- acid formation(?). = HCl Water / H 2 O = i.e.: H 3 O +..... Cl - (aq) HCl + H 2 O(l)

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Presentation transcript:

- acid formation(?)

= HCl Water / H 2 O = i.e.: H 3 O Cl - (aq) HCl + H 2 O(l)

H 3 O Cl - (aq) HCl + H 2 O(l) Energy +

= HCl(g) =  H + Cl -  (g) Energy r(HCl) HCl H + Cl  H + Cl -  H + + Cl -

HCl (2+1)REMPI Spectrum /cm -1 Energy r(HCl) HCl H + Cl  H + Cl -  H + + Cl -

HCl (2+1)REMPI Spectrum LASER /cm -1 Energy r(HCl) HCl H + Cl  H + Cl -  V 1  + H + + Cl - E  2 x 21000= cm -1 v =11 0

HCl(g)  H + Cl -  (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl  H + Cl -  H + + Cl - H 3 O +... Cl - (nxH 2 O) + n x H 2 O

HCl(g)  H + Cl -  (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl  H + Cl -  H 3 O +... Cl - (nxH 2 O)  H + Cl -    + H 2 O ::::::::::  H + Cl -      H + Cl -     n  (Castlemann et al., 2002)

HCl(g)  H + Cl -  (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl  H + Cl -  H 3 O +... Cl - (nxH 2 O) + H 2 O ::::::::::  H + Cl -    

Nozzle Pump Focus lens MCP Detector +HV HCl(g) H 2 O(l) Cooling vessel H 2 O(g) HCl/H 2 O(g) HCl    i  H + Cl -    i  h H 3 O +  Cl - ((i-1)xH 2 O)(?) HCl    i  nh  H + Cl -    i ; +

HCl(g)  H + Cl -  (g) Energy + H 3 O +... Cl - (aq) r(HCl) HCl  H + Cl -  H 3 O +... Cl - (nxH 2 O) +3 H 2 O ::::::::::  H + Cl -     +