Organic Chemistry
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Organic Chemistry The chemistry of carbon compounds Sometimes called carbon chemistry
Organic Chemistry The backbone element in the molecules of all living things is carbon
Carbon Chemistry Carbon is one of the only elements that can form long chains Carbon can form 4 covalent bonds
Organic Chemistry Carbon forms covalent bonds with hydrogen, oxygen, nitrogen, phosphorus, sulfur, and the halogens
Carbon Bonding Carbon has 4 valence electrons which can hybridize in many ways
Carbon Bonding To determine the hybridization, draw the Lewis Dot Diagram of the carbon compound
Hybridization sp 3 4-single bonds sp 2 2-single bonds & 1-double bond sp2 doubles or T + S
Multiple Bonds To make multiple bonds, p-orbitals are required
Hybridization sp 3 no p-orbitals sp 2 1 p-orbital sp2 p-orbitals
Single bonds & the first bond in multiple bonds involve end-to-end overlap:
Multiple Bonds After the 1 st bond, any others are bonds: side-to-side p-overlap
AX 4 or sp 3 H H-C-H H
AX 3 or sp 2 H C=O H
AX 2 or sp O=C=O H-C N
Carbon Bonds sp 3 4 bonds sp 2 3 & 1 bonds sp2 & 2 bonds
Carbon sp 3 Shapes AX 4 tetrahedral AX 3 Etrigonal pyramidal AX 2 E 2 v-shaped
AX 4 or sp 3 H H-C-H H
AX 3 E or sp 3.. R-N-H H
AX 2 E 2 or sp 3.. R-O: H
Carbon sp 2 Shapes AX 3 trigonal planar AX 2 Ev-shaped
AX 3 or sp 2 H C=O H
AX 2 E or sp 2 O S: R
Carbon sp Shape AX 2 linear
AX 2 or sp O=C=O H-C N