Chemistry for Changing Times 12th Edition Hill and Kolb Chapter 14 Water: Rivers of Life; Seas of Sorrow John Singer Jackson Community College, Jackson, MI © 2010 Pearson Prentice Hall, Inc.

Water: Some Unique Properties Expands when it freezes. © 2010 Pearson Prentice Hall, Inc.

Water: Some Unique Properties High Heat of Vaporization Water has a very high heat of vaporization for a liquid. Therefore, a large amount of heat is required to vaporize a small amount of water. © 2010 Pearson Prentice Hall, Inc.

Water: Some Unique Properties High Specific Heat Specific heat is the amount of heat energy necessary to raise the temperature of 1 gram of water 1 oC. © 2010 Pearson Prentice Hall, Inc.

© 2010 Pearson Prentice Hall, Inc. Water in Nature 75% of Earth’s surface is covered with water. Nearly 98% of that is seawater. About 2% of Earth’s water is frozen in the polar ice caps. © 2010 Pearson Prentice Hall, Inc.

The Water Cycle and Natural Contaminants © 2010 Pearson Prentice Hall, Inc.

The Water Cycle and Natural Contaminants Natural contaminants in water include: Gases including radon, nonmetal oxides, and others. Dissolved minerals including cations and anions. Calcium, magnesium, and iron salts cause hard water. Organic Matter: Bacteria, microorganisms, and animal wastes are all potential contaminants of natural waters. © 2010 Pearson Prentice Hall, Inc.

The Water Cycle and Natural Contaminants © 2010 Pearson Prentice Hall, Inc.

Chemical and Biological Contamination Waterborne Disease Contamination of water by pathogenic organisms was a serious problem. The EPA estimates that 30 million people in the U.S. are threatened by bacterial contamination of water supplies. It is estimated that 80% of all illness in the world is caused by water contamination. © 2010 Pearson Prentice Hall, Inc.

Chemical and Biological Contamination Acid Rain Sulfur and nitrogen oxides (SOx and NOx) are deposited as acid rain. Acidic precipitation damages the environment by lowering the pH of soil and lakes and streams. Acid rain also can corrode metals and dissolve limestone and marble. © 2010 Pearson Prentice Hall, Inc.

Chemical and Biological Contamination Sewage and Dying Lakes The release of sewage into waterways increases the biochemical oxygen demand (BOD), and leads to eutrophication (aging) of a lake. Organic matter can undergo either aerobic or anaerobic decay. © 2010 Pearson Prentice Hall, Inc.

Chemical and Biological Contamination © 2010 Pearson Prentice Hall, Inc.

The Water Cycle and Natural Contaminants Sewage and Dying Lakes Eutrophication is a natural process that is accelerated by the presence of human waste and runoff from farms, lawns, and other human activity. © 2010 Pearson Prentice Hall, Inc.

© 2010 Pearson Prentice Hall, Inc. Industrial Water Use Manufacturing processes produce waste products and use water resources. © 2010 Pearson Prentice Hall, Inc.

Groundwater Contamination Approximately one-half of the U.S. population gets its drinking water from groundwater sources. Groundwater sources in many parts of the country are contaminated. Groundwater is easy to contaminate and difficult, as well as expensive, to clean up. © 2010 Pearson Prentice Hall, Inc.

Groundwater Contamination Nitrates Nitrate contamination of groundwater is particularly a problem in rural areas. Agricultural activity contributes fertilizers and animal wastes to water sources. Nitrates are very soluble. They are therefore difficult to remove from water supplies. Nitrates are a problem with infants usually less than one year old. They metabolize nitrate to nitrite. Nitrite ions then complex heme and the baby can turn blue and die. This condition is known as methemoglobinemia (blue baby syndrome). © 2010 Pearson Prentice Hall, Inc.

Groundwater Contamination Nitrates © 2010 Pearson Prentice Hall, Inc.

Groundwater Contamination Volatile Organic Chemicals (VOCs) VOCs can contaminate groundwater and add undesirable odor to drinking water. Also, many are carcinogenic. Sources include: industrial activity, oil and brine wells, landfills, leaking underground storage tanks, and illegal dumping of organic wastes. © 2010 Pearson Prentice Hall, Inc.

Making Water Fit to Drink More than 170,000 public water systems exist in the United States. The per capita use of water in the U.S. is almost 2 million liters per year. This includes water used for industrial, agricultural, and personal purposes. This use exceeds the per capital use of other nations. © 2010 Pearson Prentice Hall, Inc.

Making Water Fit to Drink The United States Safe Drinking Water Act was first passed in 1974. It was amended in 1986 and 1996. The act authorizes the EPA to set, monitor, and enforce national health-based standards for contaminants in municipal water supplies. © 2010 Pearson Prentice Hall, Inc.

Making Water Fit to Drink The United States Safe Drinking Water Act © 2010 Pearson Prentice Hall, Inc.

Making Water Fit to Drink Parts per Million (ppm) 1 ppm = 1 g solute 106 g solution Parts per Billion (ppb) 1 ppb = 1 g solute 109 g solution © 2010 Pearson Prentice Hall, Inc.

Water Treatment Plants In most urban areas, water is treated at a water treatment plant before it is distributed to homes for consumption. © 2010 Pearson Prentice Hall, Inc.

Water Treatment Plants The first step in water treatment is to add slaked lime and alum to the water: The slaked lime and alum form the gelatinous aluminum hydroxide, which coagulates colloidal particles with bacteria. These are then removed by filtering through sand and gravel filters. Charcoal is often present in the filtering process to remove odors and the water is aerated to improve taste. © 2010 Pearson Prentice Hall, Inc.

Water Treatment Plants Chemical Disinfection Chlorine is added to kill any remaining bacteria. Municipal drinking water often contains residual chlorine so that the water can be free from bacteria at any point in the distribution system. Ozone can also be used for bacterial disinfection and has the added advantage of killing many viruses. © 2010 Pearson Prentice Hall, Inc.

Water Treatment Plants © 2010 Pearson Prentice Hall, Inc.

Water Treatment Plants Other Technologies Ultraviolet light (UV) can also be used to disinfect water. It is most effective in small-scale applications. One disadvantage is that it does not offer the residual protection that chlorine or ozone does. © 2010 Pearson Prentice Hall, Inc.

Water Treatment Plants Fluorides Many municipal water supplies have fluoride added to help prevent tooth decay. Tooth enamel is composed of a calcium phosphate complex called hydroxyapatite. Fluoride ions replace some of the hydroxide ions, making the enamel harder and less affected by acids: © 2010 Pearson Prentice Hall, Inc.

Water Treatment Plants Fluorides Water is fluoridated by adding H2SiF6 or Na2SiF6 to a concentration 0.7-1.0 ppm. Early studies showed a 50% to 70% reduction in dental caries (cavities) in populations using fluoridated drinking water. Fluoridation of drinking water is not without controversy. Some people object to the fluoridation of drinking water. © 2010 Pearson Prentice Hall, Inc.

© 2010 Pearson Prentice Hall, Inc. Wastewater Treatment Before wastewater can be returned to the environment, it should be treated to remove harmful contaminants. Municipal wastewater treatment is considered to involve up to three levels of processing. © 2010 Pearson Prentice Hall, Inc.

© 2010 Pearson Prentice Hall, Inc. Wastewater Treatment Primary sewage treatment involves holding the sewage in settling ponds to allow heavier solids to precipitate out as sludge. © 2010 Pearson Prentice Hall, Inc.

© 2010 Pearson Prentice Hall, Inc. Wastewater Treatment Secondary sewage treatment involves passing the effluent from the primary treatment through sand and gravel filters. During this process, aerobic bacteria can break down much of the organic matter. © 2010 Pearson Prentice Hall, Inc.

© 2010 Pearson Prentice Hall, Inc. Wastewater Treatment Another form of secondary treatment is called the activated sludge method. The sewage is placed into tanks and aerated with large blowers. © 2010 Pearson Prentice Hall, Inc.

© 2010 Pearson Prentice Hall, Inc. Wastewater Treatment Tertiary treatment involves further treating the sewage, such as charcoal filtration to absorb organic molecules, reverse osmosis, further filtration, distillation, etc. © 2010 Pearson Prentice Hall, Inc.

© 2010 Pearson Prentice Hall, Inc. Wastewater Treatment © 2010 Pearson Prentice Hall, Inc.

The Newest Soft Drink: Bottled Water Bottled water is the fastest growing and most profitable segment of the beverage industry. Per capita consumption is 90 liters per year and growing. Many people think that drinking bottled water is better for one’s health than drinking tap water. In many cases, bottled water is someone else's tap water. © 2010 Pearson Prentice Hall, Inc.

Alternative Sewage Treatment Systems Sludge from municipal sewage treatment systems can be used as fertilizer. A number of communities allow primary treatment in settling ponds. The effluent is then allowed to flow into marshes that filter the sewage and use the nutrients. Toilets have been developed that compost wastes. Composting toilets use no energy or water. © 2010 Pearson Prentice Hall, Inc.

We Are the Solution to Water Pollution Water is essential to our quality of life. We must do what we can to maintain the quality of our water sources. © 2010 Pearson Prentice Hall, Inc.