Gentle Intro to Semiconductors ENGN/PHYS 207
The ubiquitous LED
Collection of diodes
Diode = electronic valve Forward bias: Current flows!Reverse bias: No current flow!
The Silicon Valley
Warm-up question(s) What does it mean for a material to be able to “conduct” electricity?
Pure silicon lattice (intrinsic semiconductor) 2D lattice model showing covalent bonds in Si crystal
Band Theory of Solids Quantum Mechanics: Energy levels occupied by electrons are discrete. Amphitheatre analogy Aspendos Theatre, Turkey Conduction Band Band gap Valence Band
Energy Level Diagrams
Electron-Hole Pairs (EHPs)
Wait—what’s a hole? Vacancy in the valence band Acts like mobile positive charge An electron can fall into a hole (Recombination)
Important Fact Thermal energy to move and shake around a lattice at (T = 300K) kT = 1/40 eV = eV
Why pure silicon isn’t so hot Large energy barrier!
Let’s dope up (?) III (extra hole) IV V (extra e - ) Group Number
That’s dope: N and P type N-type: Extra electrons P-type: Extra holes Dopant electrons and holes are mobile Nuclei locked in the lattice, they are NOT mobile.
Why doping is actually good for us N-type : easily donates electrons into conduction band P-type: easily accepts electrons into valence band
The PN junction
Let there be Light…
The Diode Equation VBVB I
Silicon Diodes as Rectifiers “Electronic Valve” action Current can essentially flow in one direction only Reverse biasForward bias 0.7 V
Rainbow of Fruit Flavors
Idealized LED turn-on voltages V F (volts) I (mA) 1.8V 3.5V 3.6V
Sources Images: inst.eecs.berkeley.edu/~ee143/sp06/lectures/Semiconductor_tutorial.pdf inst.eecs.berkeley.edu/~ee143/sp06/lectures/Semiconductor_tutorial.pdf wavefunction wavefunction Animations: