HBr Br atomic lines agust,heima,.....HBr/HBr 77634_ vhw.pxp agust,www,....hbr/PXP ak.ppt Agust,heima,...HBr/XLS ak.xls agust,heima,.....HBr/HBr_overall vhw.pxp

agust,heima,.....HBr/HBr 77634_ vhw.pxp 6.8 cm -1

agust,heima,...HBr/XLS ak.xls HBr Br atomic lines See file agust, heima,...HBr/HBr 77634_ vhw.pxp H 1S+, v´=0, S J´´C&GWangC&G - Wangcorrected closest to the Br line (2P3/2 <-<- 2P3/2) average Br line(?) NIST (2P3/2 <-<- 2P3/2) Br line(?) NIST (2P1/2<-<-2P3/2) V,v´=m+8 J´´C&GWangC&G-Wang closest to the Br line(2P1/2<-<-2P3/2)

Atomic line agust,heima,.....HBr/HBr 77634_ vhw.pxp 8.4 cm -1

Atomic line agust,heima,.....HBr/HBr 77634_ vhw.pxp 3.6 cm -1

3.6 cm -1 agust,heima,.....HBr/HBr_overall vhw.pxp

Three Br atomic lines are identified: 2P3/2 <-<- 2P3/2: (NIST value) 2P1/2<-<-2P3/2 : (NIST value) 4S3/2<-<-2P3/2: (NIST value) It is worth noticing that these Br lines are all in the vicinity of HBr moleculer lines: Br linesClosest HBr lines/ spacing(cm-1) 2P3/2 <-<- 2P3/2: J´´=0, H1S+, v´=0, S serie / P1/2<-<-2P3/2 : J´´=6, V(1S+),v´=m+8, Q series / S3/2<-<-2P3/2: ? / +3.6 This suggests that Br is formed by predissociation of Rdberg states analogous to what is found for CH3Br and CF3Br.