PH In the Laboratory. Ionization of Water Equllibrium Constant, K eq.

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Presentation transcript:

pH In the Laboratory

Ionization of Water

Equllibrium Constant, K eq

Ion Product of Water, K W

pH

Acidity

Measuring pH Indicater Dyes; Methyl Red, Phenol Red, etc. pH Paper (Litmus Paper) pH Meter

Voltmeter with electrode Measures electrical potential difference across electrode due to protons 1 pH unit = 60 mV pH also dependent on temperature

pH Electrode Filled with reference solution (4 M KCl, sat. AgCl) Glass semi permable (protons cannot cross) Glass protected by plastic sleeve Some are sensitive to Tris buffer

pH Standards Color coded 4, 7, and 10 Potassium Hydrogen Pthalate Standardize everyday Bracket pH range

pH of Strong Acids HCl H + + Cl - Assume complete dissociation 1 M HCl, pH = -log [H + ] = -log 1 = ? 0.5 M HCl, pH = -log 0.5 = ? 6 M HCl, pH = -log 6 = ?

pH of Strong Bases NaOH Na + + OH - Assume complete dissociation pK W = pH + pOH = 14 pH = 14 – (-log [OH - ]) 1 M NaOH, pH = 14 – (-log 1) = ? 0.01 M NaOH, pH = 14 – (-log 0.01) = ? 6 M NaOH, pH = 14 – (-log 6) = ?

pH of a Weak Acid