OVERVIEW Introduction (myself, project) Microwave plasma system P&ID (Paschen curves) Macroscopic description of the microwave plasma Timeline Non-Thermal Plasma – WP3 –
INTRODUCTION Non-Thermal Plasma – WP3 –
INTRODUCTION OBJECTIVE Develop a prototype solution of direct chemically efficient CO2 to methanol process enabled by non- thermal microwave plasma catalysis. TASK 1-WP3 (Delivery time - 15 months) Development of a small scale plasma (catalytic) reactor integrated with analytical spectroscopic probes for on-line collection of local chemistry data. Non-Thermal Plasma – WP3 –
INTRODUCTION METHODOLOGY Experiments using bench scale microwave plasma setups. Parametric study (Power, Flow rates and Inlet composition). Data Collection with advanced analytical tools, modeling and design and development of scalable equipment. Non-Thermal Plasma – WP3 –
INTRODUCTION GAS PHASE PLASMA-ASSISTED REACTIONS: CAMERE process (2 steps) Reverse Water Gas Shift Reaction (RWGS): 1. CO 2 + H 2 CO + H 2 O v ( Δ H = 41 KJ/g mol) 2. CO + H 2 CH 3 OH ( Δ H = - 92 KJ/g mol) (Production of methanol and other fuels) Non-Thermal Plasma – WP3 –
EXPERIMENTAL SET-UP Non-Thermal Plasma – WP3 –
MICROWAVE PLASMA SYSTEM EXPERIMENTAL SET-UP: MINIFLOW 200SS Non-Thermal Plasma – WP3 –
MICROWAVE PLASMA SYSTEM EXPERIMENTAL SET-UP: SURFATRON Non-Thermal Plasma – WP3 –
MICROWAVE PLASMA SYSTEM EXPERIMENTAL SET-UP: NEW WAVEGUIDE CONFIGURATION Non-Thermal Plasma – WP3 –
MICROWAVE PLASMA SYSTEM EXPERIMENTAL SET-UP: Non-Thermal Plasma – WP3 –
MICROWAVE PLASMA SYSTEM EXPERIMENTAL SET-UP: OPTICAL EMISSION SPECTROMETER Non-Thermal Plasma – WP3 – Identification of the active species in the plasma zone by measuring emission in a certain wavelength range.
GAS ANALYSIS Non-Thermal Plasma – WP3 –
MICROWAVE PLASMA SYSTEM EXPERIMENTAL SET-UP: FOURIER TRANSFORM INFRARED SPECTROMETER Non-Thermal Plasma – WP3 – Probe the catalytic surface chemistry (identification of formed bands) by measuring how much of a shinned beam is absorbed by the sample.
MICROWAVE PLASMA SYSTEM EXPERIMENTAL SET-UP: MASS SPECTROMETER Non-Thermal Plasma – WP3 – Identification of ionized species (CO, O 2, CO 2, Ar, H 2 ) present in the plasma zone. Low-pressure requirements.
P&ID Non-Thermal Plasma – WP3 –
P&ID Plasma ignition Non-Thermal Plasma – WP3 –
PASCHEN CURVES Non-Thermal Plasma – WP3 –
MACROSCOPIC DESCRIPTION Non-Thermal Plasma – WP3 –
MACROSCOPIC DESCRIPTION OF THE MICROWAVE PLASMA TEMPERATURE PROFILE (Surfatron Body) Non-Thermal Plasma – WP3 – Finite difference method
MACROSCOPY DESCRIPTION OF THE MICROWAVE PLASMA TEMPERATURE PROFILE (Discharge tube after ignition) Non-Thermal Plasma – WP3 –
TIMELINE Non-Thermal Plasma – WP3 –
TIMELINE July December 2013 Improvement P&ID (connections, control system, product analysis) Safety report Equipment (EOS, MS, FTIR, Thermo-camera) Design a new and more adaptable waveguide configuration Labview as a controlling and programming tool Explore different ways to feed the gases into the reactor (swirl gas) Design a catalyst for gas phase plasma-assisted reactions (monolith) January March 2014 Data generation Non-Thermal Plasma – WP3 –