Chemistry in PDR Chemical reactions and species. Chemistry in PDR: should we use the same of everything? Initial abundances  Initial abundances  Species.

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Presentation transcript:

Chemistry in PDR Chemical reactions and species

Chemistry in PDR: should we use the same of everything? Initial abundances  Initial abundances  Species set  Species set  Rates  Rates  Probably YES YES for important species Probably NO

Initial Abundances Sofia & Meyer 2001 He = C = 1.79e -4 O = 4.45e -4 Na = 8.84e -7 Mg = 5.12e -6 S = 1.43e -5 Variations: He = 0.14 S = 1.4e -7 C/O = 0.5-1? Benchmarking: He = 0.1 C = 1e -4 O = 3e -4 Important species: O, C (or C/O only?), He; but as you go more into the cloud, other species become important.

Species set Is the one we are using a good standard one for low Av PDR? Is the one we are using a good standard one for low Av PDR? Should we have a set of parameters within which the set is standard? Should we have a set of parameters within which the set is standard? Should we all include PAH? Should we all include PAH?

Rate files Ohio, UMIST, Personal, Mixtures Ohio, UMIST, Personal, Mixtures List of relevant rates? Please list List of relevant rates? Please list H e H e H 3 O + + e H 3 O + + e CH e? CH e? PAH? PAH? ……please add ……please add Next 2 plots shows effect of different rates for H e and H 3 O + + e respectively. Next 2 plots shows effect of different rates for H e and H 3 O + + e respectively. H 3 + rates are from UMIST 99 (left plot) and old UMIST 96 (right) H 3 + rates are from UMIST 99 (left plot) and old UMIST 96 (right) H 3 O + are from Vejby-Christensen et al (left plot) and Williams et al 1996 (right plot). H 3 O + are from Vejby-Christensen et al (left plot) and Williams et al 1996 (right plot).