HCl, Agust,heima,....REMPI/HCl/HCl,agust07-/Fmass spectra vs v and J ak.ppt

Power / energy (mJ) I(H+)/(I(H35Cl+)+I(H37Cl+)) F<-<-X, HCl, v´=0 J´=9 J´=8 J´=7

H HCl bgrH bgrHCl I(H+) I(HCl+) 0, , , , , ,007753I(H+)/(I(H+)+I(HCl+)) v´=1; J´= \\heima.rhi.hi.is\agust\My Documents\rannsóknir\REMPI\HCl\HCl,agust07-\excel files\HClmassF vhw-ak.xls

v´=0 I(H+)/(I(H35Cl+)+I(H37Cl+)) v´=1 I(H+)/(I(H35Cl+)+I(H+)) v´=1, J=6 V´=1, J=8 v´=0, J=7,8,9 From HClmassF vhw-ak.xls Power / energy (mJ)

v´=1 : : v´=1 v´=0 I(H+)/(I(H35Cl+)+I(H37Cl+)) v´=1 I(H+)/(I(H35Cl+)+I(H+)) v´=1, J=6 V´=1, J=8 v´=0, J=7,8,9 From HClmassF vhw-ak.xls Power / energy (mJ) Datapoints for v´=1, J´= 4-9 from next slide (no 5)

pnt J´= 4 J´= 5 J´= 6 J´= 7 J´= 8 J´= 9 H 35 Cl + 35 Cl + H+H+ J´= See: 4

Comment / conclusion: The ratio I(H+)/(I(H35Cl+)+I(H+)) is: 1)-Slightly larger for v´=1 compared to v´=0 for J´=4-7 (v´=1) 2)-much larger for J´=8, v´=1, where F V coupling is observed