Model: I(total ions) = I(H+) + I(HCl+) = A(t) P m I(H+) = A(H+) P n I(H+)/(I(H+)+I(HCl+)) = (A(H+)/A(t)) P (n-m) = A(H+,t) P (n-m) ln(I(H+)/(I(H+)+I(HCl+)))

Slides:



Advertisements
Similar presentations
A c i d s & B a s e s. A c i d - B a s e T h e o r i e s A r r h e n i u s B r o n s t e d - L o w r y L e w i s A r r h e n i u s B r o n s t e d - L.
Advertisements

Use of moment generating functions. Definition Let X denote a random variable with probability density function f(x) if continuous (probability mass function.
HCl, F 
HCl: g3S-(0+)
HCl, , F, v´=0, J´=9: PC,labtop,...rannsoknir/F1DQPvsI vhwak.pxp Agust,www,...rempi/hcl/HCl,agust07-/F1DQPvsI vhwak.ppt.
HCl, agust,heima,.. REMPI/HCl/HCl,agust07-/HCLENER2-T ak.pxp agust,www,.... rempi/hcl/HCl,agust07-/HCLENER2-T ak.ppt.
Pnt I rel AK: ; agust,heima/rannsóknir/REMPI/HF/fra Wang/HF test skimmer pxp & HF t skimmer ppt Fig. 1.
HCl, d 3  1 PC(AK)/C:,.....HCl-Triplet states ak.ppt Agust,heima,...HCl-Potentials ak.pxp Agust, heima,...HCl-Triplet states.xls PC(AK)/C:,.....Experiment ej.pxp.
HCl, F
Pnt sqrt(Mw) Mw H Br Br CH379Br CH381Br+ pnt Sqrt(Mw) Coefficient values ± one standard.
200807, HCl: 1) PC,labtop....rannsoknir/HClmassFJ6-vhw-ak.pxp & xls and ppt 2) agust, heima../HCl/HCl,agust07-/ rannsoknir/HClmassFJ6-vhw-ak.pxp & xls.
HCl, C 1  AK, PC labtop C:,..../C – contour - full kmak.pxp Agust, www,..../C – contour - full kmak.ppt.
CH3Br, Relative ion intensities for CHn+: Rydberg system and nearby background ( ) & C atomic lines & Summary of REMPI spectra up to.
HCl, f 2 triplet state: Morse pot Agust,heima,...HCl-Triplet states.xls Agust,heima,...HCl-Triplet states.pxp Agust,www,...HCl-Triplet states.ppt.
HCl, V, v´=5: Effect of “Mass spectra integration” AK,PV-labt/C...HCl V(5,0) vhwkm.pxp AK,PV-labt/C...HCl V(5,0) vhwkm.ppt AK,PV-labt/C...HCl.
CH3Br, HBr spectra Agust, heima,... Jan10/CH3Br18750_19250-Hbr-sim km ak.pxp Agust, www,...Jan10/PPT ak.ppt.
HCl, V
HCl, Morse pot fit to calc. F state (CCSD & CCSD(T); AB calc, ): Agust,heima,.../REMPI/HCl/HCl,agust07-/HCl-Morse fit-F ak.pxp & Agust,www,.../rempi/hcl/HCl,agust07-/HCl-Morse.
HCl, f 3  2
Starter What is the spring constant for this spring?
F 3  3,2,1 & V,v´=8,9 agust,www,....hcl/january09/V(8,0) mass intensity ratios vs J levels vhwak.ppt.
; HCl VHW and ÁK, work agust,heima.../rannsóknir/REMPI/HCl/ HClmassF vhw.pxp & ppt.
300807; HCl, E
, HCl, F
310807, HCl, E
HCl, Agust,heima,....REMPI/HCl/HCl,agust07-/Fmass spectra vs v and J ak.ppt.
10.5 Basic Differentiation Properties. Instead of finding the limit of the different quotient to obtain the derivative of a function, we can use the rules.
Slope-Intercept Form of a Line
MwpntspeciesMwcalc 191H+1, C+11, CH+13, CH2+13, CH3+15, C2+24, C2H+24, C2H2+25,94874.
Wednesday, January 25, 2012MAT 121. Wednesday, January 25, 2012MAT 121.
Pre Calc Chapter 2 Section 6. Rational Functions Functions with the independent variable on the bottom of a fraction f(x) = N(x) D(x) Where N(x) & D(x)
Simple Linear Regression. Deterministic Relationship If the value of y (dependent) is completely determined by the value of x (Independent variable) (Like.
Lesson 2-8 Introduction to Derivatives. 2-7 Review Problem For a particle whose position at time t is f(t) = 6t 2 - 4t +1 ft.: b. Find the instantaneous.
Tangents. The slope of the secant line is given by The tangent line’s slope at point a is given by ax.
Continuity of A Function. A function f(x) is continuous at x = c if and only if all three of the following tests hold: f(x) is right continuous at x =
HCl, X pot.: rv and Bv evaluations: Agust,www,...HClnov07-/HCl-Potentials aka.ppt PC-labt.C..../rannsoknir/wavef-X-CCSD-AQZ ak.xls PC-labt.C..../rannsoknir/wavef-X-CCSD-AQZ ak.pxp.
Continuity of A Function 2.2. A function f(x) is continuous at x = c if and only if all three of the following tests hold: f(x) is right continuous at.
PHOTOFRAGMENTATIONS, STATE INTERACTIONS AND ENERGETICS OF HALOGEN CONTAINING MOLECULES: TWO-DIMENSIONAL (2+n) REMPI ÁGÚST KVARAN, et al. Science Institute,
TWO-DIMENSIONAL (2+n) REMPI SPECTROSCOPY: STATE INTERACTIONS, PHOTOFRAGMENTATIONS AND ENERGETICS OF THE HYDROGEN HALIDES JINGMING LONG, HUASHENG WANG,
 Is there a correlation between an adult’s body mass index (BMI) and their systolic blood pressure…
More with Rules for Differentiation Warm-Up: Find the derivative of f(x) = 3x 2 – 4x 4 +1.
I. Solve Get absolute value by itself, make a disjunction, solve 1) |r-7| = 92) 2|x| = 18.9.
网上报账系统包括以下业务: 日常报销 差旅费报销 借款业务 1. 填写报销内容 2. 选择支付方式 (或冲销借款) 3. 提交预约单 4. 打印预约单并同分类粘 贴好的发票一起送至财务 处 预约报销步骤: 网上报账系统 薪酬发放管理系统 财务查询系统 1.
中央财政支持社会组织参与社会服务项目 PNT 无创治疗青光眼防盲治盲医疗救助项目 中期情况汇报 中国盲人协会.
6.5 Solving and Graphing Absolute Value Equations
Mean Value Theorem.
Practice. Practice Practice Practice Practice r = X = 20 X2 = 120 Y = 19 Y2 = 123 XY = 72 N = 4 (4) 72.
Integrated Rate Law.
Sec 2.7: Derivative and Rates of Change
عمل الطالبة : هايدى محمد عبد المنعم حسين
آشنايی با اصول و پايه های يک آزمايش
Regression Computer Print Out
Objective 1A f(x) = 2x + 3 What is the Range of the function
Average Rate vs. Instantaneous Rate
CH3I summary This file includes some ideas about dissociation of
EEV, DI, S3,
Parent Functions and Transformations
Integrated Rate Law.
Differentiation Rules and Rates of Change
f(a+h) Slope of the line = Average Rate of Change = f(a+h) – f(a) h
500 nm WRITE VOLTAGE 0 V.
Bgr nLASER/ cm
Unit 6 – Fundamentals of Calculus
Warm Up Graph f(x) = 3x – 2 using a table
Characteristics.
Characteristics.
4.2 Critical Points, Local Maxima and Local Minima
Integrated Rate Law.
Chapter 4 Review.
Demo Slide.
Presentation transcript:

Model: I(total ions) = I(H+) + I(HCl+) = A(t) P m I(H+) = A(H+) P n I(H+)/(I(H+)+I(HCl+)) = (A(H+)/A(t)) P (n-m) = A(H+,t) P (n-m) ln(I(H+)/(I(H+)+I(HCl+))) = (n-m) ln(P) + ln(A) HCl, F<-<-X, (1,0), J = 6, mass analysis: agust,

pnt we04awe06awe09awe13a ,653331, ,752685, ,952699,629396H ,753166, ,953329, , ,253727,529609, ,450176, ,5HCl ,717501,6-4797, ,134539, ,146695,419527, ,250727, ,653331,630513bgr.(H+) ,253727,530691bgr.(HCl+) ,2-1444,7-2717,5I(H+) , , I(HCl+) 0, , , ,023994I(H+)/(I(H+)+I(HCl+)) -4, , , ,72995ln(ratio) 0,0350,060,090,13power (after autotracker) -3, , , ,04022ln(P)

Coefficient values ± one standard deviation a (inters ) = ± b(slope) = ± ln(I(H+)/(I(H+)+I(HCl+))) ln(P)

Coefficient values ± one standard deviation a = ± b = ± ln(I(H+)/(I(H+)+I(HCl+))) ln(P)

Coefficient values ± one standard deviation a = ± Inf b = ± Inf ln(I(H+)/(I(H+)+I(HCl+))) ln(P)

Summary: ln(P) ln(I(H+)/(I(H+)+I(HCl+))) (n-m) = 0.79 (n-m) = 0.69 (n-m) = 0.63

Conclusion: Slope is resonably close to the value 1, i.e. (n-m) = 1 as to be expected for the case n = 4 and m = 3