Average Composition of the Troposphere Gas Name Formula Abundance (%) Residence time (approx) Nitrogen N %42,000,000 years Oxygen O %5,000 years *Water H 2 O 0 to 4%10 days Argon Ar 0.93%~Infinite *Carbon Dioxide CO %4 years Neon Ne %~Infinite Helium He %~Infinite *Methane CH %10 years Hydrogen H %3 years *Nitrous Oxide N 2 O %170 years *Ozone O %20 days *variable gases

EVOLUTION OF THE ATMOSPHERE Earth thought to have formed about 4.5 billion years ago: Atmosphere probably consisted of gases then abundant in the solar system -> hydrogen and helium. Most of these gases were lost to space Over time a secondary atmosphere was formed: (Current atmosphere doesn't contain much hydrogen or helium). outgassing from cooling magma Volcanoes efflux: H 2 0, CO 2, SO 2, N 2, H 2, Cl 2 Upon cooling of this prehistoric atmosphere: Water vapor condensed and precipitated to form oceans. Some carbon dioxide dissolved in droplets also precipitated out.

Eventually anaerobic bacteria developed some 3.5 billion years ago: Could survive in the absence of oxygen. Began the conversion of carbon dioxide to oxygen while removing Carbon Dioxide which is now stored primarily in carbonate rocks. Plankton and shellfish continue this process more effeciently. As oxygen started to become abundant, some of it broke down by the sun’s radiation into atomic oxygen and eventually formed ozone. Ozone absorbed most of harmful ultraviolet radiation to make Earth suitable for life. The atmosphere we know was produced by biological processes.

Geological carbon cycle In the geological carbon cycle, carbon moves between rocks and minerals, seawater, and the atmosphere. Carbon dioxide in the atmosphere reacts with some minerals to form the mineral calcium carbonate (limestone). This mineral is then dissolved by rainwater and carried to the oceans. Once there, it can precipitate out of the ocean water, forming layers of sediment on the sea floor. As the Earth’s plates move, through the processes of plate tectonics, these sediments are subducted underneath the continents. Under the great heat and pressure far below the Earth’s surface, the limestone melts and reacts with other minerals, releasing carbon dioxide. The carbon dioxide is then re-emitted into the atmosphere through volcanic eruptions. (Illustration by Robert Simmon, NASA GSFC) Slow time scale - controls atmospheric carbon dioxide on time scales of hundreds of millions of years

Biological/Physical carbon cycle - shorter than geologic cycle Land plants ~ 50 years atmosphere ~ 4 years soils ~ 25 years Fossil fuels ~ 650 years oceans ~ 100s to 1000s years carbonates ~ 150 years

Addition of O 2 to the Atmosphere Today, the atmosphere is ~21% free oxygen. How did oxygen reach these levels in the atmosphere? Revisit the oxygen cycle: * Oxygen Production o Photochemical dissociation - breakup of water molecules by ultraviolet + Produced O 2 levels approx. 1-2% current levels + At these levels O 3 (Ozone) can form to shield Earth surface from UV o Photosynthesis - CO 2 + H 2 O + sunlight = organic compounds + O 2 - produced by cyanobacteria, and eventually higher plants - supplied the rest of O 2 to atmosphere. Thus plant populations-> * Oxygen Consumers o Chemical Weathering - through oxidation of surface materials (early consumer) o Animal Respiration (much later) o Burning of Fossil Fuels (much, much later) Throughout the Archean there was little to no free oxygen in the atmosphere (<1% of presence levels). What little was produced by cyanobacteria, was probably consumed by the weathering process. Once rocks at the surface were sufficiently oxidized, more oxygen could remain free in the atmosphere. During the Proterozoic the amount of free O 2 in the atmosphere rose from %. Most of this was released by cyanobacteria, which increase in abundance in the fossil record 2.3 Ga. Present levels of O 2 were probably not achieved until ~400 Ma.

Vertical structure of atmospheric pressure

Atmospheric temperature: vertical structure

Vertical structure as a function of latitude

Venus Mars

The Ocean: composition Dissolved salts comprise 3.5% by volume of sea water Originate from weathered rocks, volcanic, and atmosperic sources Composition of sea water remarkably uniform and constant over time

Density of ocean water varies by < 7%

Variations of density as a function of salinity and temperature

Vertical structure of ocean in different latitudes