Advanced Higher Unit 3 Elemental microanalysis. Elemental Microanalysis Elemental microanalysis (or combustion analysis) is used to determine the masses.

Slides:

Advertisements

Similar presentations

Copyright Sautter EMPIRICAL FORMULAE An empirical formula is the simplest formula for a compound. For example, H 2 O 2 can be reduced to a simpler.

Advertisements

GRAB A CALCULATOR AND GET OUT A PIECE OF PAPER FOR NOTES. Empirical Formulas.

Calculate the Empirical Formula for a compound with the following composition: 46.16% carbon; 53.84% nitrogen 1)Change % to grams (if needed) 2)Convert.

Calculating Empirical and Molecular Formulas

Unit V: The Mole Concept V.5. Empirical and Molecular Formulae.

Percentage Composition and Empirical Formula

Percent Composition and Empirical Formulas

Chemistry Notes Empirical & Molecular Formulas. Empirical Formula The empirical formula gives you the lowest, whole number ratio of elements in the compound.

Empirical and Molecular Formulas. Formaldehyde CH 2 O Acetic acid C 2 H 4 O 2 Gylceradehyde C 3 H 6 O 3 40% C; 6.7% H; 53.3% O.

2.00 ECS 1.00 IonsMass Finding the Empirical Formula of a Compound © Chemworks.

Determining Chemical Formulas Experimentally % composition, empirical and molecular formula.

Percent Composition, Empirical and Molecular Formulas Courtesy

Finding Theoretical Yield and Percent Yield

Chapter 3 Percent Compositions and Empirical Formulas

Mass Conservation in Chemical Reactions Mass and atoms are conserved in every chemical reaction. Molecules, formula units, moles and volumes are not always.

FINDING EMPIRICAL AND CHEMICAL FORMULAS BY EXPERIMENT Chemistry 11 Ms. McGrath.

4.6 MOLECULAR FORMULAS. 1. Determine the percent composition of all elements. 2. Convert this information into an empirical formula 3. Find the true number.

Empirical Formulas. Empirical formula tells the relative number of atoms of each element in a compound Mole concept provides a way of calculating the.

Empirical Formulas 4/1 - ATB: If an unknown sample has 1 mole of H and 1 mole of Cl, what would be the formula of this compound?

Empirical Formulas. Empirical formula tells the relative number of atoms of each element in a compound Mole concept provides a way of calculating the.

BRADY PROBLEM 2.83 Tutorial on the procedure of solving for empirical and molecular formulas from a combustion reaction.

Percentage Composition: is the percent mass of each element present in a compound.

© 2012 Pearson Education, Inc. Finding Empirical Formulas.

Using the MOLE. Percentage composition Percentage composition is the mass of individual elements in a compound expressed as a percentage of the mass of.

Percentage Percentage means ‘out of 100’

 Mass of crucible + lid = g  Mass of crucible + lid + Mg = g  Mass of crucible + lid + magnesium oxide = g.

What Could It Be? Empirical Formulas The empirical formula is the simplest whole number ratio of the atoms of each element in a compound. Note: it is.

1 Chapter 10 “Chemical Quantities” Yes, you will need a calculator for this chapter!

Combustion Analysis Ex - Find the empirical formula of vitamin C (ascorbic acid), a compound that contains only C, H, and O. Combustion of g of.

% Composition, Empirical Formulas, & Molecular Formulas.

Empirical Formulas. Gives the lowest whole-number ratio of the elements in a compound. Example: Hydrogen Peroxide (H 2 O 2 ) Empirical Formula- HO.

Mr. Chapman Chemistry 20. Converting from grams to moles Need: Moles and Mass worksheet.

Empirical and Molecular Formulas. Formulas  molecular formula = (empirical formula) n  molecular formula = C 6 H 6 = (CH) 6  empirical formula = CH.

Empirical and Molecular Formulas. CH 2 O CH 3 OOCH = C 2 H 4 O 2 CH 3 O Empirical Formula A formula that gives the simplest whole-number ratio of the.

Calculating Empirical Formula Using percentage or mass to find the Empirical Formula.

1 Percent Composition: Identifies the elements present in a compound as a mass percent of the total compound mass. The mass percent is obtained by dividing.

Molecular Weight, Percent Composition, Empirical Formula.

From Empirical Formulas

Calculations based on Compounds Molar mass Practice mole conversions  Check answers from methane problems  Determining formulas based on data  % composition.

IC5.4.4 Empirical formulae from experimental data © Oxford University Press Empirical formulae from experimental data.

A blast from the past Combustion: when fuel burns, water and carbon dioxide are the products. Sometimes is a hydrocarbon fuel (contains carbon and hydrogen)

Molecular Formula Calculations Combustion & Weight Percent C x H y + (x + y/4) O 2  x CO 2 + y/2 H 2 O C 2 H 5 OH + 3 O 2  2 CO H 2 O.

Percent Mass, Empirical and Molecular Formulas. Calculating Formula (Molar) Mass Calculate the formula mass of magnesium carbonate, MgCO g +

FINDING EMPIRICAL AND CHEMICAL FORMULAS BY EXPERIMENT

Unit V: The Mole Concept

Calculating Empirical Formulas

EMPIRICAL FORMULA VS. MOLECULAR FORMULA .

Empirical Formulas.

Empirical and Molecular Formulas

EMPIRICAL FORMULA The empirical formula represents the smallest ratio of atoms present in a compound. The molecular formula gives the total number of atoms.

Empirical and Molecular Formulas

Calculating Empirical and Molecular Formulas

Empirical/Molecular Notes

Empirical and Molecular Formulas

Empirical/Molecular Notes

Empirical and Molecular Formulas

Empirical and Molecular Formulas

Empirical Formula Combustion analysis is one of the most common methods for determining empirical formulas. A weighed compound is burned in oxygen and.

Vocabulary Percent Composition -

Empirical and Molecular Formulas

From percentage to formula

Empirical and Molecular Formulas

Percentage Composition

What Could It Be? Finding Empirical and Molecular Formulas.

Empirical Formulas Molecular Formulas.

Empirical and Molecular Formulas

Empirical/Molecular Notes

Calculating Empirical and Molecular Formulas

Combustion analysis Combustion analysis is a method used in both organic chemistry and analytical chemistry to determine the elemental composition (more.

Empirical Formulas, Hydrates, and Molecular Formulas

Presentation transcript:

Advanced Higher Unit 3 Elemental microanalysis

Elemental Microanalysis Elemental microanalysis (or combustion analysis) is used to determine the masses of the elements in a sample of an organic compound in order to calculate its empirical formula. The carbon, hydrogen and nitrogen contents are measured using an instrument known as a CHN analyser.

The Process Step 1 -An accurate mass of sample (~2 mg) is weighed out. Step 2 -Sample is then placed in a sealed oxygen atmosphere and combusted at ~1000 °C. Step 3 -CO 2, H 2 O and N x O y are produced and passed through a CHN analyzer (a different but similar analyzer is used for S) Step 4 -Other elements, except oxygen, are determined by alternative methods. Step 5 -Samples are analysed in dup;icates to give more reliable results.Results are calculated and expressed as a percentage, by mass. Now watch the RSC video on ‘Elemental Microanalysis’

Empirical Formula Calculations C H O  1 =6 12  1 =12 1  1 = ElementMass Present RAMMoles present  by smallest Whole number ratio Calculate the empirical mass of a compound that contains 72 % carbon, 12 % hydrogen, and 16 % oxygen Empirical Formula is C 6 H 12 O

Calculate the empirical formula of the following two examples a) C = % H = 7.32 % O = % b)C = % H = % O = % C5H6OC5H6O C 5 H 10 O

A sample of an organic compound with a mass of 1.224g was completely burned in oxygen and found to produce 2.340g of CO 2 and 1.433g of H 2 O. Calculate the empirical formula of the organic compound. Mass of carbon = 12.0/44.0 x = 0.638g Mass of hydrogen = 2.0/18.0 x = 0.159g Mass of oxygen = – ( ) =0.427g

Number of moles Mole ratio C0.638/12 = / = 2 H0.159/1 = / = 6 O0.427/16= / = 1 Empirical formula = C 2 H 6 O

Exercise Now try the exercise on page 3 of your Unit 3(d) notes.