2 nd Annual K-12 Teachers Clean Energy Workshop July 30, 2015 Scott McDonald Biofuels Development Director Illinois Carbon Capture & Storage

ARCHER DANIELS MIDLAND COMPANY The Industrial Carbon Capture and Storage (ICCS) project is administered by the U.S. Department of Energy's Office of Fossil Energy and managed by the National Energy Technology Laboratory (award number DE-FE ) and by a cost share agreement with the Archer Daniels Midland Company, University of Illinois through the Illinois State Geological Survey, Schlumberger Carbon Services, and Richland Community College. This ICCS project received DOE funding from the American Recovery and Reinvestment Act of 2009 ($141.4 million). The Midwest Geological Sequestration Consortium is funded by the U.S. Department of Energy through the National Energy Technology Laboratory via the Regional Carbon Sequestration Partnership Program (contract number DE-FC26-05NT42588) and by a cost share agreement with the Illinois Department of Commerce and Economic Opportunity, Office of Coal Development through the Illinois Clean Coal Institute. The Midwest Geological Sequestration Consortium (MGSC) is a collaboration led by the geological surveys of Illinois, Indiana, and Kentucky Acknowledgements

ARCHER DANIELS MIDLAND COMPANY ADM Company Profile Core Purpose Connecting the harvest to the home and transforming crops into products that serve vital needs for food and energy. Key Facts FacilitiesOver 700 with sales in 140 Countries FY 2013 Net Sales:$90 billion Employees:31,000 Processing 74,000 MTD of corn 164,000 MTD of oilseeds 28,000 MTD of wheat 1,800 MTD of cocoa Logistics 27,400 Rail cars 2,500 Barges 600 Trucks – 1,300 Trailers 52 Oceangoing vessels

ARCHER DANIELS MIDLAND COMPANY ADM Company Profile Core Purpose Connecting the harvest to the home and transforming crops into products that serve vital needs for food and energy. Key Facts Facilities:Over 700 with sales in 140 Countries FY 2013 Net Sales:$90 billion Employees:31,000 Processing 74,000 MTD of corn 164,000 MTD of oilseeds 28,000 MTD of wheat 1,800 MTD of cocoa Logistics 27,400 Rail cars 2,500 Barges 600 Trucks – 1,300 Trailers 52 Oceangoing vessels

ARCHER DANIELS MIDLAND COMPANY Illinois Basin Decatur Project - Large scale geologic test to inject 1.0 million mt of CO 2 over a three year period (1,000 MT/day). Illinois Industrial CCS Project - Target & demonstrate advanced CCS technologies at industrial scale facilities. - Inject and store 1.0 million mt CO 2 per year (3,000 tons/day). - Study the interaction of two separate plumes. ADM - Decatur CCS Projects

ARCHER DANIELS MIDLAND COMPANY

Wet CO 2 from Corn-to-Ethanol Fermentation CO 2 Inlet Separator Centrifugal Blower (3000 HP) CO 2 P=35 Dehydrated CO 2 to 4 th Stage CO 2 Contactor 3 rd Stage Discharge CO 2 P=590 CO 2 Sequestration ~7,000 ft. depth in Mt. Simon Sandstone New Albany Shale (D=2000, T=120): Tertiary Seal Primary Source of Drinking Water (D=140) Pre-Cambrian Granite (D=7200) Eau Claire Shale (D=5000, T=500): Primary Seal Mt. Simon Sandstone (D=5500, T=1600): Saline Reservoir Maquoketa Shale (D=2600, T=200): Secondary Seal Centrifugal Booster Pump (400 HP) Reciprocating Compressors (3250 HP) 4 Stages with Intercoolers 4 th Stage Discharge CO 2 P=1425 Tri-ethylene Glycol Dehydration Unit Return Dry Glycol Water Glycol Regenerator Supercritical CO 2 8-in, 1-mile Pipeline MTPD M<0.005 Water Regenerator Reboiler 24-in line 1500-ft Injection Well P set by permit (estimate < 2300) St. Peter Sandstone Lower Most USDW (D=4000) Project Process Flow Diagram

ARCHER DANIELS MIDLAND COMPANY CO 2 Collection Facility

ARCHER DANIELS MIDLAND COMPANY Low Pressure CO 2 Delivery 24” CO 2 Transfer Line (1,800 ft)

ARCHER DANIELS MIDLAND COMPANY Main Compression Building

ARCHER DANIELS MIDLAND COMPANY Main Compression Building

ARCHER DANIELS MIDLAND COMPANY Main Compression Building

ARCHER DANIELS MIDLAND COMPANY CO 2 Dehydration Unit CO 2 TEG Water TEG + Water

ARCHER DANIELS MIDLAND COMPANY Main Compression Building

ARCHER DANIELS MIDLAND COMPANY HP CO 2 Transmission Line

ARCHER DANIELS MIDLAND COMPANY IBDP Injection Well

ARCHER DANIELS MIDLAND COMPANY Geophysical Modeling CO 2 Plume Position S-SWN-NE Eau Claire Lower Mt Simon Upper Mt Simon Cross Section Orientation

ARCHER DANIELS MIDLAND COMPANY Geophysical Modeling CO 2 Plume Position S-SWN-NE Eau Claire Lower Mt Simon Upper Mt Simon Cross Section Orientation

ARCHER DANIELS MIDLAND COMPANY Geophysical Modeling CO 2 Plume Position S-SWN-NE Eau Claire Lower Mt Simon Upper Mt Simon Cross Section Orientation

ARCHER DANIELS MIDLAND COMPANY Geophysical Modeling CO 2 Plume Position S-SWN-NE Eau Claire Lower Mt Simon Upper Mt Simon Cross Section Orientation

ARCHER DANIELS MIDLAND COMPANY Geophysical Modeling CO 2 Plume Position S-SWN-NE Eau Claire Lower Mt Simon Upper Mt Simon Cross Section Orientation

ARCHER DANIELS MIDLAND COMPANY Geophysical Modeling CO 2 Plume Position S-SWN-NE Eau Claire Lower Mt Simon Upper Mt Simon Cross Section Orientation

ARCHER DANIELS MIDLAND COMPANY Geophysical Modeling CO 2 Plume Position S-SWN-NE Eau Claire Lower Mt Simon Upper Mt Simon Cross Section Orientation

ARCHER DANIELS MIDLAND COMPANY Geophysical Modeling CO 2 Plume Position S-SWN-NE Eau Claire Lower Mt Simon Upper Mt Simon Cross Section Orientation

ARCHER DANIELS MIDLAND COMPANY Geophysical Modeling CO 2 Plume Position S-SWN-NE Eau Claire Lower Mt Simon Upper Mt Simon Cross Section Orientation

ARCHER DANIELS MIDLAND COMPANY Thank You! Industrial Carbon Capture and Storage Project: U.S. Department of Energy Award No. DE-FE Administered by the DOE’s Office of Fossil Energy Managed by the National Energy Technology Laboratory DOE cost share from American Recovery and Reinvestment Act of 2009 Cost Share Agreements: Archer Daniels Midland Company University of Illinois through the Illinois State Geological Survey Schlumberger Carbon Services Richland Community College Project Team Members Contacts: Dr. Sai Gollakota (NETL-DOE) Dr. Robert Finley, (ISGS) John Medler, (Schlumberger Carbon Services) Dr. Douglas Brauer (RCC) (Disclaimer: Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.)