de Broglie wavelength de Broglie argued that there was a wavelength that could be written from.

Slides:



Advertisements
Similar presentations
Electrons as Waves Sarah Allison Claire.
Advertisements

Introduction to Quantum Theory
The Modern Atomic Model After Thomson: Bohr, Placnk, Einstein, Heisenberg, and Schrödinger.
Chapter 3 Classical Statistics of Maxwell-Boltzmann
Happyphysics.com Physics Lecture Resources Prof. Mineesh Gulati Head-Physics Wing Happy Model Hr. Sec. School, Udhampur, J&K Website: happyphysics.com.
Electron Configuration Mapping the electrons. Electron Configuration The way electrons are arranged around the nucleus.
MSEG 803 Equilibria in Material Systems 8: Statistical Ensembles Prof. Juejun (JJ) Hu
Quantum Model of the Atom l Bohr l de Broglie l Heisenberg l Schrödinger.
AME Int. Heat Trans. D. B. GoSlide 1 Non-Continuum Energy Transfer: Gas Dynamics.
Why are electrons restricted to specific energy levels or quantized? Louis de Broglie – proposed that if waves have particle properties, possible particles.
Thermo & Stat Mech - Spring 2006 Class 18 1 Thermodynamics and Statistical Mechanics Statistical Distributions.
Lecture 17: Intro. to Quantum Mechanics
Lecture 2210/26/05. Moving between energy levels.
Lecture 27 Overview Final: May 8, SEC hours (4-7 PM), 6 problems
Statistical Mechanics Physics 313 Professor Lee Carkner Lecture 23.
Chemistry 40S Unit 2 – Atomic Structure Lesson 2.
ELEMENTS OF STATISTICAL THERMODYNAMICS AND QUANTUM THEORY
Physics 451 Quantum mechanics I Fall 2012 Sep 10, 2012 Karine Chesnel.
Electron Configuration. The way electrons are arranged around the nucleus.
Bound States 1. A quick review on the chapters 2 to Quiz Topics in Bound States:  The Schrödinger equation.  Stationary States.  Physical.
Quantum Mechanical Model of the Atom Chapter 6 Part III.
Quantum Mechanical Theory. Bohr Bohr proposed that the hydrogen atom has only certain _________________. Bohr suggested that the single electron in a.
The Ideal Monatomic Gas. Canonical ensemble: N, V, T 2.
Element Elements and Compounds Dual Nature of Matter and Radiation Structure of Atom Compounds A compound is a substance composed of two or more elements,
 S univ =  S sys +  S surr Must be ____ for spontaneity as dictated by… + …the Second Law of Thermodynamics  S surr =  H / T (at constant P) So that:
CHE-20028: PHYSICAL & INORGANIC CHEMISTRY QUANTUM CHEMISTRY: LECTURE 3
Chapter 5/1© 2012 Pearson Education, Inc. Wavelike Properties of Matter The de Broglie equation allows the calculation of a “wavelength” of an electron.
Bound States Review of chapter 4. Comment on my errors in the lecture notes. Quiz Topics in Bound States: The Schrödinger equation. Stationary States.
Lecture 20. Continuous Spectrum, the Density of States (Ch. 7), and Equipartition (Ch. 6) The units of g(  ): (energy) -1 Typically, it’s easier to work.
Electron Configuration. The way electrons are arranged around the nucleus.
Chapter 6 Electronic Structure of Atoms. The Wave Nature of Light The light that we can see with our eyes, visible light, is an example of electromagnetic.
Quantum Theory the modern atomic model. Bohr Model of the Atom a quantum model proposed by Niels Bohr in 1913 It helped to explain why the atomic emission.
The Quantum Model of the Atom. Intro to Quantum Mechanics.
Copyright©2000 by Houghton Mifflin Company. All rights reserved. 1 Chemistry FIFTH EDITION by Steven S. Zumdahl University of Illinois.
Bohr vs the quantum mechanical model of the atom
Weird experiments Schrödinger equation.
Physics 1202: Lecture 31 Today’s Agenda Announcements: Extra creditsExtra credits –Final-like problems –Team in class HW 9 this FridayHW 9 this Friday.
Chapter – 6 Oct 24, 2011 Part - B The legends of physical sciences.
Orbitals: What? Why? The Bohr theory of the atom did not account for all the properties of electrons and atoms.
Electron & Hole Statistics in Semiconductors A “Short Course”. BW, Ch
Electromagnetic Spectrum Section 1 The Development of a New Atomic Model Chapter 4.
EXAMPLE 2.2 OBJECTIVE Solution Comment
Lecture 26 — Review for Exam II Chapters 5-7, Monday March 17th
Quantum Atom. Problem Bohr model of the atom only successfully predicted the behavior of hydrogen Good start, but needed refinement.
Modern Model of the Atom The emission of light is fundamentally related to the behavior of electrons.
The Quantum Mechanical Model Chemistry Honors. The Bohr model was inadequate.
Introduction Gomen-nasai: Have not finished grading midterm II
UNIT 1: Structure and properties wave mechanical model
Review of solid state physics
The units of g(): (energy)-1
Atomic Theory.
Equilibrium Carrier Statistics
Electron Configuration
Quantum Model of the Atom
III. Quantum Model of the Atom (p )
The Quantum Mechanical Model
Quantum Theory Light Theory Part 4.
Electron Clouds and Probability
Electron Configuration
Electron Clouds and Probability
Modern Physics Photoelectric Effect Bohr Model for the Atom
Atom Model History - Democritus a fifth century B.C. Greek philosopher proposed that all matter was composed of indivisible particles called atoms (Greek.
Hydrogen Atom Emission Spectrum
Quantum Mechanical Model of the Atom
Section 5.2 Quantum Theory and the Atom
Erwin Schrödinger The many problems with the Bohr model were corrected by Erwin Schrödinger, an Austrian physicist. The Schrödinger Equation:
Electron Configuration
III. Quantum Model of the Atom (p )
Democritus and Leucippus
Bohr vs the quantum mechanical model of the atom
Presentation transcript:

de Broglie wavelength de Broglie argued that there was a wavelength that could be written from

Schrödinger equation

a 1 a 0 a 2 a0a

Schrödinger equation

Schrödinger equation electron in free space

Schrödinger equation

element nlms Hydrogen 100+1/2 or -1/2 Helium 100+1/2 & -1/2 Beryllium 200+1/2 & -1/2 Lithium 200+1/2 or -1/2

Heisenberg uncertainty principle

Simple marbles – number of ways of organizing the three balls

Simple marbles – number of ways of organizing 5 balls in 3 pails (microstates)

entropy

Entropy of five marbles in the three pails – 2 & 1 & 2

Two constraints

Calculate the dimensions of a rectangular garden that has a hill that is surrounded by a fence of a fixed length c. (Lagrange multiplier)

entropy

Maxwell Boltzmann distribution

Water bag distribution

Schrödinger equation

12345 Are there electrons in the state? 12345

Fermi-Dirac distribution n j is the number of particles in state j e j is the energy of state j g j is the degeneracy of state j (the number of states with energy e j )  is the chemical potential  B is Boltzmann’s constant T is absolute temperature

Fermi-Dirac distribution