Chapter 7-1Chemistry 120 Online LA Tech Chapter 7 Gases, Liquids, and Solids.

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Presentation transcript:

Chapter 7-1Chemistry 120 Online LA Tech Chapter 7 Gases, Liquids, and Solids

Chapter 7-2Chemistry 120 Online LA Tech © Steven Fuller/Peter Arnold, Inc. Gases, Liquids, and Solids → CO 7.1 Ice, water, and mist are simultaneously present in this winter scene in Yellowstone National Park.

Chapter 7-3Chemistry 120 Online LA Tech ← Fig. 7.1 The water in the lake behind the dam has potential energy as a result of its position. Hydro-power from potential energy Betty Weiser/Photo Researchers

Chapter 7-4Chemistry 120 Online LA Tech Kinetic Energy and Collisions Fig. 7.2 Upon release, the steel ball on the left transmits its kinetic energy through a series of elastic collisions to the ball on the right.

Chapter 7-5Chemistry 120 Online LA Tech Table 7.1 Properties of Gases, Liquids, and Solids

Chapter 7-6Chemistry 120 Online LA Tech Fig. 7.3 (a) In a solid, the particles are close together. (b) In a liquid, the particles slide freely over one another. (c) In a gas, the particles are in random motion. Arrangement of Particles in three States

Chapter 7-7Chemistry 120 Online LA Tech Gases in random motion → Fig. 7.4 Gas molecules can be compared to billiard balls in random motion, bouncing off one another.

Chapter 7-8Chemistry 120 Online LA Tech Popping into different states Phil Degginger/Color-Pic  CC 7.1

Chapter 7-9Chemistry 120 Online LA Tech Compressibility of gases → Fig. 7.5 When a gas is compressed, the amount of empty space in the container is decreased.

Chapter 7-10Chemistry 120 Online LA Tech ← Fig. 7.6 The essential components of a mercury barometer are a graduated glass tube, a glass dish, and liquid mercury. Barometer: Measuring the Pressure of gases

Chapter 7-11Chemistry 120 Online LA Tech Boyle and the gas Laws → Fig. 7.7 Robert Boyle was self- taught. Through his efforts, the true value of experimental investigation was first recognized. Edgar Fahs Smith Collection, University of Pennsylvania

Chapter 7-12Chemistry 120 Online LA Tech ← Fig. 7.8 Data illustrating the inverse proportionality associated with Boyle’s law. Boyles’ Law:

Chapter 7-13Chemistry 120 Online LA Tech Charles Law Fig. 7.9 When the volume of a gas at constant temperature decreases by half, the average number of times a molecule hits the container walls is doubled.

Chapter 7-14Chemistry 120 Online LA Tech ← Fig Filling a syringe with a liquid is an application of Boyle’s law. Application of Boyle’s Law

Chapter 7-15Chemistry 120 Online LA Tech Charles and gas laws → Fig Jacques Charles in the process of working with hot- air balloons made the observations that led to the formulation of what is now known as Charles’s law. Edgar Fahs Smith Collection, University of Pennsylvania

Chapter 7-16Chemistry 120 Online LA Tech ← Fig Data illustrating the direct proportionality associated with Charles’s law. Charles Law

Chapter 7-17Chemistry 120 Online LA Tech Dalton and the Partial Pressure → Fig John Dalton had an interest in the study of weather.

Chapter 7-18Chemistry 120 Online LA Tech Fig A set of four containers can be used to illustrate Dalton’s law of partial pressures. The pressure in the fourth container equals the sum of the first three. Dalton’s law of partial pressures

Chapter 7-19Chemistry 120 Online LA Tech Blood gases and their solubilty  CC 7.2

Chapter 7-20Chemistry 120 Online LA Tech Summary of gas laws  CAG 7.1

Chapter 7-21Chemistry 120 Online LA Tech Changes of states → Fig There are six changes of state possible for substances.

Chapter 7-22Chemistry 120 Online LA Tech Sublimation of Iodine (a) The beaker contains iodine crystals. (b) Iodine has an appreciable vapor pressure even below its melting point. Fig. 7.15

Chapter 7-23Chemistry 120 Online LA Tech Vapor pressure and equilibrium Fig (a) the liquid level drops for a time, (b) then becomes constant. At that point a state of equilibrium has been reached in which (c) the rate of evaporation equals the rate of condensations.

Chapter 7-24Chemistry 120 Online LA Tech Boiling point of liquids → Fig Bubbles of vapor form within a liquid when the temperature of the liquid reaches the liquid’s boiling point.

Chapter 7-25Chemistry 120 Online LA Tech ← Fig The converse of the pressure cooker “phenomenon” is that food cooks more slowly at reduced pressure. How you cook? Low or high pressure Brian Bailey/Network Aspen

Chapter 7-26Chemistry 120 Online LA Tech Intermolecular forces: Dipole-dipole → Fig There are many dipole- dipole interactions possible between randomly arranged CIF molecules.

Chapter 7-27Chemistry 120 Online LA Tech Vapor pressure and the temperature Table 7.2

Chapter 7-28Chemistry 120 Online LA Tech Pressure cooker: how does it work? Table 7.4

Chapter 7-29Chemistry 120 Online LA Tech Boiling point and Eelvation Table 7.3

Chapter 7-30Chemistry 120 Online LA Tech ← Fig Depiction of hydrogen bonding among the water molecules. Strongest intermolecular force: The hydrogen bonding

Chapter 7-31Chemistry 120 Online LA Tech Three types of hydrogen bonding → Fig Diagrams of hydrogen bonding involving selected simple molecules.

Chapter 7-32Chemistry 120 Online LA Tech Hydrogen bonding in ice  CC 7.3

Chapter 7-33Chemistry 120 Online LA Tech ← Fig If there were no hydrogen bonding between water molecules, the boiling point of water would be approximately -80C. How does hydrogen bonding affect properties

Chapter 7-34Chemistry 120 Online LA Tech London Dispersion Forces: → Fig Nonpolar molecules can develop instantaneous dipoles and induced dipoles.

Chapter 7-35Chemistry 120 Online LA Tech Summary of intermolecular forces  CAG 7.2