Globally Harmonized System Hazard Communication

Introduction Introduction Instructor Program Hazard Communication Standard (HCS)/Globally Harmonized System (GHS)

HCS/GHS Terminal Objective The students will be able to identify the presence and classification of hazardous materials through documentation and observation.

ENABLING OBJECTIVES The students will: Identify the impact of Globally Harmonized System (GHS).

Background OSHA Final Rule Published March, 2012 Primary focus on 29CFR1910.1200 Hazard Communication Standard (HCS) (HazCom) Changed many other OSHA standards HAZWOPER Health Hazard definition changed to match Hazardous Communication Standard Many of the specific chemical (“1000 series”) hazards defined, sign changes, and notification changes Definition changes within flammable liquids and other standards

OSHA Hazardous Communication Standard (HCS)(29CFR1910.1200) Ensure chemical safety in the workplace Information about the identities and hazards of the chemicals must be available and understandable to workers.

OSHA Hazardous Communication Standard (HCS)(29CFR1910.1200) OSHA Standard (HCS) requires the development and dissemination of information: Chemical manufacturers and importers are required to evaluate the hazards of the chemicals they produce or import prepare labels and safety data sheets to convey the hazard information to their downstream customers; Employers with hazardous chemicals in their workplaces must have labels and safety data sheets for their exposed workers train them to handle the chemicals appropriately.

OSHA Hazardous Communication Standard (HCS)(29CFR1910.1200) Major changes to the Hazard Communication Standard (meet GHS) Hazard classification: Provides specific criteria for classification of health and physical hazards, as well as classification of mixtures. Labels: Chemical manufacturers and importers will be required to provide a label that includes a harmonized signal word, pictogram, and hazard statement for each hazard class and category. Precautionary statements also must be provided. Materials Safety Data Sheets (MSDS) now Safety Data Sheets (SDS): Will now have a specified 16-section format. Information and training: Employers are required to train workers by December 1, 2013 on the new labels elements and safety data sheets format to facilitate recognition and understanding.

Globally Harmonized System (GHS) Hazard Communication Standard (HCS) now aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Provides a common and coherent approach to classifying chemicals and communicating hazard information on labels and safety data sheets Primary purpose of revised Standard is to improve the quality and consistency of hazard information in the workplace by providing easily understandable information on appropriate handling and safe use of hazardous chemicals. Another purpose of update is to help reduce trade barriers Additional Information: http://www.osha.gov/dsg/hazcom/index.html

GHS of Classification and Labeling of Chemicals Approach to: Defining health, physical, and environmental hazards of chemicals Creating classification processes that use available data on chemicals for comparison with the defined hazard criteria Communicating hazard information, as well as protective measures, on labels and Safety Data Sheets (SDS)

GHS (cont.) Attempt to create international standard for hazard identification systems Differences exist internationally and also within nations

GHS (cont.) For Instance, in the U.S. all of the following have different systems and definitions: Consumer Product Safety Commission (CPSC) Department of Transportation (DOT) Environmental Protection Agency (EPA) Occupational Safety and Health Administration (OSHA)

Flammable/Combustible Liquids - Now In flashpoint - minimum temperature in degrees Fahrenheit at which a liquid will give off sufficient vapors to form an ignitable mixture with air OSHA HCS Flammable = 0-100 Degrees Combustible = 100-200 deg. OSHA/NFPA Combustible = 100-200+ degrees EU Extremely/Highly/Flammable = 0-131 Deg. DOT Flammable = 0-140 Degrees Combustible = 140-200 deg. IMO ICAO/IATA Flammable = 0-140 Degrees CPSC Flammable = 0-100 Degrees Combustible = 100-150 deg. ANSI Z129.1 Extremely Flammable = 0-140 Deg. Combustible = 140-200 deg. GHS Everything actually called Flammable Liquid

Flammable Liquids GHS Category Criteria NFPA/ ICC class now NFPA 704 now 1 Flash point < 23°C (73°F) and initial boiling point ≤ 35°C (95°F) IA 4 2 Flash point < 23°C (73°F) and initial boiling point > 35°C (95°F) IB 3 Flash point ≥ 23°C (73°F) and ≤ 60°C (140°F) IC & II 2 & 3 Flash point ≥ 60°C (141°F) and ≤ 93°C (200°F) IIIA

Physical Hazard Explosives Flammable Gases Flammable Aerosols Oxidizing Gases Gases Under Pressure Flammable Liquids Flammable Solids Self-Reactive Substances Pyrophoric Liquids Pyrophoric Solids Self-Heating Substances Substances which, in contact with water, emit flammable gases Oxidizing Liquids Oxidizing Solids Organic Peroxides Corrosive to Metals

Health Hazard Acute Toxicity Skin Corrosion/Irritation Serious Eye Damage/Eye Irritation Respiratory or Skin Sensitization Germ Cell Mutagenicity Carcinogenicity Reproductive Toxicology Target Organ Systemic Toxicity - Single Exposure Target Organ Systemic Toxicity - Repeated Exposure Aspiration Toxicity

Category Defines degree of hazard/danger for a type of substance. Flammable Liquid – Category 1 Flash point < 23°C (73°F) and initial boiling point ≤ 35°C (95°F) Skin Corrosion Irritation – Category 3 Mild Skin Irritation - Reversible adverse effects in dermal tissue Note this is reverse of traditional NFPA 704 or HMIS system where minimal hazard is 1 and worst case is a 4

Category Numbers Gasoline Example Flammable Liquid - Category 2 Skin Corrosion/Irritation - Category 2 Germ Cell Mutagenicity - Category 1B Carcinogenicity - Category 1B Toxic to Reproduction - Category 1A Specific Target Organ Toxicity (Single Exposure) - Category 3 (respiratory irritation, narcosis) Specific Target Organ Toxicity (Repeat Exposure) - Category 1 (liver, kidneys, bladder, blood, bone marrow, nervous system) Aspiration Hazard - Category 1 Hazardous to the Aquatic Environment – Acute Hazard - Category 3 3 2 2 3

Label Elements Symbols/Pictograms Signal Words Hazard Statements Precautionary Statements/Pictograms Product Identifier (Ingredients) Supplier Information Supplemental Information (Optional)

HCS Pictograms

HCS Pictograms (cont’d.) 2 - 21

Signal Words The signal word indicates the relative degree of severity a hazard. The signal words used in the GHS are “Danger” for the more severe hazards “Warning” for the less severe hazards. Some lower level hazard categories do not use signal words. Only one signal word corresponding to the class of the most severe hazard should be used on a label.

Statements Located on label and SDS Hazard Statements Hazard statements are standardized and assigned phrases that describe the hazard(s). Precautionary Statements Precautionary information supplements the hazard information by briefly providing measures to be taken to minimize or prevent adverse effects

Hazard Statements Assigned alphanumeric code Letter H Number Numbers Not required to use the code – only the statement words Letter H Number 2 for physical hazards 3 for health hazards 4 for environmental hazards Numbers Two additional numbers corresponding to specific hazard group

Hazard Statements H200 Unstable explosive H201 Explosive, mass explosive hazard H220 Extremely flammable gas H221 Flammable gas H300 Fatal if swallowed H330 Fatal if inhaled H400 very toxic to aquatic life

Precautionary Statements Assigned alphanumeric code Not required to use the code – only the statement words Letter P Number 1 for general 2 for prevention 3 for response 4 for storage 5 for disposal Numbers Two additional numbers corresponding to sequential listing

Precautionary Statements P102 Keep out of reach of children P223 Do not allow contact with water P301 IF SWALLOWED ……. P362 Take off contaminated clothing P375 Fight fire remotely due to risk of explosion P410 Protect from sunlight P501 Dispose of contents/container to ….

Precautionary Pictograms Optional Pictograms

Transport “Pictograms”

Sample Label 2 - 30

Sample Label – Sulfuric Acid

Chinese Label - Ethyl Micheler’s Ketone

“Combination” Label

Label Identification

Label Identification

Safety Data Sheet Material Safety Data Sheet (MSDS) will now be called Safety Data Sheet (SDS) Sixteen sections similar to what was previously recommended Hazard Identification in Section 2 Previously Section 2 was Composition/Ingredients OSHA HCS regulations will now make the format mandatory

SDS Requirements 1. Substance and company identification 2. Hazards identification 3. Composition/ in-formation on ingredients 4. First-aid measures 5. Fire fighting measures 6. Accidental release measures 7. Handling and storage 8. Exposure control/ personal protection 9. Physical and chemical properties 10. Stability and reactivity 11. Toxicological information

SDS Requirements (cont.) 12. Ecological information 13. Disposal considerations 14. Transport information 15. Regulatory information 16. Other information OSHA Enforces previous 11 elements and element 16

Review sample MSDS/SDS Gasoline, Sample for Training

GHS OSHA Phase-In Effective Completion Date Requirement(s) Who December 1, 2013 Train employees on the new label elements and safety data sheet (SDS) format. Employers June 1, 2015* December 1, 2015 Compliance with all modified provisions of this final rule, except: The Distributor shall not ship containers labeled by the chemical manufacturer or importer unless it is a GHS label Chemical manufacturers, importers, distributors and employers June 1, 2016 Update alternative workplace labeling and hazard communication program as necessary, and provide additional employee training for newly identified physical or health hazards. Transition Period to the effective completion dates noted above May comply with either 29 CFR 1910.1200 (the final standard), or the current standard, or both Chemical manufacturers, importers, distributors, and employers 2 - 40