M. SOBIESIAK, B. PODKOŚCIELNA, B. GAWDZIK DEPARTMENT OF POLYMER CHEMISTRY, FACULTY OF CHEMISTRY, MARIA CURIE-SKŁODOWSKA UNIVERSITY, PL. M. CURIE-SKŁODOWSKIEJ.

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M. SOBIESIAK, B. PODKOŚCIELNA, B. GAWDZIK DEPARTMENT OF POLYMER CHEMISTRY, FACULTY OF CHEMISTRY, MARIA CURIE-SKŁODOWSKA UNIVERSITY, PL. M. CURIE-SKŁODOWSKIEJ 5, LUBLIN, POLAND COST ACTION FP1105 San Sebastian TH MAY 2015

ATR-FTIR spectra of monomers COST ACTION FP1105 San Sebastian TH MAY cm cm cm cm , 1260 and 1175 cm , 1380, 1240 and 1180 cm -1

ATR-FTIR spectra of St-DVB polymers COST ACTION FP1105 San Sebastian TH MAY 2015 GroupSignal [cm -1 ] Metylene groups Acrylane Ether Hydroxyl 2854, 2923, 1458, and , 1242, and and and 1109

Operational conditions of TG measurements: heating rate 10ºC/min dynamic atmosphere of helium40mL/min range of temperature50-800ºC mass of the sample ca. 10mg COST ACTION FP1105 San Sebastian TH MAY 2015 DTG curves of presented polymers

ATR-FTIR spectra confirmed successful modification of lignin and its building up into polymeric network. The lignin or derivatives in St-DVB polymer make it more hydrophilic due to the presence of oxygen containing functionalities. TG-DTG-FTIR analyses proved that St-DVB modified with lignin or its derivatives possess better thermal stabilities than unmodified St-DVB. These features make the presented materials very interesting for application in chromatographic techniques. COST ACTION FP1105 San Sebastian TH MAY 2015