DIOXIN MEASUREMENTS IN CANDIDATE COUNTRIES PROJECT DIOXIN MEASUREMENT IN TURKEY BACKGROUND AND CAPABILITIES Sönmez DAĞLI Environmental Engineer,MSc TUBITAK-MRC ENERGY SYSTEMS AND ENVIRONMENTAL RESEARCH INSTITUTE P.O.Box 21 Gebze-Kocaeli TURKEY

PRESENTATION PLAN 1-Who is MRC-ESERI? 2-History of Dioxin in MRC-ESERI 3-Our Capabilities 4-Main Dioxin Sources in Turkey 5-Proposed Measurement Sites in Turkey

Who is MRC-ESERI TUBITAK-The Scientific and Technical Research Council of Turkey The TUBITAK Marmara Research Center (MRC), one of the research and development (R&D) units of TUBITAK, was established in 1972. MRC 700 trained and experienced personnel, about 400 researchers. More Information www.mam.gov.tr/english/index.html

Who is MRC-ESERI TUBITAK-MRC is constituted of 5 institutes, namely: Information Technologies Research Institute Energy Systems and Environmental Research Institute Materials and Chemical Technologies Research Institute Food Science and Technology Research Institute Earth and Marine Sciences Research Institute

History of Dioxin in MRC-ESERI January 03: Market searched for Dioxin in Turkey & EU February 03: Dioxin study business plan prepared March 03: EPA, EN Standards translated to Turkish April 03: Institutions for training searched in Europe May 03: PCDD and PCDF sources, formation and toxicity examined

History of Dioxin in MRC-ESERI June 03: materials and equipments ordered for EN-1948/1-2 ; Contact with MoE, metal recovery firms searched in Turkey for this project August 03: Extraction and clean-up systems are performed for EN-1948/1-2, first trials September 03: Calibration of HRMS with standards done October 03: The results are validated for Accreditation, Recoveries %80-120 for TCDD/F, PeCDD/F, HxCDD/F and %100-140 for OCDD/F

History of Dioxin in MRC-ESERI November 03: CRM for accreditation ordered; the first real extraction and clean-up trials from adsorbent (XAD-2) studied December 03: The mistakes of our experimental system searched, clarifying the procedure January 04: Obtained the higher recoveries in the analyse of CRM

Our Capabilities-Mass Spectrometry Lab MRC-Mass Spectrometry Laboratory 1 pc GC with FID Dedector (FISONS) 1 pc GC with MS Dedector (FISONS) 1 pc Head Space Sampler (Perkin Elmer) 1 pc Thermal Desorber (Perkin Elmer) 1 pc HPLC (Shimadzu) 1 pc HRMS (Micromass) with GC (without autosampler)

Our Capabilities-Mass Spectrometry Lab

Our Capabilities-Mass Spectrometry Lab

Our Capabilities-Mass Spectrometry Lab

Our Capabilities-Mobile Air Quality Lab Determination of various emission and air quality parameters such as particulate matter, organic gases, heavy metals, traffic and industrial activities. Mobile air quality laboratory is isolated from heat, dust and water A UPS to back up all the equipment for electricity cut off for 2 hours Computer System for on-line monitoring and data acquisition Air conditioner to stable inside temperature of the cabin in range of +10 °C and +35 °C MGC 101, calibration unit(gas-mixture calibrator) and calibration tubes

Our Capabilities-Mobile Air Quality Lab Analyse parameters of Air Quality/Mobil Air Quality Lab -Stack gases (SOx-EPA6C, NOx-EPA CTM022,CO-EPA CTM30) * -VOC Sampling -Heavy Metals -Halogenated compounds -Ammonia -Dust (EPA 17) * -Dioxin and Furane Sampling * Accredited by DAP/DAR (Germany)

Our Capabilities-Mobile Air Quality Lab Weather Quality Measurements -Particulate matter -Sulphur Dioxide -Nitrogen Oxide -Volatile Organics -Carbon monoxide and dioxide -Ozone -Passive samplers for air quality measurement (HF, HCl,NOx, VOC, O3) -Air Quality Modelling

Main Dioxin Sources in Turkey * Waste Incineration (1 Industrial,7 medical waste incinerator) * Ferrous and Non-Ferrous Metal Production (3 Iron ore sintering facilities, >100 foundries, >100 sec.aluminium producer) * Power Generation and Heating (5 Power Plants with fossil fuel, 5 Power Plants with Natural gas, 1 municipal compost gas incinerator) * Production of Mineral Products (40 Cement facilities, >10 Lime prod.facilities

Main Dioxin Sources in Turkey * Uncontrolled Combustion Processes (Forest fires 8514 Ha/year 2002, Agricultural residue burning) * Production of Chemicals ( 1 Petrochemistry Facility-156.000 ton/year PVC, 54 pulp and paper facilities-1.762.500 ton paper/year 2003) * Disposal/Landfill (The most important problem in Turkey, >%80 of daily municipal wastes are handling with wild landfill)

Secondary Aluminium Producers

Lead-Zinc-Copper Recovery Facilities

Proposed Measurement Sites in Turkey,Ankara

-MRC will great appreciate getting a role in this project Results -MRC will great appreciate getting a role in this project -MRC will gain strategic assistance in the scope of this project -Dioxin subject will gain a particular attention by industry and governmental institutions