8/29/20151 Collier County Public Schools Florida Right-to-Know Law OSHA Hazardous Communication

8/29/20152

3 Florida-Right-To-Know Chapter 442 Hazardous Communication Title 29 CFR

8/29/20154 What is the Florida Right-To-Know Law? Alike in meaning to the OSHA Hazcom standard Written to protect the community Written to protect workers

8/29/20155 The Government Regulation Requires: That companies research their products to determine their hazards That chemical manufacturers provide detailed information about their chemicals to their customers That chemical manufacturers provide warning labels for the chemicals they produce Employers train the people who handle or are exposed to chemicals about their hazards

8/29/20156 The Government Regulation Requires: Employers maintain a chemical exposure plan to protect employees from the chemicals in the workplace

8/29/20157 What is a Chemical Exposure Plan? Provides employees with updated, completed MSDS’s (Material Safety Data Sheets) Makes sure all containers and secondary containers are labeled as to their contents Makes sure that Personal Protective Equipment is provided to employees at no cost

8/29/20158 What is a Chemical Exposure Plan? Makes sure that training is done annually or as needed Gives chemical information / location to local fire and emergency personnel Names individuals responsible for maintaining written program/MSDS’s

8/29/20159 What is an MSDS? An MSDS is a detailed instruction sheet which describes each chemical in your workplace.

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8/29/ MSDS’s Usually Contain 9 Sections Even though chemical manufacturers can write their MSDS’s in any format the information is generally set up in the 9 section format

8/29/ MSDS Sections Section I - Material IdentificationSection I - Material Identification Section II - Hazardous IngredientsSection II - Hazardous Ingredients Section III - Physical DataSection III - Physical Data Section IV - Fire and Explosion DataSection IV - Fire and Explosion Data Section V - Health Hazard InformationSection V - Health Hazard Information Section VI - Reactivity DataSection VI - Reactivity Data

8/29/ MSDS Sections Section VII - Spill or Leak ProceduresSection VII - Spill or Leak Procedures Section VIII - Special Protection InformationSection VIII - Special Protection Information Section IX - Special PrecautionsSection IX - Special Precautions

8/29/ Material Identification Identifies the chemical manufacturer, emergency phone number, address, the chemical name, trade name, chemical family and chemical formula Manufacturer’s Name Emergency Telephone Number XYZ Manufacturer (000) Address 555 S. 5th St. Naples, FL Chemical Name and Synonyms Trade Name and Synonyms Isopropyl Alcohol IPA Isopropanol Chemical Family Formula Alcohol CH3CH0HCCH3

8/29/ Hazardous Ingredients Lists all the parts of a chemical mixture Lists % of a chemical in the mixture Lists what the allowable exposure limit is (TLV) Section II - Hazardous Ingredients Paint, Preservatives & Solvents % TLV Alloys and Metallic % TLV PigmentsN/ABase Metal N/A CatalystN/AAlloys N/A VehicleN/AMetal Coatings N/A SolventsIPA Filler Metal N/A AdditivesN/AOther Others Hazardous Mixtures of Other Liquids, Solids, or Gases

8/29/ Physical Data States at what point the chemical will boil How much vapor a chemical will emit; the lower boiling point, the higher the vapor pressure States how heavy the vapors a chemical emits are compared to air States how well the chemical will combine with water

8/29/ Physical Data Compares the weight of the chemical to water States how explosive the chemical is Describes the appearance and odor of the chemical Section III - Physical Data Boiling Point (F) 1atm, deg f(c) 80 (82) Specific Gravity (h20).786 Vapor Pressure 33 Percent Volatile by volume ca100 Vapor Density (air) 2.07 Evaporation Rate 2.6 Solubility in Water Complete Appearance and Odor Clear, colorless liquid with alcohol odor

8/29/ Fire and Explosion Hazard Data States the temperature at which the chemical will ignite Gives the methods for putting out a fire caused by this chemical Lists precautions to take to prevent fire/explosion Section IV - Fire and Explosion Hazard Data Flash Point (method used) Flammable Limits LEL UEL 53 (closed cap)% by volume Extinguishing Media Carbon dioxide, dry chemical, alcohol foam Special fire fighting procedures Use water spray to cool exposed containers Use fine mist to smother fire and/or disperse vapors Unusual Fire and Explosion Hazards Moderate explosion hazard when material is exposed to heat or flames. OSHA class 1B flammable liquid

8/29/ Health Hazard Information States the maximum exposure that the body can take Describes the effects of overexposure Lists first aid procedures Section V - Health Hazard Data Threshold Limit Value 400ppm Effects of overexposure Mild irritation to the nose and throat. Eye contact will cause irritation and burning sensations. Prolonged exposure above TLV will cause carcosis, nausea, and headaches Emergency and First Aid Procedures Eye contact - flush with water for 15 minutes and get medical help. Skin contact - remove contaminated clothing and flush with water. Inhalation - move to fresh air. Ingestion - drink water and get prompt medical help.

8/29/ Reactivity Data States whether the chemical is stable or unstable Lists chemicals which cause harmful reactions Lists the conditions which should be avoided during handling or storage States whether or not the chemical will decompose into a hazardous material Section VI - Reactivity Data StabilityUnstableConditions to avoid Stable X Incompatibility (materials to avoid) Acetaldehyde, Ethylene Oxide and Strong Oxidizing Agents Hazardous Decomposition Products Carbon Monoxide Hazardous Polymerization May Occur Conditions to avoid: Do not use aluminum containers Will Not Occur X

8/29/ Spill or Leak Procedures States the steps to be taken in case of a leak or spill States how to dispose of waste properly States whether or not the chemical presents an environmental hazard Section VII - Spill or Leak Procedures Steps to be taken in case material is released or spilled Absorb small spills with paper towels. Contain large spills, collect or absorb them with vermiculite, spill absorbent or sand. Use water spray to dilute and flush Waste Disposal Method Do not flush to water courses or to sewer or enclosed area. Burn waste liquid in approved incinerator or dispose via licensed waste disposal company.

8/29/ Special Protection Information States whether or not respiratory protection is required States ventilation specifications Lists personal protective equipment needed while handling Section VIII - Special Protection Information Respiratory Protection (Specify type) Local Exhaust Special VentilationHoods to maintain 1pm face velocity Mechanical Other Protective Gloves Eye Protection Neoprene gloves and aprons Chemical goggles Other Protective Equipment For emergency - self contained breathing apparatus with full facepiece

8/29/ Special Precautions Lists any additional precautions that should be taken while handling or storing chemical Section IX - Special Precautions Precautions to be taken in Handling and Storing Store in cool, ventilated area, in manner for Class 1B flammable liquid. Bond and ground containers for transfer. Other Precautions Wash thoroughly after handling. Do not smoke or eat in storage or use areas.

8/29/ MSDS Binders Must be kept in an area accessible to all personnel Must contain an MSDS for every chemical kept within the work area Must be organized in a fashion so that MSDS sheets can be accessed quickly

8/29/ Labeling Labels should be immediate visual warnings on containers that hold hazardous chemicals NFPA and HMIS labels are two types of labels which provide immediate hazard warningsNFPA and HMIS labels are two types of labels which provide immediate hazard warnings

8/29/ National Fire Protection Assoc. NFPA Labels are divided into 4 parts: Health hazard, Fire hazard, Stability/Reactivity hazards and Special hazards The Numbers from 0-4 represent the degree of danger in each of the sections

8/29/ Hazardous Material Identification System HMIS labels work on the same principle as NFPA labels but an additional section lists *personal protective equipment required while handling the chemical

8/29/ Personal Protective Equipment A - Protective GlassesA - Protective Glasses B - Protective Glasses & GlovesB - Protective Glasses & Gloves C - Protective Glasses, Gloves & ApronC - Protective Glasses, Gloves & Apron D - Face Shield, Gloves & ApronD - Face Shield, Gloves & Apron E - Protective Glasses, Gloves & Vapor Filter MaskE - Protective Glasses, Gloves & Vapor Filter Mask F - Protective Glasses, Gloves, Apron & Vapor RespiratorF - Protective Glasses, Gloves, Apron & Vapor Respirator G - Protective Glasses, Gloves & Vapor RespiratorG - Protective Glasses, Gloves & Vapor Respirator H - Goggles, Gloves, Apron, & Vapor RespiratorH - Goggles, Gloves, Apron, & Vapor Respirator I - Protective Glasses, Gloves & Vapor/Dust RespiratorI - Protective Glasses, Gloves & Vapor/Dust Respirator J - Goggles, Gloves, Apron & Vapor/Dust RespiratorJ - Goggles, Gloves, Apron & Vapor/Dust Respirator K - Airline Hood or Mask, Gloves, Full Body Suit, BootsK - Airline Hood or Mask, Gloves, Full Body Suit, Boots X - Consult with Supervisor for Special InstructionsX - Consult with Supervisor for Special Instructions

8/29/ Labeling Requirements Every container which contains a chemical substance (liquid, solid, gas) shall be appropriately labeled to identify what is inside This applies to secondary containers such as spray bottles, squeeze bottles, etc.

8/29/ Training Must be conducted annuallyMust be conducted annually Must be redone if the workplace changesMust be redone if the workplace changes Must be reviewed if a new chemical is introduced into the work areaMust be reviewed if a new chemical is introduced into the work area Must be done before employee is exposedMust be done before employee is exposed Participants must be evaluated to check for understandingParticipants must be evaluated to check for understanding

8/29/ POSTERS You Have a Right to Know About the Toxic Substances in Your WorkplaceYou Have a Right to Know About the Toxic Substances in Your Workplace Hazardous Materials Identification System *Hazard Index *PPE IndexHazardous Materials Identification System *Hazard Index *PPE Index

8/29/ DEFINITIONS ChemicalChemical FlashpointFlashpoint Hazardous ChemicalHazardous Chemical LabelLabel MSDSMSDS MixtureMixture WorkplaceWorkplace

8/29/ Video Understanding Hazard Communication video (10 min)Understanding Hazard Communication video (10 min)

8/29/ Quiz Right to Know / Hazard Communication Employee Training QuizRight to Know / Hazard Communication Employee Training Quiz Pass / FailPass / Fail

8/29/ Thank you for participating in this training session. Please contact the Code Enforcement & Permitting Department if you have additional questions or concerns at extension 4373