Polymer chemistry Polymer chemistry Chapter 1 Introduction to Polymer Science 1.1 Concept and History 1.2 Classification and Nomenclatur 1.3 Clssification.

Slides:



Advertisements
Similar presentations
C2 - Material Choices Revision
Advertisements

1 Polymers Chapter 8- Part 1 Manufacturing Processes, 1311 Dr Simin Nasseri Southern Polytechnic State University.
Petrochemical Products. Petrochemical Products Products made from petroleum consist of long chains called polymers Each link in the chain is a small molecular.
Polymers Larry Scheffler Version 1.0.
Polymers: Giants Among Molecules. Chapter 102 Macromolecules Compared to other molecules, they are enormous –Molar mass: 10,000–1,000,000+ g/mol –Not.
1 Chemistry for Engineering Logistics POLYMERS AND POLYMER MATERIALS 1. Basic Terms in Polymer Chemistry 2. Manufacture of Polymer Products Department.
CHAPTER 14 Polymer Structures.
Chapter 13 Unsaturated Hydrocarbons
Chemistry 1120 Polymers. Monomer monos - one meros - parts Polymers poly - many meros - parts From yahoo images.
PE335 Lecture 21 Lecture# 3 Molecular Mass and Chain Microstructure Mass vs. Weight Molecular “Weight” and Distribution Averages Polydispersity Property.
Introduction to Materials Science, Chapter 14, Polymer Structures University of Virginia, Dept. of Materials Science and Engineering 1 Chapter Outline:
1 "I just want to say one word to you -- just one word -- 'plastics.'" Advice to Dustin Hoffman's character in The Graduate.
Polymer Chemistry CHEM List of Topics No. of Weeks Contact Hours Introduction to polymer chemistry, definitions and types of polymeric materials.
Polymers!: Chapter 7 – Principals of Polymeric Materials = Polymer science – basic overview, chemical makeup, strengthening techniques and fillers, morphology,
Chapter 9: The World of Polymers and Plastics
What does it mean to be organic in Earth Science? Popular culture? In Home Decorating?
Chapter 9: The World of Polymers and Plastics
Professor: Michael Eastman Ph.D. Assistant: David Chavez-Flores
Synthetic and Biological Polymers
Physical-chemical properties of biopolymers.
Synthesizing a Silicate Chain to Form Superballs.
POLYMER PLANET.
Let’s start with MONOmers. What is a MONOmer? Mono means "one". So, monomers are those itty bitty molecules that can join together to make a long polymer.
Polymers.
Chapter 10 Polymers: Giants Among Molecules
CHE 411 POLYMER TECHNOLOGY Prof. AbdulAziz A. M. Wazzan.
Polymer Structure Polyolefins with side chains have stereocenters on every other carbon With so many stereocenters, the stereochemistry can be complex.
Polymers HairFurFingernailsSilkCottonPolyamides(nylons)PolyesterPolyethylenePVAPVCDacronLycra What are they all?
ENG2000: R.I. Hornsey Poly: 1 ENG2000 Chapter 5 Polymers.
What is a Polymer? Withrow University High School May 2008.
Polymer Chemistry Polymer Characteristics and Classifications Ms. Mandel Honors Physical Science.
solid polymers: ~ g/mol
6.3 Organic Compounds This PowerPoint accompanies reading pages 161 to 167.
Chapter 9: The World of Polymers and Plastics Why is plastic so important? What happens to recycled plastics and polymers? Are there downsides to recycling?
Polymers.
What is a Polymer? Withrow University High School May 2008.
Solids, liquids and gasses
Organic Polymers.
2.3 notes Carbon Compounds. Organic chemistry- study of compounds that contain bonds between C atoms Carbon: -can bond with 4 e- to another atom -can.
Carbon and Carbon Compounds. Carbon and carbon compounds Focus questions: 1. Why can carbon form so many different compounds? 2. How are properties of.
Organic Compounds- polymers Mrs. Brostrom Integrated Science.
The Structure and Properties of Polymers Also known as Bonding + Properties.
Polymers and Composites. Carbon Carbon can be in so many different compounds because: 1.It can form 4 covalent bonds. 2. They can bond in chains or ring.
2.1 Introduction to Polymers. Where do we get silk?
Intro to Polymers. Polymers Poly – many Mer - parts Long chain molecules made of many smaller repeating units.
POLYMERS Group members: Nurul Athirah Binti Abd.Razak ( ) Maisarah Binti Mohamed Hanafi ( ) Nur Fasihah Binti Mohd. Ariffin ( ) Khairussyifa.
Chapter 2- Polymer Chemistry
Definition: A molecule that is made of repeating structural units. Each individual unit is known as a monomer.
Polymers : are compounds comprising many modern synthetic materials and a large percentage of biological components. The Structure of Polymers : They are.
POLYMER STRUCTURE, MECHANICAL PROPERTIES AND APPLICATION
Polymer Science  Introduction  Classification of Polymer  Polymerization & It’s types  Characteristics of Polymer  Application of Polymer.
"I just want to say one word to you -- just one word -- 'plastics.'"
Polymerization.
Synthetic and Biological Polymers
Monomer is a small molecule Polymer is a long chain of monomers
Polymers: what they are and how they work?
POLYMER CHEMISTRY CT 107 LECTURER: MRS N. P
By: Muhammad Haseeb Iqbal National Textile University
Polymers Learning Objectives: Describe what a polymer is.
An overview of polymers
Biochemistry Notes pt. 3.
Natural & Synthetic Polymers
Engineering Materials: Chemistry, Pollution, and Solutions
Section 3 – pg 306 Polymers and Composites
The Structure and Properties of Polymers
Engineering Materials Polymeric materials
Pop Quiz.
Subject: Engineering Chemistry Unit: III
Natural vs. Man Made.
Presentation transcript:

Polymer chemistry Polymer chemistry

Chapter 1 Introduction to Polymer Science 1.1 Concept and History 1.2 Classification and Nomenclatur 1.3 Clssification of Polymerization reaction 1.4Molecular-Weight Distribution 1.5Microcosmic Structure of polymer 1.6 Microcosmic shape 1.7 Polymer Morphology and Thermal Transition

1.1 Concept and History Brief Introduction Polymers are made up of many many molecules all strung together to form really long chains (and sometimes more complicated structures, too).

Property Remember that polymers are very very long chains. These long chains: can bend and twist and get all tangled up, can stick to each other, move much slower because they're so big. Let's see how each of these affects how polymers act.

Polymer Chains Tangle Up (Chain Entanglement) The longer a polymer chain is, the more tangled up it can get. Since the chains are harder to pull out or separate, that can make things made out of polymers stronger. Some polymers are more straight and stiff than others. These won't tangle up as much, but they're strong for a different reason - stiff chains can pack together and stick to each other.

Polymer Chains Stick to Other Polymer Chains (Summationof Intermolecular Forces): Think of molecules as being like magnets. Some are like very weak magnets, and some are like strong magnets. So, some can be pulled apart easily, but others take a lot more energy to pull them apart. Polymer chains are like this too, but remember that they're much much longer than molecules. When the chains stick together very strongly, it can be really tough to pull them apart. If the chains happen to be straight and stiff and all lined up next to each other, it can be REALLY hard to pull them apart. A great example is cellulose in wood. The chains lay next to each other, straight and sticky (like strong magnets). That makes trees (and lots of houses!) strong and tall.

Polymer Chains Move Slower than Molecules (Time Scale of Motion) We can see what happening when polymers dissolve in a liquid. Those long chains move around so slowly that they make the solution flow much slower. The longer the chains, the slower the flow. If we measure how long it takes for a polymer solution to flow through a special tube, we can learn more about how big the polymer chains are.

Polymers in life

Poly(styrene-butadiene-styrene), or SBS, is a hard elastomer that's used for things like the soles of shoes, tire treads, and other places where durability is important. It's a copolymer called a block copolymer made of three segments. The first is a long chain of polystyrene, the middle is a long chain of poly butadiene, and the last segment is another long chain of polystyrene.

Certain polymers, such as proteins, cellulose, and silk, are found in nature, while many others, including polystyrene, polyethylene, and nylon, are produced only by synthetic routes. In some cases, naturally occurring polymers can also be produced synthetically. An important example is natural rubber, known as polyisoprenein its synthetic form.

Polymers that are capable of high extension under ambient conditions find important applications as elastomers. In addition to natural rubber, there are several important synthetic elastomers including nitrileand butyl rubber.

Other polymers may have characteristics that permit their formation into long fibers suitable for textile applications. Other polymers may have characteristics that permit their formation into long fibers suitable for textile applications. The synthetic fibers, principally nylon and polyester, are good substitutes for naturally occurring fibers such as cotton, wool, and silk. The synthetic fibers, principally nylon and polyester, are good substitutes for naturally occurring fibers such as cotton, wool, and silk.

1.1.2Concept polymer ( Macromolecules, High Polymer ) The word polymer is derived from the classical Greek words poly meaning "many" and meres meaning "parts." Polymers are substances consisting of many structural units connected by covalent bonds. Simply stated, a polymer is a long- chain molecule that is composed of a large number of repeating units of identical structure.

Monomer; Structure unit degree of polymerization Poly- means "many" and -mer means "part" or "segment". Mono means "one". So, monomers are those itty bitty molecules that can join together to make a long polymer chain. Monomer : material employed in the preparation of the polymer. Many many many MONOmers make a POLYmer!

Structure units are connected to one another in the polymer molecule, or polymeric structure, by covalent bonds. repeat unit: The atoms that make up the backbone of a polymer chain come in a regular order, and this order repeats itself all along the length of the polymer chain. For example, look at polypropylene : Its backbone chain is made up of just two carbon atoms repeated over and over again. One carbon atom has two hydrogen atoms attached to it, and the other carbon atom has one hydrogen atom and one pendantmethyl group (CH 3 ).

This is called the repeat structure or the repeat unit. To make things simple, we usually only draw one unit of the repeat structure, like this: The repeat unit is put inside brackets, and the subscript n just stands for the number of repeat units in the polymer chain.

Another example: styrene monomers join together to make polystyrene:

Degree of polymerization: refers to the number average obtained by dividing the total number of structural units by the total number of molecules. Polymer molecular weight: M 0 : molecular weight of repeating unit DP : Degree of polymerization, M  DP × M 0

History

H . Standinger