1 Chapter 6 Chemical Quantities 6.2 The Mole Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings

2 Collection Terms A collection term states a specific number of items. 1 dozen donuts = 12 donuts 1 ream of paper = 500 sheets 1 case = 24 cans Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings

3 A mole (mol) is a collection that contains The same number of particles as there are carbon atoms in g of carbon x atoms of an element (Avogadro’s number). 1 mol C = x C atoms 1 mol Na = x Na atoms 1 mol Au = x Au atoms A Mole of Atoms

4 A mole Of a covalent compound has Avogadro’s number of molecules. 1 mol CO 2 = x CO 2 molecules 1 mol H 2 O = x H 2 O molecules Of an ionic compound contains Avogadro’s number of formula units. 1 mol NaCl = x NaCl formula units 1 mol K 2 SO 4 = x K 2 SO 4 formula units A Mole of A Compound

5 Samples of One Mole Quantities Table 6.1 Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings

6 Avogadro’s number x can be written as an equality and two conversion factors. As an equality: 1 mol = x particles As conversion Factors: x particles and 1 mol 1 mol x particles Avogadro’s Number

7 Using Avogadro’s Number Avogadro’s number Converts moles of a substance to the number of particles. How many Cu atoms are in 0.50 mol Cu? 0.50 mol Cu x x Cu atoms 1 mol Cu = 3.0 x Cu atoms Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings

8 Using Avogadro’s Number Avogadro’s number Converts particles of a substance to moles. How many moles of CO 2 are 2.50 x CO 2 molecules? 2.50 x CO 2 x 1 mol CO x CO 2 = 4.15 mol CO 2

9 1. The number of atoms in 2.0 mol Al is A. 2.0 Al atoms B. 3.0 x Al atoms C. 1.2 x Al atoms 2. The number of moles of S in 1.8 x atoms S is A. 1.0 mol S atoms B. 3.0 mol S atoms C. 1.1 x mol S atoms Learning Check

10 C. 1.2 x Al atoms 2.0 mol Al x x Al atoms 1 mol Al B. 3.0 mol S atoms 1.8 x S atoms x 1 mol S x S atoms Solution

11 Subscripts and Moles The subscripts in a formula state The relationship of atoms in the formula. The moles of each element in 1 mol of compound. Glucose C 6 H 12 O 6 In 1 molecule: 6 atoms C 12 atoms H6 atoms O In 1 mol: 6 mol C 12 mol H 6 mol O

12 Subscripts State Atoms and Moles 1 mol C 9 H 8 O 4 = 9 mol C 8 mol H 4 mol O Copyright © 2008 by Pearson Education, Inc. Publishing as Benjamin Cummings

13 Factors from Subscripts Subscripts used for conversion factors Relate moles of each element in 1 mol compound. For aspirin C 9 H 8 O 4 can be written as: 9 mol C 8 mol H 4 mol O 1 mol C 9 H 8 O 4 1 mol C 9 H 8 O 4 1 mol C 9 H 8 O 4 and 1 mol C 9 H 8 O 4 1 mol C 9 H 8 O 4 1 mol C 9 H 8 O 4 9 mol C 8 mol H 4 mol O

14 Learning Check A. How many moles O are in mol aspirin C 9 H 8 O 4 ? B. How many O atoms are in mol aspirin C 9 H 8 O 4 ?

15 Solution A. How many mol O are in mol aspirin C 9 H 8 O 4 ? mol C 9 H 8 O 4 x 4 mol O = mol O 1 mol C 9 H 8 O 4 subscript factor B. How many O atoms are in mol aspirin C 9 H 8 O 4 ? mol C 9 H 8 O 4 x 4 mol O x x O atoms 1 mol C 9 H 8 O 4 1 mol O subscript Avogadro’s factor Number = 3.61 x O atoms

16 Learning Check How many O atoms are in mol aspirin C 9 H 8 O 4 ?

17 Solution How many O atoms are in mol aspirin C 9 H 8 O 4 ? mol C 9 H 8 O 4 x 4 mol O x x O atoms 1 mol C 9 H 8 O 4 1 mol O subscript Avogadro’s factor number = 3.61 x O atoms