Chapter 6 Periodic Trends Trends video: http://www.cleanvideosearch.com/media/action/yt/watch?videoId=u2ogMUDBaf4

Organizing Elements Chemists used the properties of elements to sort them into groups. Mendeleev arranged the elements in his period table in order of increasing mass. In the modern periodic table, elements are arranged in order of increasing atomic mass. Periodic law stated that when the elements are arranged in order of increasing atomic number, there is a periodic separation of their physical and chemical properties.

Organizing Elements Recall Groups (Families) are the columns Periods are the row Representative elements are in groups 1A through 7A (1,2 and 13-17). They display a wide range of physical and chemical properties. the s and p sublevels of representative elements are not filled.

Organizing Elements Representative elements include Alkali Metals in group 1 or 1a Alkaline Earth in Metals group 2 or 2a Carbon Family in group 14 or 4a Nitrogen Family in group 15 or 5a Oxygen Family in group 16 or 6a Halogens in group 17 or 7a

Organizing Elements Other Families/Groups Transition Metals in groups 3-12 or 3b to 2b These elements are characterized by d orbital’s that contain electrons. Noble Gases in group 18 or 8a Have full p orbitals Lanthanide Series top row in F block Actinide Series bottom row in F block Inner transition metals include the Lanthanide and Actinide Series (bottom two rows pulled out of periodic table) These elements are characterized by f orbital’s that contain electrons.

Classes of Elements Three classes of elements are metals, nonmetals, and metalloids. Metals are good conductors of heat and electric current Are found on the left side of the periodic table Metals are solid at room temperature (except mercury). Metals are ductile (can be drawn into wires) and Malleable (hammered in to sheets) Nonmetals are poor conductors of heat and electric current. Are found on the right side of the periodic table Solid nonmetals tend to be brittle. Most are gasses at room temperature Metalloids (or semi metals) have properties similar to metals and non metals. Sit on the dark line (red on ours)

Periodic Trends Metallic Nature: as you move across a period (left to right) the elements get less metallic; as you move down a group the elements get more metallic. Francium is most metallic element. Metallic Nature DECREASES Metallic Nature INCREASES

Metallic Nature Practice List the elements in order of INCREASING metallic nature: As F Fr Hf Pd Which element is the least metallic? Ca Ga Ge Kr List the elements in order of DECREASING metallic nature: Fr Hg I Nd Pb Xe According to metallic trends what is the least metallic element on the periodic table.

Metallic Nature Practice Answers List the elements in order of INCREASING metallic nature: As F Fr Hf Pd F<As<Pd<Hf<Fr Which element is the least metallic? Ca Ga Ge Kr Krypton (Kr) List the elements in order of DECREASING metallic nature: Fr Hg I Nd Pt Xe Fr> Nb>Pt >Hg>I>Xe According to metallic trends what is the least metallic element on the periodic table. Helium

Periodic Trends Atomic Charge the charge in the nucleus of the atom Atomic mass the mass of the element Both generally increase as you move across a period and down a family Atomic Charge and mass INCREASES Atomic Charge and mas INCREASES

Periodic Trends Atomic radius is one half of the distance between the nuclei of two atoms of the same elements when the atoms are joined. In general, atomic size increases from top to bottom within a group because you are adding energy levels (shielding effect is greater) and decreases from left to right across a period because of effective nuclear charge (greater pull on electrons due to addition of proton) Atomic Radius INCREASES Atomic Radius DECREASES

What is effective nuclear charge and shielding effect? The effective nuclear charge is the net positive charge experienced by an electron in a multi-electron atom. The term "effective" is used because the shielding effect of negatively charged electrons prevents higher orbital electrons from experiencing the full nuclear charge by the repelling effect of inner-layer electrons. The shielding effect describes the decrease in attraction between an electron and the nucleus in any atom with more than one electron shell. when more electrons are involved, each electron feels not only the electromagnetic attraction from the positive nucleus, but also repulsion forces from other electrons in other shells. This causes the net force on electrons in outer shells to be significantly smaller in magnitude. Because of this these electrons are not as strongly bonded to the nucleus as electrons closer to the nucleus

Atomic Mass, Radius and Charge Practice Arrange in order of increasing atomic Radius: I In Mo Pd Sr Te Arrange in order of decreasing atomic mass: I In Mo Pd Sr Te Arrange in order of increasing atomic mass: Ac Ca Lr Pa Te Th What element has the smallest atomic radius? What element has the smallest atomic mass?

Atomic Mass, Radius and Charge Practice Answers Arrange in order of increasing atomic Radius: I In Mo Pd Sr Te I<Te<In<Pd<Mo<Sr Arrange in order of decreasing atomic mass: I In Mo Pd Sr Te I>Te>In>Pd>Mo>Sr Arrange in order of increasing atomic mass: Ac Ca Lr Pa Te Th Ca<Te<Ac<Pa<Th<Lr What element has the smallest atomic radius? Helium What element has the smallest atomic mass? Hydrogen

Periodic Trends Ions is an atom or groups of atoms that has a positive or negative charge. Positive and negative ions from when electrons are transferred between atoms. Cation is an atom or groups of atoms with a positive charge that have lost electrons. Metals form Cations Anion is an atom or groups of atoms with a negative charge that have gained electrons. Nonmetals form Anions

Group 1a forms +1 ion Group 2a forms +2 ion Group 3a forms +3 ion Group 4a can form +4 or -4 Group 5a forms -3 ion Group 6a forms -2 ion Group 7a forms -1 ion Group 8 a will not react or form ions

Ion Practice Write the ion that each of the following elements will form: Al K Br Mg Cs P Ca Rn Cl S Ga Se

Ion Practice Answers Write the ion that each of the following elements will form: Al+3 K-1 Br-1 Mg+2 Cs+1 P-3 Ca+2 Rn (no ion forms) Cl-1 S-2 Ga+3 Se-2

Periodic Trends Elements form Ions to achieve a noble gas electron configuration (a full outer shell) Full outer energy shells for MOST atoms contain 8 valance electrons. As metals lose electrons they form a positive charge (cation) and their radius shrinks The greater the charge the smaller the radius As nonmetals gain electrons they form a negative charge (anion) and their radius expands The greater the charge the larger the radius

Periodic Trends Ionic radius the radius of an atom that has formed an ion by losing or gaining electrons In general, ionic radius increases from top to bottom within a group because you are adding energy levels and decreases from left to right across a period because of the removal/addition of electrons Atomic Radius INCREASES Atomic Radius DECREASES

Ionic & Atomic Radius practice Use grater than (>) or less than (<) to show how the size of the atoms and ions are related. Na Na+1 Br-1 Ca+2 Al Al+3 S S-2 Al+3 Na+1 Al+3 P-3 Arrange in order of increasing Ionic size. . I Mg Na Rb Sr Sb

Periodic Trends Ionization energy is the energy required to remove the first electron from an atom First ionization energy tends to decrease from top to bottom within a group and increase from left to right across a period. Ionization Energy DECREASES Ionization Energy INCREASES

Periodic Trends Electronegativity is the ability of an atom of an element to attract electrons when the atom is in a compound. Electronegativity values decrease from top to bottom within a group, and values tend to increase from left to right across a period. MOST electronegativite element is Fluorine Electronegativity DECREASES Electronegativity INCREASES

Electronegativity & Ionization Energy Practice What is most Electronegative element? What is element with highest Ionization energy? Put in order of decreasing ionization energy: Cs Fr K Li Na Rb Put in order of increasing electronegativity: Al Cl Mg S P Put in order of decreasing ionization energy: Ag I In Mo Rb Y

Electronegativity & Ionization Energy Practice Answers What is most Electronegative element? Fluorine What is element with highest Ionization energy? Helium Put in order of decreasing ionization energy: Cs Fr K Li Na Rb Li> Na> K> Rb> Cs> Fr Put in order of increasing electronegativity: Al Cl Mg S P Mg< Al< P< S< Cl Put in order of decreasing ionization energy: Ag I In Mo Rb Y I> In> Mo> Y>Rb