Www.kostic.niu.edu © MMIV* Prof. M. Kostic FUEL-CELL AND HEAT-ENGINE ENERGY-CONVERSION COMPARATIVE ANALYSIS FUEL-CELL AND HEAT-ENGINE ENERGY-CONVERSION.

Slides:



Advertisements
Similar presentations
Heat Engines A Brief Review of Thermodynamics Thermodynamics  The science of thermodynamics deals with the relationship between heat and work.  It.
Advertisements

Short Version : nd Law of Thermodynamics Reversibility & Irreversibility Block slowed down by friction: irreversible Bouncing ball: reversible.
1st & 2nd Law Analysis for Combustion Process
Combustion and Power Generation
This Week > POWER CYCLES
O n t h e T r a c k o f M o d e r n P h y s i c s 4/1 With full throttle Not only Carnot In a diesel.
Kinetic Theory and Thermodynamics
AP PHYSICS. p. 423 #59 A 1500W heat engine operates at 25% efficiency. The heat energy expelled at the low temperature is absorbed by a stream of water.
Advanced Thermodynamics Note 4 The Second Law of Thermodynamics
ENERGY CONVERSION ES 832a Eric Savory Lecture 12 – Large-scale plants Department of Mechanical and Material Engineering.
Thermodynamics Lecture Series Applied Sciences Education.
Heat Engines Heat Engines. Heat Engine cycles. Carnot cycle. Refrigerators & Air conditioners. Heat Pumps. 2 nd Law considerations. Entropy.
Lecture 11. Real Heat Engines and refrigerators (Ch. 4) Stirling heat engine Internal combustion engine (Otto cycle) Diesel engine Steam engine (Rankine.
ENTC 303: Fluid Mechanics and Fluid Power
Chapter 18 The Second Law of Thermodynamics. Irreversible Processes Irreversible Processes: always found to proceed in one direction Examples: free expansion.
Physics 52 - Heat and Optics Dr. Joseph F. Becker Physics Department San Jose State University © 2003 J. F. Becker.
Heat and Work: Part 2 Conservation of Energy Heat Engines Second Law of Thermodynamics Energy Efficiency OTEC.
Carnot Thermodynamics Professor Lee Carkner Lecture 12.
080125© M. Kostic Prof. M. Kostic Mechanical Engineering NORTHERN ILLINOIS UNIVERSITY Uniqueness and Universality of Heat Transfer: Challenges and Opportunities.
Thermo & Stat Mech - Spring 2006 Class 5 1 Thermodynamics and Statistical Mechanics Heat Engines and Refrigerators.
A cylinder containing an ideal gas is heated at constant pressure from 300K to 350K by immersion in a bath of hot water. Is this process reversible or.
Thermo & Stat Mech - Spring 2006 Class 6 1 Thermodynamics and Statistical Mechanics Entropy and the Second Law of Thermodynamics.
CHP & Fuel Cells at Home. Combined Heat and Power (CHP) aka “Cogeneration”
For next time: Read: § 8-6 to 8-7 HW11 due Wednesday, November 12, 2003 Outline: Isentropic efficiency Air standard cycle Otto cycle Important points:
For the cyclic process shown, W is:D A] 0, because it’s a loop B] p 0 V 0 C] - p 0 V 0 D] 2 p 0 V 0 E] 6 p 0 V 0 For the cyclic process shown,  U is:
Subject: thermal efficiency, mechanical efficiency, volumetric efficiency Student: 1391/12/5.
Engines, Motors, Turbines and Power Plants: an Overview Presentation for EGN 1002 Engineering Orientation.
Physics 207: Lecture 26, Pg 1 Dec. 1. Physics 207: Lecture 26, Pg 2 Lecture 26, Dec. 1 Goals: Chapter 19 Chapter 19  Understand the relationship between.
Energy and the Environment Fall 2013 Instructor: Xiaodong Chu : Office Tel.:
WCB/McGraw-Hill © The McGraw-Hill Companies, Inc.,1998 Thermodynamics Çengel Boles Third Edition 14 CHAPTER Chemical Reactions.
Reacting Mixtures and Combustion
Heat, Work, and Internal Energy Thermodynamic Processes.
VII. The second low of Thermodynamics
HEAT ENGINE D.A.DEGREE ENGG. & TECHNOLOGY
1 FUNDAMETALS OF ENERGY CONVERSIONS Doc. Ing. Tomáš Dlouhý, CSc.
Review for Exam 2.
Entropy Change by Heat Transfer Define Thermal Energy Reservoir (TER) –Constant mass, constant volume –No work - Q only form of energy transfer –T uniform.
An adiabatic free expansion of a gas in a thermally isolated container is not reversible because _____ . Select the correct answer. work must be.
Reversibility. Reversible Process  Quasi-static processes meant that each step was slo enough to maintain equilibrium.  If the process is reversed the.
The Stirling Engine. History  Developed in 1816 by Reverend Dr. Robert Stirling  Originally developed as an air engine  Invented to conserve fuel and.
19. 2 nd Law of Thermodynamics 1. Reversibility & Irreversibility 2. The 2 nd Law of Thermodynamics 3. Applications of the 2 nd Law 4. Entropy & Energy.
Energy and the Environment Fall 2013 Instructor: Xiaodong Chu : Office Tel.:
NTU ME H.K. Ma Department of Mechanical Engineering National Taiwan University, Taipei, Taiwan November, 2009 台灣大學機械工程系能源環境實驗室.
MME 2009 Metallurgical Thermodynamics
PHY1039 Properties of Matter Heat Engines, Thermodynamic Efficiency, and Carnot Cycles April 30 and May 3, 2012 Lectures 17 and 18.
The Bases of Energy: forms, units and efficiency
kr 1 Lecture Notes on Thermodynamics 2008 Chapter 7 Entropy Prof. Man Y. Kim, Autumn 2008, ⓒ Aerospace.
203/4c18:1 Chapter 18: The Second Law of Thermodynamics Directions of a thermodynamic process Reversible processes: Thermodynamic processes which can be.
Mon. Apr. 20 – Physics Lecture #39 Heat Engines and the Second Law of Thermodynamics 1. Lab 32: It’s Getting Hot In Here – Heat Engine Demos 2. Energy,
Thermodynamic Processes
Cycles  A series of processes which return a system to its initial state  Heat engine: receives heat; does work  Reversed cycle: cool or heat when work.
Chapter 12 Laws of Thermodynamics. Chapter 12 Objectives Internal energy vs heat Work done on or by a system Adiabatic process 1 st Law of Thermodynamics.
Chapter 8. Production of Power from Heat 고려대학교 화공생명 공학과.
Gestão de Sistemas Energéticos 2015/2016 Exergy Analysis Prof. Tânia Sousa
Further Analysis of Irreversible Processes P M V Subbarao Professor Mechanical Engineering Department Other Methods to Account the Entropy Generation…..
THERMODYNAMICS CYCLES RELATED TO POWER PLANTS
Chapter 20 Lecture 35: Entropy and the Second Law of Thermodynamics HW13 (problems):19.3, 19.10, 19.44, 19.75, 20.5, 20.18, 20.28,
Text pages Gibbs Free Energy Free Energy – Enthalpy and Entropy Combine Entropy and enthalpy both determine if a process is spontaneous (thermodynamically.
Carnot theorem and its corollary. Most energy extracted from the fuel in power plants is dumped to the environment as waste heat, here using a large cooling.
Solar collectors for water heating
Gas Power Cycles.
Entropy 1 m3 of N2 gas is in a sealed container at room temperature. The gas increases its volume by two processes 1) isothermal expansion and 2) adiabatic.
Reversibility.
The Laws of Thermodynamics
Physics 202 Lecture 6 Thermodynamics.
Lecture 43 Heat engine and efficiency
Chapter 8 Production of Power from Heat.
Gestão de Sistemas Energéticos 2016/2017
20th Century Thermodynamic Modeling of Automotive Prime Mover Cycles
Entropy and Free Energy Thermochemistry
Presentation transcript:

© MMIV* Prof. M. Kostic FUEL-CELL AND HEAT-ENGINE ENERGY-CONVERSION COMPARATIVE ANALYSIS FUEL-CELL AND HEAT-ENGINE ENERGY-CONVERSION COMPARATIVE ANALYSIS “ An Actual Engineering Topic! " Prof. M. Kostic Mechanical Engineering Mechanical Engineering NORTHERN ILLINOIS UNIVERSITY

© MMIV* Prof. M. Kostic Hydrogen Fuel Cell…

© MMIV* Prof. M. Kostic TABLE I: Energy-to-work conversion efficiencies Engine/ProcessEfficiency % Otto (gasoline) engine25-35 Diesel engine30-40 Gas turbine30-40 Steam turbine30-40 Nuclear, steam turbine30-35 Combined gas/steam turbines Fuel cell (hydrogen, etc.) Photovoltaic cell10-20 Windmill30-40 (59% limit) Hydro turbine80-85 Electro-mechanical motor/generator80-95

© MMIV* Prof. M. Kostic Chemical reaction

© MMIV* Prof. M. Kostic Maximum possible reversible work

© MMIV* Prof. M. Kostic Enthalpy of hydrogen formation or combustion

© MMIV* Prof. M. Kostic Efficiency of a hydrogen fuel-cell

© MMIV* Prof. M. Kostic Efficiency of a hydrogen fuel-cell (2)

© MMIV* Prof. M. Kostic Standard Formation Enthalpy (h f ) and Gibbs Free Energy (g f ) for Water-Vapor(g) and Water-Liquid(l) [in scale]. 95% 100% 83%

© MMIV* Prof. M. Kostic Maximum adiabatic combustion temperature

© MMIV* Prof. M. Kostic Combustion entropy generation and work lost due to entropy generation (combustion irreversibility)

© MMIV* Prof. M. Kostic Combustion Second Law efficiency (i.e., work availability, or exergy efficiency)

© MMIV* Prof. M. Kostic Heat engine, constant T ad temperature, ideal Carnot cycle

© MMIV* Prof. M. Kostic Heat engine, constant and variable temperature, ideal Carnot cycle

© MMIV* Prof. M. Kostic Heat engine, constant temperature Carnot cycle

© MMIV* Prof. M. Kostic Heat engine, variable temperature, ideal Carnot cycle

© MMIV* Prof. M. Kostic Conclusion

© MMIV* Prof. M. Kostic Conclusion…... the practical efficiencies are usually half of their theoretical limits, about 35% and 50% for heat engines and fuel cells, respectively. Still, further developments are needed to overcome fuel-cell limitations in low power density and competitive cost.

© MMIV* Prof. M. Kostic No Limits … No Limits … The Future Belongs To… … Whoever Gets There First NO SPEED LIMIT

© MMIV* Prof. M. Kostic You may contact Prof. Kostic at: mailto: mailto: or on the Web: prof.mkostic.com prof.mkostic.com Prof. M. Kostic Mechanical Engineering Mechanical Engineering NORTHERN ILLINOIS UNIVERSITY