High Pressure Studies of Titanium Hydride Up to 50 GPa with Synchrotron X-ray Diffraction Greg Harding 1, Patricia Kalita 2, Stanislav Sinogeikin 3, Andrew.

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Presentation transcript:

High Pressure Studies of Titanium Hydride Up to 50 GPa with Synchrotron X-ray Diffraction Greg Harding 1, Patricia Kalita 2, Stanislav Sinogeikin 3, Andrew Cornelius 2 1 Harvey Mudd College; 2 HiPSEC, Department of Physics and Astronomy, UNLV; 3 Carnegie Institute of Washington

Abstract Titanium hydride has the potential to play an important role in the efficiency of high density hydrogen storage. A sample of TiH 2 was placed in a diamond anvil cell and studied from ambient pressure up to 53 GPa using in situ synchrotron x-ray diffraction at the Advanced Photon Source (APS) of Argonne National Laboratory (Sector 16, HPCAT). From data of the evolution of the structure with pressure, an equation of state was obtained to model the behavior of the unit cell of TiH 2 between 0 and 53 GPa

Introduction Crystals change structure as pressure increases Change in structure results in new properties Diamond anvil cell (DAC) allows for high pressure in situ x-ray diffraction X-ray diffraction reveals information about the structure of the material Synchrotron x-rays allow for smaller samples to be studied due to high flux Face-Centered Cubic structure. Blue atoms are Ti and red are H. Body-Centered Tetragonal structure.

Methods – Diamond Anvil Cell Rhenium gasket indented between two diamond culets Electric Discharge Machine (EDM) used to drill hole through center of indentation Sample placed on diamond culet in gasket hole Gold flake and ruby microspheres added so that pressure can be inferred from ruby florescence lines or positions of Au peaks on diffraction pattern Ne gas used as hydrostatic medium Sample chamber Gasket Diamond anvil DAC diagram adapted from earth.northwestern.edu Photograph of DAC used in experiments

Methods – X-ray Diffraction DAC placed in x-ray beam Pressure increased in 1-2 GPa steps Diffraction patterns recorded for each step Circular pattern integrated to generate linear model using Fit2D Peak fitting used to find spacing between atoms Structure inferred from spacing Powder diffraction pattern at a pressure of 1.9 GPa Intensity vs. Angle across pressure range Graph on right magnified to make peaks more visible 2-θ(deg)

Data Analysis Peak fitting yields cell parameters Corresponding pressures and volumes can be fitted to Equation of State using following formula: where K 0 is the bulk modulus and V 0 is the volume at atmospheric pressure Equation of State fit for TiH 2. Bulk modulus is 136 GPa. For comparison, the bulk modulus of diamond is around 442 GPa.

Results/Conclusions Peak splitting on diffraction pattern confirms phase change in material TiH 2 undergoes a structure change from face-centered cubic (fcc) to body-centered tetragonal (bct) before 1.3 GPa and remains bct up through 53.3 GPa Titanium hydride has a relatively high bulk modulus of 136 ± 3 GPa Comparison of diffraction patters for two phases of TiH 2

Acknowledgements This work was performed at HPCAT (Sector 16, beam line IDB), Advanced Photon Source, Argonne National Laboratory. Use of the HPCAT facility was supported by DOE-BES, DOE-NNSA (CDAC), NSF, DOD-TACOM, and the W.M. Keck Foundation. Use of the APS was supported by DOE-BES, under Contract No. DE-AC02-06CH Support from the REU program of the National Science Foundation under grant DMR is gratefully acknowledged. The authors thank GSECARS, at the Advanced Photon Source, Argonne National Laboratory for the use of their gas loading setup