTRE OF SYMMETRY
3-D figures. Reflectional Symmetry For 2D figure: If a plane figure can be divided by a line into two identical parts and these parts are mirror images.
Elementary Crystallography for X-ray Diffraction
1 Excursions in Modern Mathematics Sixth Edition Peter Tannenbaum.
Symmetry Motif: the fundamental part of a symmetric design that, when repeated, creates the whole pattern Operation: some act that reproduces the.
Crystallography and Diffraction Theory and Modern Methods of Analysis Lectures 1-2 Introduction to Crystal Symmetry Dr. I. Abrahams Queen Mary University.
1 Internal Order and Symmetry GLY 4200 Fall, 2015.
Chem Lattices By definition, crystals are periodic in three dimensions and the X-ray diffraction experiment must be understood in the context of.
2D Symmetry (1.5 weeks). From previous lecture, we know that, in 2D, there are 3 basics symmetry elements: Translation,mirror (reflection),and rotation.
Symmetry Figures are identical upon an operation Reflection Mirror Line of symmetry.
CRYSTALLOGRAPHY.
Test 1: Tuesday October 6 (Chapters 1-6) One page of notes is strongly encouraged. Test questions will not be as hard as the homework from Ashcroft book.
Transformation in Geometry Transformation A transformation changes the position or size of a shape on a coordinate plane.
Lecture 12 Crystallography
Symmetry Two points, P and P ₁, are symmetric with respect to line l when they are the same distance from l, measured along a perpendicular line to l.
Crystallography ll.
Symmetry, Groups and Crystal Structures
ESO 214: Nature and Properties of Materials
EQ: How can I identify symmetry in figures? Do Now 1. Give the coordinates of triangle ABC with vertices (7, 2), (1, 2), (4, –5) reflected across the y-axis.
Key things to know to describe a crystal
Symmetry.
Point & Space Group Notations
Symmetry Rotation Translation Reflection. A line on which a figure can be folded so that both sides match.
1 Crystals possess different symmetry elements. The definite ordered arrangement of the faces and edges of a crystal is known as `crystal symmetry’. CRYSTAL.
المحاضرة 4 التركيب البلوري-التماثل
Crystal Structure and Crystallography of Materials
Symmetry. What Is Symmetry? Fundamental organizing principle in nature and art Preserves distances, angles, sizes and shapes.
Transformation in Geometry Transformation A transformation changes the position or size of a polygon on a coordinate plane.
Periodic patterns.
Internal Order and Symmetry
Internal Order and Symmetry
Point Groups Roya Majidi 1393.
SOLID STATE By: Dr.DEPINDER KAUR.
SOLID STATE By: Dr.Bhawna.
Miller indices/crystal forms/space groups
Crystal Structure and Crystallography of Materials
Symmetry Summary GLY 4200 Lab 5 - Fall, 2017.
Objectives • Written and graphic symbols of symmetry elements
Symmetry, Groups and Crystal Structures
Crystals Crystal consist of the periodic arrangement of building blocks Each building block, called a basis, is an atom, a molecule, or a group of atoms.
Symmetry, Groups and Crystal Structures
Symmetry Summary GLY 4200 Lab 5 - Fall, 2012.
Symmetry Elements II.
Symmetry “the correspondence in size, form and
Operations of the 1st kind. no change in handedness. rotation Cn
Internal Order and Symmetry
WARM-UP 8 in. Perimeter = _____ 7 in. Area = _____ 12 in. 4 cm
Create a design (image) on the graph paper on the last page, making sure at least 3 vertices land on whole number (integer) coordinates, in the upper left.
Crystal Chem  Crystallography
Symmetry Summary GLY 4200 Lab 5 - Fall, 2019.
Presentation transcript:

Symmetry Motif: the fundamental part of a symmetric design that, when repeated, creates the whole pattern Operation: some act that reproduces the motif to create the pattern Element: an operation located at a particular point in space

6 6 2-D Symmetry Symmetry Elements 1. Rotation a. Two-fold rotation = 360o/2 rotation to reproduce a motif in a symmetrical pattern A Symmetrical Pattern 6 6

6 6 2-D Symmetry Symmetry Elements 1. Rotation a. Two-fold rotation = 360o/2 rotation to reproduce a motif in a symmetrical pattern = the symbol for a two-fold rotation Operation 6 Motif Element 6

6 6 2-D Symmetry Symmetry Elements 1. Rotation a. Two-fold rotation = 360o/2 rotation to reproduce a motif in a symmetrical pattern = the symbol for a two-fold rotation 6 first operation step second operation step 6

2-D Symmetry Symmetry Elements 1. Rotation a. Two-fold rotation Some familiar objects have an intrinsic symmetry

2-D Symmetry Symmetry Elements 1. Rotation a. Two-fold rotation Some familiar objects have an intrinsic symmetry

2-D Symmetry Symmetry Elements 1. Rotation a. Two-fold rotation Some familiar objects have an intrinsic symmetry

2-D Symmetry Symmetry Elements 1. Rotation a. Two-fold rotation Some familiar objects have an intrinsic symmetry

2-D Symmetry Symmetry Elements 1. Rotation a. Two-fold rotation Some familiar objects have an intrinsic symmetry

2-D Symmetry Symmetry Elements 1. Rotation a. Two-fold rotation Some familiar objects have an intrinsic symmetry

2-D Symmetry Symmetry Elements 1. Rotation a. Two-fold rotation Some familiar objects have an intrinsic symmetry 180o rotation makes it coincident Second 180o brings the object back to its original position What’s the motif here??

6 6 6 2-D Symmetry Symmetry Elements 1. Rotation b. Three-fold rotation = 360o/3 rotation to reproduce a motif in a symmetrical pattern 6 6 6

6 6 6 2-D Symmetry Symmetry Elements 1. Rotation b. Three-fold rotation = 360o/3 rotation to reproduce a motif in a symmetrical pattern 6 step 1 6 step 3 6 step 2

Symmetry Elements 1. Rotation 2-D Symmetry Symmetry Elements 1. Rotation 6 6 6 6 6 1-fold 2-fold 3-fold 4-fold 6-fold Objects with symmetry: 9 d a Z t identity 5-fold and > 6-fold rotations will not work in combination with translations in crystals (as we shall see later). Thus we will exclude them now.

4-fold, 2-fold, and 3-fold rotations in a cube Click on image to run animation

6 6 2-D Symmetry Symmetry Elements 2. Inversion (i) inversion through a center to reproduce a motif in a symmetrical pattern = symbol for an inversion center inversion is identical to 2-fold rotation in 2-D, but is unique in 3-D (try it with your hands) 6 6

2-D Symmetry Symmetry Elements 3. Reflection (m) Reflection across a “mirror plane” reproduces a motif = symbol for a mirror plane

2-D Symmetry We now have 6 unique 2-D symmetry operations: 1 2 3 4 6 m Rotations are congruent operations reproductions are identical Inversion and reflection are enantiomorphic operations reproductions are “opposite-handed”

2-D Symmetry Combinations of symmetry elements are also possible To create a complete analysis of symmetry about a point in space, we must try all possible combinations of these symmetry elements In the interest of clarity and ease of illustration, we continue to consider only 2-D examples

Try combining a 2-fold rotation axis with a mirror 2-D Symmetry Try combining a 2-fold rotation axis with a mirror

2-D Symmetry Try combining a 2-fold rotation axis with a mirror Step 1: reflect (could do either step first)

2-D Symmetry Try combining a 2-fold rotation axis with a mirror Step 1: reflect Step 2: rotate (everything)

2-D Symmetry Try combining a 2-fold rotation axis with a mirror Step 1: reflect Step 2: rotate (everything) Is that all??

2-D Symmetry Try combining a 2-fold rotation axis with a mirror Step 1: reflect Step 2: rotate (everything) No! A second mirror is required

2-D Symmetry Try combining a 2-fold rotation axis with a mirror The result is Point Group 2mm “2mm” indicates 2 mirrors The mirrors are different (not equivalent by symmetry)

Now try combining a 4-fold rotation axis with a mirror 2-D Symmetry Now try combining a 4-fold rotation axis with a mirror

Now try combining a 4-fold rotation axis with a mirror Step 1: reflect 2-D Symmetry Now try combining a 4-fold rotation axis with a mirror Step 1: reflect

2-D Symmetry Now try combining a 4-fold rotation axis with a mirror Step 1: reflect Step 2: rotate 1

2-D Symmetry Now try combining a 4-fold rotation axis with a mirror Step 1: reflect Step 2: rotate 2

2-D Symmetry Now try combining a 4-fold rotation axis with a mirror Step 1: reflect Step 2: rotate 3

Now try combining a 4-fold rotation axis with a mirror 2-D Symmetry Now try combining a 4-fold rotation axis with a mirror Any other elements?

Now try combining a 4-fold rotation axis with a mirror 2-D Symmetry Now try combining a 4-fold rotation axis with a mirror Any other elements? Yes, two more mirrors

Now try combining a 4-fold rotation axis with a mirror 2-D Symmetry Now try combining a 4-fold rotation axis with a mirror Any other elements? Yes, two more mirrors Point group name??

Now try combining a 4-fold rotation axis with a mirror 2-D Symmetry Now try combining a 4-fold rotation axis with a mirror Any other elements? Yes, two more mirrors Point group name?? 4mm Why not 4mmmm?

2-D Symmetry 3-fold rotation axis with a mirror creates point group 3m Why not 3mmm?

6-fold rotation axis with a mirror creates point group 6mm 2-D Symmetry 6-fold rotation axis with a mirror creates point group 6mm

2-D Symmetry All other combinations are either: Incompatible (2 + 2 cannot be done in 2-D) Redundant with others already tried m + m  2mm because creates 2-fold This is the same as 2 + m  2mm

2-D Symmetry The original 6 elements plus the 4 combinations creates 10 possible 2-D Point Groups: 1 2 3 4 6 m 2mm 3m 4mm 6mm Any 2-D pattern of objects surrounding a point must conform to one of these groups

3-D Symmetry New 3-D Symmetry Elements 4. Rotoinversion a. 1-fold rotoinversion ( 1 )

3-D Symmetry New 3-D Symmetry Elements 4. Rotoinversion a. 1-fold rotoinversion ( 1 ) Step 1: rotate 360/1 (identity)

3-D Symmetry New 3-D Symmetry Elements 4. Rotoinversion a. 1-fold rotoinversion ( 1 ) Step 1: rotate 360/1 (identity) Step 2: invert This is the same as i, so not a new operation

3-D Symmetry New Symmetry Elements 4. Rotoinversion b. 2-fold rotoinversion ( 2 ) Step 1: rotate 360/2 Note: this is a temporary step, the intermediate motif element does not exist in the final pattern

3-D Symmetry New Symmetry Elements 4. Rotoinversion b. 2-fold rotoinversion ( 2 ) Step 1: rotate 360/2 Step 2: invert

3-D Symmetry New Symmetry Elements 4. Rotoinversion b. 2-fold rotoinversion ( 2 ) The result:

3-D Symmetry New Symmetry Elements 4. Rotoinversion b. 2-fold rotoinversion ( 2 ) This is the same as m, so not a new operation

New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 )

3-D Symmetry New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 ) Step 1: rotate 360o/3 Again, this is a temporary step, the intermediate motif element does not exist in the final pattern 1

3-D Symmetry New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 ) Step 2: invert through center

3-D Symmetry New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 ) Completion of the first sequence 1 2

3-D Symmetry New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 ) Rotate another 360/3

3-D Symmetry New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 ) Invert through center

3-D Symmetry New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 ) Complete second step to create face 3 3 1 2

3-D Symmetry New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 ) Third step creates face 4 (3  (1)  4) 3 1 4 2

3-D Symmetry New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 ) Fourth step creates face 5 (4  (2)  5) 5 1 2

3-D Symmetry New Symmetry Elements 4. Rotoinversion c. 3-fold rotoinversion ( 3 ) Fifth step creates face 6 (5  (3)  6) Sixth step returns to face 1 5 1 6

3-D Symmetry New Symmetry Elements 4. Rotoinversion This is unique c. 3-fold rotoinversion ( 3 ) This is unique 3 5 1 4 2 6

New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 )

New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 )

3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) 1: Rotate 360/4

3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) 1: Rotate 360/4 2: Invert

3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) 1: Rotate 360/4 2: Invert

3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) 3: Rotate 360/4

3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) 3: Rotate 360/4 4: Invert

3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) 3: Rotate 360/4 4: Invert

3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) 5: Rotate 360/4

3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) 5: Rotate 360/4 6: Invert

3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) This is also a unique operation

3-D Symmetry New Symmetry Elements 4. Rotoinversion d. 4-fold rotoinversion ( 4 ) A more fundamental representative of the pattern

3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) Begin with this framework:

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1 2

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1 2

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1 3 2

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1 3 2

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1 3 2 4

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1 3 2 4

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1 3 5 2 4

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1 3 5 2 4

New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) 1 3 5 2 6 4

3-D Symmetry New Symmetry Elements 4. Rotoinversion e. 6-fold rotoinversion ( 6 ) Note: this is the same as a 3-fold rotation axis perpendicular to a mirror plane (combinations of elements follows) Top View

3-D Symmetry New Symmetry Elements 4. Rotoinversion A simpler pattern e. 6-fold rotoinversion ( 6 ) A simpler pattern Top View

We now have 10 unique 3-D symmetry operations: 1 2 3 4 6 i m 3 4 6 Combinations of these elements are also possible A complete analysis of symmetry about a point in space requires that we try all possible combinations of these symmetry elements

3-D Symmetry 3-D symmetry element combinations a. Rotation axis parallel to a mirror Same as 2-D 2 || m = 2mm 3 || m = 3m, also 4mm, 6mm b. Rotation axis  mirror 2  m = 2/m 3  m = 3/m, also 4/m, 6/m c. Most other rotations + m are impossible 2-fold axis at odd angle to mirror? Some cases at 45o or 30o are possible, as we shall see

3-D Symmetry 3-D symmetry element combinations d. Combinations of rotations 2 + 2 at 90o  222 (third 2 required from combination) 4 + 2 at 90o  422 ( “ “ “ ) 6 + 2 at 90o  622 ( “ “ “ )

3-D Symmetry As in 2-D, the number of possible combinations is limited only by incompatibility and redundancy There are only 22 possible unique 3-D combinations, when combined with the 10 original 3-D elements yields the 32 3-D Point Groups

But it soon gets hard to visualize (or at least portray 3-D on paper) 3-D Symmetry But it soon gets hard to visualize (or at least portray 3-D on paper) Fig. 5.18 of Klein (2002) Manual of Mineral Science, John Wiley and Sons

3-D Symmetry The 32 3-D Point Groups Every 3-D pattern must conform to one of them. This includes every crystal, and every point within a crystal Table 5.1 of Klein (2002) Manual of Mineral Science, John Wiley and Sons

3-D Symmetry The 32 3-D Point Groups Regrouped by Crystal System (more later when we consider translations) Table 5.3 of Klein (2002) Manual of Mineral Science, John Wiley and Sons

3-D Symmetry The 32 3-D Point Groups After Bloss, Crystallography and Crystal Chemistry. © MSA