CH3Br, : Energetics for CH 3 Br(g) -> H2(g) + C(g) + HBr(g) agust,heima,...Nov09/PPT ak.ppt

CH 3 Br(g) -> H2(g) + C(g) + HBr(g) CH 3 (g) + Br(g)) 70.3 kcal mol -1 = cm -1 Handbook of bond energies: CH + (g) +H 2 (g) + Br(g)) eV =Appearance nergy eV = Bond energy (CH + ) C + (g) + H 2 (g) + H(g) + Br(g)) eV = = -D 0 0 (HBr) Huber and Herzberg: Constants of diatomic molecules C + (g) +H 2 (g) +HBr(g)) eV = cm -1 = - IE(C) notes eV= cm -1  E = = cm -1

CH3Br(g) -> H2(g) + C(g) + HBr(g) CH3(g) + Br(g)) 70.3 kcal mol-1 = cm-1 Handbook of bond energies: CH+(g) +H2(g) + Br(g)) eV CH+(g) +2H(g) + Br(g)) 4.5 eV eV C+(g) +3H(g) + Br(g)) cm eV = C+(g) +H2(g) +H(g) + Br(g)) eV = = -D 0 0 (HBr) Huber and Herzberg: Constants of diatomic molecules C+(g) +H2(g) +HBr(g)) eV = cm-1= - IE(C) notes