Carbon and Nitrogen Cycling Robert F. Chen UMassBoston Environmental Coastal and Ocean Sciences (ECOS)

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Presentation transcript:

Carbon and Nitrogen Cycling Robert F. Chen UMassBoston Environmental Coastal and Ocean Sciences (ECOS)

Carbon Fourth most abundant element in the universe Basis for life 4 bonds Forms complex molecules Gaseous form Buckminster Fullerene Megaphone Bastadin-5 Moronic Acid

Photosynthesis Where does the mass of a tree come from? CO 2 + H 2 O  CH 2 O + O 2

Global Productivity

Respiration Mitochondria, bacteria, fires, combustion engines O2 + CH2O  CO2 + H2O Fossil Fuels burned at 20,000 times natural rates of oxidation

CO2 Emissions

Atmospheric Measurements

“Missing Sink” of Atmospheric CO2 (in Gigatons Carbon—10 15 gmC) Fossil Fuel Burning=6.0+/- 0.5 Deforestation=0.9+/-0.7 Atmospheric Increase =3.2+/-0.1 Oceanic Uptake=2.0 +/-0.8 “Missing Sink”=1.7 +/1.2

Mass Balance Total mass is always conserved Each element is also conserved in a closed system Can you design a closed system that is sustainable indefinitely? Eco-sphere.com

Neponset River Estuary Urban: Largest salt marsh in Boston Small: ~6km long; ~100m wide <5m deep, 3m tidal range Oldest dam in the country Extensive salt marsh and mudflats

Granite Ave. Bridge Gulliver’s Creek

Minishuttle Instrumentation Minishuttle underway at ~4 kts

Cycles are linked CO2 + H2O  CH2O + O2

Biosphere 2 /virtualtour/beach.ht mhttp:// /virtualtour/beach.ht m 7 people, O2 began to drop Why?

Nitrogen Cycle

Needs Amino Acids  proteins Nucleic Acids Chlorophyll Carbon to Nitrogen ratio

Sources Nitrogen Fixing bacteria –Legumes –Clover –Cyanobacteria Lightning Haber Process (factory fertilizer production) Internal combustion engines (cars) Mankind has doubled N-inputs to coastal areas  eutorphication

Fall Colors Chlorophyll-N recalled Accessory pigments shown Huge loss of C, but not N

Lawn calculation If you add 1 pound of nitrogen fertilizer to your lawn, how many pounds of lawn clippings must you carry away? Water Carbon/Nitrogen ratio

Frameworks Elements and compounds Mixtures and pure substances (solutions) Conservation of Mass Energy and living things Changes of ecosystems over time/affect of mankind