BCE Time (years) CE Stone Age Bronze ageIron Age The ages of civilization and Metal Consumption
Mineral Resource Consumption Copper Lead Iron Aluminium Zinc
Metal consumption – resources
Life expectancies of resources of selected commodities based on crustal abundance
Metal Recycling
Rates Metal Recycling
Metallic Mineral Exploration – Looking for the proverbial needle in the haystack
Black Smokers and Massive Sulphide Ore Deposits 350 o C CuCl ZnCl 2 PbCl 2 Chalcopyrite Sphalerite Pyrite (FeS 2 ) (CuFeS 2 ) (ZnS)
Black Smokers Fluids precipitate sulphide minerals on the walls of the chimneys (Pyrite, FeS2; Chalcopyrite, CuFeS2; Sphalerite ZnS).
Massive Sulphide Ore Formation
Black Smokers and Massive Sulphide Ore Deposits
Sphalerite Pyrite Pyrite and sphalerite Sphalerite Pyrite Chalcopyrite Sphalerite Pyrrhotite Massive Sulphide Ores
Hydrothermal vein deposits 1 cm Hot water dissolves metals as complex molecules, e.g. H 2 WO 4 or Hg(HS) 2. Quartz and metallic minerals precipitate in fractures in response to cooling or changes in water chemistry Cinnabar (HgS ) m 10 cm Hg-bearing quartz vein Fluid inclusion Wolframite (Fe,Mn)WO 4 )
Porphyry Copper deposits 1 cm Porphyry ore Brine (NaCl-H 2 O) exsolves from cooling diorite intrusion Cu dissolved as CuCl 2, Fe as FeCl 2 Reaction with H 2 S on cooling to form chalcopyrite (CuFeS 2 ) Open pit mine
Au(HS) H H 2 O = Au O 2 + 2H 2 S Removed by boiling Native gold Formation of an epithermal gold deposit Gold-bearing quartz veins Native gold
Alluvial deposits Gold panning Gold nugget
Witwatersrand Goldfields Gold- bearing conglomerate (Produces 35% of world’s gold)
Understanding Planet Earth The Earth as a System