ElectroChem Inc. PEM Fuel Cell with Dead-ended Operation Radha Jalan, Ph.D. President and CEO ElectroChem, Inc 400 W. Cummings Park Woburn, MA USA Presented at ICEPS-2008 November 27 th
ElectroChem Inc. A Brief History 1986 ElectroChem founded 1992 First to develop and sell a portable fuel cell system 1993 First to develop computerized test equipment 1995 First fuel cell company to be online : First to develop a test station for 5 independent cells testing 2005 Received Massachusetts High Tech All Star Energy Award
ElectroChem Inc. The Company A leading company working in the area of Energy Storage, Hydrogen Generation and Fuel Cells 40 years of experience in developing new technologies for NASA, DOE, DOD, and EPRI Over 20 years of experience in developing, manufacturing and selling fuel cell products to researchers around the world A vision of a future where a sustainable global economy resides in harmony with a clean, healthy environment
ElectroChem Inc. ECcell TM Energy Storage System a Regenerative System
ElectroChem Inc. Electrolyzer Based Home Hydrogen Refueling (HHR) System
ElectroChem Inc. Research Objectives Develop Passive PEM fuel cells - No moving parts - Dead-ended operation Develop PEM fuel cells for zero-gravity operation
ElectroChem Inc. Dead-ended Operation (I) Dead-ended operation is not considered in a Reformate fuel cell When pure H 2 is used as fuel, Dead-ended operation can be applied to H 2 side of a fuel cell Oxidant Air Fuel H 2, CO, CO 2 Oxidant Air Fuel H 2
ElectroChem Inc. Dead-ended Operation (II) When pure O 2 is used as an oxidant, It is considered to have an O 2 Dead-ended operation - High energy efficiency - Safety concerns But There is a challenge to remove the product water while running an O 2 Dead-ended operation fuel cell Oxidant O 2 Fuel H 2
ElectroChem Inc. Product Water Removal Water is produced on the O 2 /Air side of fuel cells Dead-ended operation Porous flow channel Water is transported by wicking effect ElectroChem MEA Open-ended operation Open flow channel Water is carried away by high air flow Conventional MEA
ElectroChem Inc. Fuel Cell Test Parameters Fuel cell size : 50 cm 2 Operation condition: - 75 o C, 30 psig (H 2 /O 2 ) mA/cm 2 Test parameters - operate fuel cell at one stoic of reactant gas - change the orientation of the fuel cel l
ElectroChem Inc. Cell Stability operate fuel cells at one stoic of reactant gas Demonstrates very stable performance at low excess gas conditions
ElectroChem Inc. Zero-Gravity Evaluation
ElectroChem Inc. Orientation Independence (I) No significant effect due to changing of orientations 0o0o H2H2 O2O2 90 o O 2 electrode
ElectroChem Inc. Orientation Independence (II) Product water can be moved upward against gravity 180 o
ElectroChem Inc. Orientation Independence (III) 270 o O 2 electrode 90 o O 2 electrode No significant effect due to changing of orientations
ElectroChem Inc. Comparative Cell Performance Porous flow field provides an advantage: The elimination of mass transfer limit
ElectroChem Inc. Conclusions Fuel cell with open channel demonstrates higher performance than the conventional flow channel cell – better reactant gas transport The cell demonstrates Stable Operation at Extremely Low Excess Oxygen Flow Rates - Enabling Passive Operation The cell demonstrates no effects of Change in Orientation on performance - Potential for “Zero-G” Water Removal
ElectroChem Inc. Acknowledgement This work was funded by NASA under Contract NNJ06JD71C