PHYS3004 Crystalline Solids

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Presentation transcript:

PHYS3004 Crystalline Solids Prof. P.A.J. de Groot

1. BONDING IN SOLIDS Born-Oppenheimer Approximation Linear Combination of Atomic Orbitals

1. BONDING IN SOLIDS Covalent bonding Ionic bonding Metallic bonding Van der Waals bonding

1. BONDING IN SOLIDS Covalent bonding: LCAO Bonding and anti-bonding states

2. CRYSTAL LATTICES Lattice & basis Wigner-Seitz cell R1

3. RECIPROCAL LATTICE Diffraction of waves (x-rays) Reciprocal lattice

3. RECIPROCAL LATTICE First Brillouin zone Bloch theorem:

4. FREE ELECTRON MODEL – JELLIUM Electrons in a box Time independent Schrödinger eq. Plane wave solutions Boundary conditions (box is finite)

4. FREE ELECTRON MODEL – JELLIUM Density of states Fermi energy

4. FREE ELECTRON MODEL – JELLIUM Charge oscillations – plasmons Electrical transport (relaxation time) Quantum Jellium Hall effect Breakdown of Jellium Model

5. NEARLY-FREE ELECTRON MODEL Perturbation theory – only significant changes in E(k) near degenerate points

5. NEARLY-FREE ELECTRON MODEL Effective mass Electrons and holes

6. TIGHT BINDING jellium  nearly-free electrons  tight binding  atoms

6. TIGHT BINDING LCAO Bloch theorem Crystal momentum

7. MAGNETIC PROPERTIES OF CRYSTALS Paramagnetism – partly filled shells Curie’s law

7. MAGNETIC PROPERTIES OF CRYSTALS Pauli paramagnetism Ferromagnetism & mean field theory

7. MAGNETIC PROPERTIES OF CRYSTALS

8. SEMICONDUCTORS Intrinsic Doping (donors/acceptors) Valence band Conduction band

8. SEMICONDUCTORS Transport (electrons/holes) Einstein relation

8. SEMICONDUCTORS MOSFET Depletion width Gate-controlled conduction channel 2D electron gas – quantum Hall effect Vs metal SiO2 x p-Si