CF3Br agust,heima,....Mars11/XLS ak.xls agust,www,......April11/PPT ak.xls agust,heima,....Mars11/PXP ak.pxp agust,heima,....Mars11/CF3HBr REMPI Spectra vhw.pxp agust,heima,....Mars11/CF3HBr REMPI Spectra vhw ak.pxp

Quantum defects (  ), summary: spdf CH3Br CF3Br Br Br ath CH3Br agust,heima,...Mars11/XLS ak.xls 1) Derived by fit in agust,heima,....Mars11/PXP ak.pxp 1)

3/2;5p;d= X(3/2) X(1/2) ½; 5p;d= X(3/2) /2;6p;d= Possible np (->X) Rydberg states(?): agust,heima,....Mars11/CF3HBr REMPI Spectra vhw.pxp; Lay:3; Gr:0 CF 3 + 1D-REMPI and abs. spectrum CF 3 + 1D-REMPI abs. spectrum

X(3/2);5p;  = X(3/2) X(1/2) X(½); 5p;  = X(1/2) X(3/2);4d;  = X(3/2) X(3/2);4d;  = A(½) A(1/2);5p;  = Possible 5p (->X(3/2&1/2) and A(1/2)) and 4d (->X(3/2&1/2) Rydberg states(?):  =2  =0  =2 Vibrational bands agust,heima,....Mars11/CF3HBr REMPI Spectra vhw.pxp; Lay:3; Gr:0

Rel. CF 3 * Fluorescene ref: Suto & Lee (´83) Rel. Abs. agust,heima,....Mars11/CF3HBr REMPI Spectra vhw ak.pxp; Lay:3; Gr:0

There is no clear correlation between the CF3* fluorescenec and the CF3* 1D REMPI spectrum whereas there is a correlation between the CF3* 1D REMPI spectrum and the absorption spectrum in the sence that the major REMPI spectrum fits the absorption due to transition to the 5p Rydberg state

Br atom 1D-REMPI and abs. spectrum agust,heima,....Mars11/CF3HBr REMPI Spectra vhw.pxp; Lay:4; Gr:1