Pauli principle. Wolfgang Pauli and Niels Bohr study spin.

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Presentation transcript:

Pauli principle

Wolfgang Pauli and Niels Bohr study spin

Σ ∆ l = ±1 ∆ S = 0

Σ ∆ l = ±1 ∆ S = 0

H2H2

H2H2

He 2

He 2 + ion.

H 2 + ion

H 2 - ion

The relative sizes of the lithium 1s and 2s atomic orbitals

Li 2

The three mutually perpendicular 2p orbitals on tow adjacent boron atoms.

The two p oribitals on the boron atom that overlap head-on combine to form bonding and antibonding orbitals.

The expected MO energy-level diagram for the combination of the 2 P orbitals on two boron atoms.

The expected MO energy-level diagram for the B 2 molecule

The correct MO energy-level diagram for the B 2 molecule.

The MO energy-level diagrams, bond orders, bond energies, and bond lengths for the diatomic molecules, B 2 through F 2.

An apparatus used to measure the paramagnetism of a sample

When liquid oxygen is poured into the space between the poles of a strong magnet, it remains there until it boils away. Source: Donald Clegg

The MO energy-level diagram for the NO molecule

The MO energy-level diagram for both the NO+ and CN- ions

A partial MO energy-level diagram for the HF molecule

The electron probability distribution in the bonding MO of the HF molecule

+ ↓