Lecture 12. Conjugate acid/base pairs HA + B  A - + BH +

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Presentation transcript:

Lecture 12

Conjugate acid/base pairs HA + B  A - + BH +

Salts Ionic solid Product of acid/ base reaction  neutralization

Autoprotolysis of water H 2 O + H 2 O  H 3 O + + OH - K w = [OH - ][H 3 O + ]  = 1.01 x o C

What is pH? pH = -log{H 3 O + } ~ -log[H 3 O + ] pH of pure water? Acidic vs. Bases

Strength of Acids/Bases

Weak Acid : Doesn’t completely dissociates

Strength of Acids/Bases Weak Base: Doesn’t completely dissociates

Relationship between K a and K b

Polyprotic acids

Ionic Strength C = molarity z = charge 1:1 electrolytes (NaCl) - μ = molarity 2:1, etc electrolytes (BaCl 2 ) - μ > molarity

What is the ionic strength of 0.1 M LiCl? What is the ionic strength of 0.1M Ca(NO 3 ) 2 ?

Electrolyte (salt) effect Effective concentration of ions become less as μ increases Shielding effect Non-ideal behavior

Activity [i] o = 1M (makes {i} dimensionless) γ is activity coefficient

Extended Debye-Hückel equation α – ion size z - charge γ – activity coefficient μ – ionic strength

Interpolate