CH +, CH, and CN Emission from the Red Rectangle Lewis M. Hobbs, Julie A. Thorburn, D. G. York, Takeshi Oka, Department of Astronomy and Astrophysics,

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CH +, CH, and CN Emission from the Red Rectangle Lewis M. Hobbs, Julie A. Thorburn, D. G. York, Takeshi Oka, Department of Astronomy and Astrophysics, the University of Chicago, Theodore P. Snow, Center for Astrophysics and Space Astronomy, University of Colorado, and John Barentine, New Mexico State University and Apache Point Observatory 59 th Ohio State University International Symposium on Molecular Spectroscopy WI02, 2:05 pm, June 23, 2004

1937 Birth of Molecular Astrophysics Theodore Dunham, Jr Walter Sydney Adams, T. Adams, Jr. PASP 49, 29 (1937) PAAS 9, 5 (1937) P. Swings & L. Rosenfeld, ApJ 86, 483 (1937) A.McKellar, PASP 52, 187, 312 (1940) 53, 233 (1941) CH CN Pub. Dom. Astroph. Obs. 7, 251 (1941) A. E. Douglas and G. Herzberg, ApJ 94, 381 (1941) CH +

Men’shchikov et al. A & A 393, 867 (2002)

Apache Point Observatory 3.5-meter 3,800–10,000 Å ; /  ~ 38,000 (8 km/s) S/N ~ nights, from Feb to Feb emission lines detected. 57 atomic, 76 molecular

CH + CH CN (0 - 0) 4236 Å Waelkens, van Winckel, Trams, Waters, A & A 256, L15 (1992) Balm and Jura, A & A 261, L25 (1992) Hall, Miles, Sarre, Fossey, Nature 358, 629 (1992) Bakkers, van Dishoeck, Waters, Schoenmaker, A & A 323, 469 (1997) (1  0) 3969 Å, (2-1) 4177 Å, (1-1) 4443 Å, (0- 1) 4793 Å, (1-2) 5029 Å, 52 lines up to J = Å 3 lines 3875 Å 24 lines up to N = 14

f = 5.45 × f = 1.08 × 10 -3

CH + (0 - 0) CH (0 - 0) CH + and CH are in different regions

CN up to N = 14

CH + Spontaneous emission time τ A → X τ ~ 1 μs Larsson, Siegbahn, CP 76, 175 (1983) v = 1→0 τ ~ 1 s Ornellas, Machado, JCP 84, 1296 (1985) J = 6→5 τ ~ 2.15 s Sun, Freed, JCP 88, 2659 (1988) μ A→X = 0.47 Debye μ 1→0 = Debye μ 0 = Debye B 0 = cm -1 Critical density n c ~ 10 8 cm -3 ! NGC 7072 up to J = 6 Cernicharo, Liu, Gonzalez-Alfonso, Cox, Barlow, Lim, Swinyard, ApJ 483, L65 (1997)

Collisional thermalization ?? What is the collision partner ?? H, H 2, (He), (e - )

The Enigma of CH + Chemistry Production C + + H → CH + + hν cm 3 s -1 C + + H 2 → CH + + H Endothermic by 0.4 eV C + H 3 + → CH + + H 2 Destruction CH + + H → C + + H 2 Exothermic by 0.4 eV CH + + H 2 → CH H Exothermic by 1.7 eV CH + + e - → C + H No way to thermalize CH + by collisions!!

Lambert, Danks, ApJ, 303, 401(1986) C + + H 2 * ↔ CH + + H v = eV CH + + H 2 → CH H k 1 n(C + )n(H 2 * ) = k -1 n(CH + )n(H) + k 2 n(CH + )n(H 2 ) The critical density should still be high > 10 8 cm -3

CN Spontaneous emission time τ A → X τ ~ 0.2 μs Bauschlicher, Langhoff, Taylor (1988) J = 14 → 13 τ ~ 12 s Langhoff, Bauschlicher(1989) μ 0 = Debye B 0 = cm -1 Critical density n c ~ 10 8 cm -3 !

Hertzprung-Russell Diagram R ~ 300R 