Concepts to Rvw Pressure –Stand demo –Sound demo Units of pressure –Pa –mm Hg –torr –atm –psi

Conversions in Pressure 1 atm = 760 mm Hg 1 atm = 760 torr 1 atm = 1.01 x 10 5 Pa or 101 kPa 1 atm = 14 psi

Practice 1.Convert 1.75 atm to kPa. 2.Convert 1.75 atm to mm Hg.

Hmmmm? Why do you almost close your mouth and blow when you have a burn on your skin to cool it? Why do you open your mouth wider when you want to warm your hands?

Run through of laws Equation to know: P 1 V 1 = P 2 V 2 T must be in Kelvin T 1 T 2 Dalton’s law of partial pressures (duh) next next Boyle’s law (last class) next next Charles’ law next next Gay-Lussac (what you will design) next

Dalton’s Law Gas collection thru water Pros Cons Table A-8 in appendix A Pg 859

How to do Dalton’s law problems Sample prob B P T = P gas + P H2O

Practice prob pg 367 GivensEq’n T = 20 o C Pressure = Partial press of H = torr Partial press of water = 17.5 torr ?? = room pressure at time

Pg 367 #5 Givens T = 23 o C Room pressure = 785 mmHg Partial pressure of water = 21.1 mm Hg ??? Partial pressure of nitrogen back

Boyle’s Law Why does it get harder squeeze as the volume decreases? How does this fit with breathing? back

Charles’ Law Dillon’s story— why everyone should know science Earlier aviation people used balloons Reason for Kelvin scale and absolute zero back

Guy-Lussac Using the pressure sensors, thermometers and a bottle of club soda determine how you can verify G-L law. You will need other materials but the set- up if for YOUR group to determine.

Gas Volumes  Noticed early on volumes didn’t add  Water example  Molar mass of gases = set volume  # =

Practice What volume does 0.68 mol of gas occupy at STP? What quantity of gas, in moles, is 2.21 STP?

Pg 392 # 43 more practice

Gas Stoichiometry Propane is use in gas grills. The complete combustion of propane is given by the following: C 3 H O 2  3CO H 2 O What volume, in liters, of oxygen is needed for the complete combustion of 0.35 L of propane?

Pg 382 Practice What volume of oxygen gas is needed to react completely with L of CO to form carbon dioxide? Assume all volume measurements are made at the same temperature and pressure.

Pg 382 Nitric acid can be made by the reaction of gaseous nitrogen dioxide with water according to the following reaction: 3NO 2(g) + H 2 O (l)  2 HNO 3(l) + NO (g) If 708 L of NO 2 react with water, what volume of NO will be produced? Assume all measurements are at same temp and pressure.