Storage ring measurements of the dissociative recombination of H 3 + : a closer look Holger Kreckel University of Illinois at Urbana-Champaign Kyle N.

Slides:



Advertisements
Similar presentations
Visible transitions from ground-state H 3 + and their Einstein-B coefficients measured with high-sensitivity action spectroscopy Dr. Annemieke Petrignani.
Advertisements

Mats Larsson Stockholm University. Oka 1999 The 2001 year crisis The clouds are dispersing Outstanding questions Outlook.
Dissociative Recombination of Cold H 3 + and its Interstellar Implications  T. Oka (University of Chicago), T. R. Geballe (Gemini Observatory)  A. J.
Laboratory Measurements of Primordial Chemistry. Daniel Wolf Savin Columbia Astrophysics Laboratory Xavier Urbain Université catholique de Louvain.
Implications of the H H 2  H 2 + H 3 + reaction for the ortho- to para-H 3 + ratio in interstellar clouds Kyle N. Crabtree, Lt. Col. Brian A. Tom,
Martin Freer (Matthew Barr) School of Physics and Astronomy, University of Birmingham, UK On Behalf of: R3B, Birmingham, LPC……… Correlations at the limits.
23 June Performance of a Continuous Supersonic Expansion Discharge Source Evaluated by Laser-Induced Fluorescence Spectroscopy.
MODELING OF H 2 PRODUCTION IN Ar/NH 3 MICRODISCHARGES Ramesh A. Arakoni a), Ananth N. Bhoj b), and Mark J. Kushner c) a) Dept. Aerospace Engr, University.
Benjamin McCall and Takeshi Oka University of Chicago Kenneth H. Hinkle National Optical Astronomy Observatories Thomas R. Geballe Joint Astronomy Centre.
The Non-Thermal Rotational Distribution of Interstellar H 3 + (ApJ, in press ) Takeshi Oka and Erik Epp, Department of Astronomy and Astrophysics, and.
Galactic Center Region Concentrated stars and interstellar matter High Energy Density (gravity, MHD, kinetic) Strong magnetic field :B ~ mG High external.
Hot and Diffuse Gas near the Galactic Center Probed by Metastable H 3 + Thomas R. Geballe Gemini Observatory Miwa Goto Max Planck Institute for Astronomy.
Laboratory spectroscopy of H3+
Physics, Chemistry and Astronomy of H 3 + Royal Society Discussion Meeting And the Satellite Meeting January 16-18, 2006.
Towards High Resolution Cavity Enhanced Spectroscopy with Fast ion Beams Andrew Mills, Brian Siller, Manori Perera, Holger Kreckel, Ben McCall.
Progress in measurements of dissociative recombination CRP on Atomic and Molecular Data for Plasma Modelling Mats Larsson Department of Physics Stockholm.
Laboratory for Optical Physics and Engineering CO + and C 2 Spectra Generated by CO 2 Atmospheric Pressure Glow Discharge in MicroChannels Chul Shin, Thomas.
Measuring DR cross sections Absolute recombination rate coefficients of tungsten ions from storage-ring experiments Stefan.
Storage ring measurements of the Dissociative Recombination of H 3 + : a closer look Holger Kreckel University of Illinois at Urbana-Champaign A fundamental.
Holger Kreckel, Andrew Mills, Manori Perera, Brian Siller, Kyle Crabtree, Carrie Kauffman, Benjamin J. McCall University of Illinois at Urbana-Champaign.
Nuclear Astrophysics with the PJ Woods, University of Edinburgh.
Experimental cross sections for electron-impact ionization and electron-ion recombination Research Coordination Meeting, IAEA CRP, Vienna, September.
Nuclear dynamics in the dissociative recombination of H 3 + and its isotopologues Daniel Zajfman Max-Planck-Institut für Kernphysik and Weizmann Institute.
Kinetic Processes in Recombining H 3 + plasmas Rainer Johnsen University of Pittsburgh THEO MURPHY INTERNATIONAL SCIENTIFIC MEETING ON Chemistry, astronomy.
Determination of fundamental constants using laser cooled molecular ions.
Spectroscopic Studies of the H H 2 Reaction at Astrophysically Relevant Temperatures Brian A. Tom, Brett A. McGuire, Lauren E. Moore, Thomas J. Wood,
Forschergruppe Laboratory Astrophysics Interstellar Molecules.
Instrumentation in the Molecular Physics Group Presented by: Mats Larsson.
H 3 + : A Case Study for the Importance of Molecular Laboratory Astrophysics Ben McCall Dept. of ChemistryDept. of Astronomy.
New Laboratory and Theoretical Studies of Astrophysically Important Reactions of H 3 + Ben McCall Dept. of ChemistryDept. of Astronomy.
T. Oka, PRL 45,531 (1980) What is H 3 + ?  2y 2x  Equilateral triangle structure  Simplest stable polyatomic molecule  No stable excited electronic.
Dynamics in Solid Hydrogen below 4 K David T. Anderson Department of Chemistry, University of Wyoming Laramie, WY th International.
A Search for the 8.5  m Vibrational Spectrum of C 60 in the Laboratory and Space Susanna L. Widicus Weaver 1, Brian E. Brumfield 1, Andrew A. Mills 1,
Pulsed-jet discharge matrix isolation and computational study of Bromine atom complexes: Br---BrXCH 2 (X=H,Cl,Br) OSU 66 th International Symposium on.
The REXTRAP Penning Trap Pierre Delahaye, CERN/ISOLDE Friedhelm Ames, Pierre Delahaye, Fredrik Wenander and the REXISOLDE collaboration TAS workshop, LPC.
Breaking the Symmetry in Methyl Radical: High resolution IR spectroscopy of CH 2 D Melanie Roberts Department of Chemistry and Biochemistry, JILA University.
Electron-impact rotational excitation of H 3 + : relevance for thermalization and dissociation Alexandre Faure* Laurent Wiesenfeld* & Jonathan Tennyson.
High Precision, Sensitive, Near-IR Spectroscopy in a Fast Ion Beam Michael Porambo, Holger Kreckel, Andrew Mills, Manori Perera, Brian Siller, Benjamin.
November 6, 2010 MWAM 2010 University of Illinois1 The ortho:para ratio of H 3 + in diffuse molecular clouds Kyle N. Crabtree, Nick Indriolo, Holger Kreckel,
FLAIR meeting, GSI March Positron Ring for Antihydrogen Production A.Sidorin for LEPTA collaboration JINR, Dubna.
PROGRESS & RESULTS IN THE DEVELOPMENTS OF THE SENSITIVE, COOLED, RESOLVED ION BEAM SPECTROMETER (SCRIBES) Andrew Mills, Brian Siller, Michael Porambo,
Daniel Zajfman Max-Planck Institute for Nuclear Physics Heidelberg, Germany and Weizmann Institute of Science Rehovot, Israel Physics with Colder Molecular.
Theoretical study of ion-pair formation in electron recombination with H 3 + Royal Society Discussion meeting on Physics, Chemistry and Astronomy of H.
Copyright All rights reserved. June 25, 2015ISMS, 2015
Electron-molecule collisions in harsh astronomical environments Alexandre Faure 1 & Jonathan Tennyson 2 1 Université de Grenoble / CNRS, France 2 University.
Chemical Probing Spectroscopy of H 3 + above the barrier to linearity Holger Kreckel* Max-Planck-Institut für Kernphysik, Heidelberg, Germany * Present.
Observation Of Nuclear Spin Selection Rules In Supersonically Expanding Plasmas Containing H 3 + Brian Tom, Michael Wiczer, Andrew Mills, Kyle Crabtree,
Photoelectron Imaging of Vibrational Autodetachment from Nitromethane Anions Chris L. Adams, Holger Schneider, J. Mathias Weber JILA, University of Colorado,
The Influence of Free-Running FP- QCL Frequency Jitter on Cavity Ringdown Spectroscopy of C 60 Brian E. Brumfield* Jacob T. Stewart* Matt D. Escarra**
1 Ultracolod Photoelectron Beams for ion storage rings CSR E-Cooler TSR (magnetic) e-target e-cooler CSR (electrostatic) E lab : eV Current -
D. Zhao, K.D. Doney, H. Linnartz Sackler Laboratory for Astrophysics, Leiden Observatory, University of Leiden, the Netherlands T he 3 μm Infrared Spectra.
The low-temperature nuclear spin equilibrium of H 3 + in collisions with H 2 Kyle N. Crabtree, * Benjamin J. McCall University of Illinois, Urbana, IL.
Superfluid effects in para-H 2 clusters probed by CO 2 rotation-vibration transitions Hui Li, Robert J. LeRoy, Pierre-Nicolas Roy Department of Chemistry.
Sub-Doppler Jet-Cooled Infrared Spectroscopy of ND 2 H 2 + and ND 3 H + in NH Stretch Fundamental Modes Astronomical Molecular Spectroscopy in the Age.
Modeling the influence of nuclear spin in the reaction of H 3 + with H 2 Kyle N. Crabtree, Brian A. Tom, and Benjamin J. McCall University of Illinois.
Sequential Bond Dissociation Energies of Fe + (CO 2 ) n (n = 1-5) Meghan MacKenna*, Hideya Koizumi, and P.B. Armentrout Department of Chemistry, University.
Initial Development of High Precision, High Resolution Ion Beam Spectrometer in the Near- Infrared Michael Porambo, Brian Siller, Andrew Mills, Manori.
SCRIBES Sensitive Cooled Resolved Ion BEam Spectroscopy
Precision Tests of Fundamental Interactions with Ion Trap Experiments
The Performance Of A Continuous Supersonic Expansion Discharge Source
The Performance Of A Continuous Supersonic Expansion Discharge Source
Nuclear Spin Dependence of the Reaction of H3+ with H2
Is HO2+ a Detectable Interstellar Molecule?
The H3+ + H2 Reaction; A Possible Mechanism for para- H3+ Enrichment in the Diffuse Interstellar Medium Lieutenant Colonel Brian A. Tom, USAF University.
Institut de Physique de Rennes, Université de Rennes I, Rennes
Tokyo Univ. Science Mitsunori Araki, Yuki Matsushita, Koichi Tsukiyama
Spectroscopic measurements of the reaction H3+ + H2  H2 + H3+
Investigating the Cosmic-Ray Ionization Rate in the Galactic Interstellar Medium through Observations of H3+ Nick Indriolo,1 Ben McCall,1 Tom Geballe,2.
Nuclear spin of H3+ in diffuse molecular clouds
Stepwise Internal Energy Control for Protonated Methanol Clusters
Presentation transcript:

Storage ring measurements of the dissociative recombination of H 3 + : a closer look Holger Kreckel University of Illinois at Urbana-Champaign Kyle N. Crabtree Brian A. Tom Benjamin J. McCall Oldřich Novotny* Annemieke Petrignani Max H. Berg Dennis Bing Manfred Grieser Claude Krantz Michael Lestinsky* Mario B. Mendes Christian Nordhorn Roland Repnow Julia Stützel Andreas Wolf TSR Group University of Illinois Richard Thomas Stockholm University Henrik Buhr Weizmann Institute *Columbia University, NY

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look H He CN O Ne Mg Fe SiSAr The relevance of H 3 + : astronomer‘s periodic table

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look The relevance of H 3 + : engine of interstellar chemistry H 3 + formation H 2 + c.r. H e - H H 2 H H Proton-hop reactions H X XH + +H 2

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Steady State: [H 3 + ]  = keke [e - ] [H 2 ] The enigma of H 3 + in diffuse clouds Cosmic ray ionization rate DR rate coefficient

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look year “Perceived” H 3 + DR rate coefficient Glosik et al.( ) Stat. & flow. afterglow Adams, Smith, Alge(1984 ) Flow. afterglow Adams, Smith (1987 ) Flow. afterglow Amano (1988 ) IR spectroscopy Larsson et al. (1993 ) Storage ring McCall et al. (2003 ) Storage ring Kreckel et al. (2005 ) Storage ring Leu, Biondi, Johnsen (1973 ) Stat. afterglow H 3 + DR rate coefficient at 300K

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Storage ring measurements: concept radiative relaxation of internal excitations (rotation, vibration) direct measurement 100% detection efficiency high resolution Advantages Problem H 3 + ! radiative relaxation incomplete

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look (1,0 0 ) theory (2,0 0 ) theory experimental data (T < 1ms) experimental data (T > 2s) (0,0 0 ) theory Coulomb explosion results H 3 + Kreckel et al., PRA 66, (2002) Vibrations decay within the first 2s of storage Some rotational states stay forever

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look H2H2 Gas inlet 2 atm Solenoid valve -900 V ring electrode Pinhole flange/ground electrode H3+H3+ “Cold” ion sources Supersonic expansion CRYRING cm Cryogenic ion trap TSR 2004

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look ● TSR electron temp. kT ┴ =0.5 meV ~ 6K kT || =25 μeV trap temp. 13 K Kreckel, PRL 95, (2005) ● CRYRING kT ┴ = 2 meV ion temp K McCall, Nature 422, 500 (2003) Storage ring results with “cold” H 3 + ion sources Theory Kokoouline and Greene

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look + ortho I = 3/2 para I = 1/2 + The holy grail: state specific measurements H 3 + rotational levels

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Nuclear spin effect: exp. and theory 2005 ۰para H 2 ۰normal H 2 experiment kT ┴ =4 meV theory Greene et al. - para - ortho Kreckel et. al, PRL 95, (2005)

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Theory with more accurate resonance energies S. Fonseca dos Santos et al., JCP 127,

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Quantifying nuclear spin effects B. Tom et al., JCP 130, Reduced rate coeff.

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look skimmer discharge electrode pinhole plunger piezo actuator locking nut 6 cm high pressure H 2 reservoir low pressure Piezo expansion source

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Cavity ring down measurements at UIUC Difference frequency generation: 3.67 μm

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Transitions observed HG

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Rotational temperature pure H 2 discharge, 2bar T rot =110 K 1:5 H 2 :Argon discharge, 2bar T rot =180 K No vibrations found!

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Nuclear spin manipulation 1:5 n-H2 : Argon mixture p-H 3 + fraction p 3 = (47.9 ± 2) % 1:5 p-H2 : Argon mixture p-H 3 + fraction p 3 = (70.8 ± 2) % ortho H 3 + para H 3 +

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look UI Champaign-Urbana MPI-K Heidelberg DR measurements at TSR T est S torage R ing

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Absolute scale of the rate coefficient electron beam switched off electron target length storage ring circumference electron density

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Comparison to CRYRING 2002 CRYRING 2002 (n-H 2 ) TSR 2009 (n-H 2 :Ar 1:5)

1 m DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look H e - beam vel. Rotational temperature: imaging basics d 2-dimensional imaging, point source P(D) 3-dimensional imaging, point source d ~ √E k 2-dimensional imaging, extended source δtδt detector

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look 2-dimensional imaging of the 3-body breakup H e - H + H + H n e (cooler) = 1.4 x 10 7 cm -3 n e (target) = 1.34 x 10 6 cm -3 expected KER = 4.79 eV

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look 2-dimensional imaging of the 3-body breakup 950 K 450 K 200 K rotational temperatures (uncertainties ~ 200 K) H e - H + H + H

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Piezo source extraction potentials

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Conditions on-axis downstream of the nozzle Collisional heating during Ion extraction? skimmer

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Detailed comparison of the (reduced) rate coefficient TSR / 22-pole trap 2007 CRYRING / Solenoid 2002 TSR / piezo 2009

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Nuclear spin dependence of the rate coefficient 1:5 n-H2 : Argon mixture 1:5 p-H2 : Argon mixture p 3 = (47.9 ± 2) % p 3 = (70.8 ± 2) % Extrapolation: 100% ortho H % para H 3 + Reduced rate coeff.

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Summary While we measure a rotational temperature of 200K with CRD spectroscopy, the stored H 3 + ions are much hotter than the ion source. We observed clear differences between different ion sources → the heating is probably happening prior to injection into the ring. We observed for the first time detailed structures in the rate coefficients for ortho-H 3 + and para-H 3 + at low energies. The holy grail? Still out there … Results: Kreckel et al., submitted to PRA Petrignani et al., in preparation

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Perspectives: the case to continue the quest Kyle N. Crabtree et al., to be published It is crucial to understand: H H 2 and H 3 + (J=1,K=0,1) + e -

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look Collaboration Kyle N. Crabtree Brian A. Tom Benjamin J. McCall Oldřich Novotny* Annemieke Petrignani Max H. Berg Dennis Bing Manfred Grieser Claude Krantz Michael Lestinsky* Mario B. Mendes Christian Nordhorn Roland Repnow Julia Stützel Andreas Wolf TSR Group University of Illinois Richard Thomas Stockholm University Henrik Buhr Weizmann Institute *Columbia University, NY Funding: National Science Foundation Max-Planck Society German-Israeli Foundation Eurppean Comission

DR 2010, Lake Tahoe, Aug 19th 2010 Holger Kreckel Storage ring measurements … of H 3 + : a closer look