Application of biobased plastics as food packaging material

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Presentation transcript:

Application of biobased plastics as food packaging material Dr. ir. Nanou Peelman International conference and exhibition on Biopolymers and Bioplastics 10-12/08/2015 Beste voorzitter, juryleden, collega’s, vrienden en familie, welkom op mijn doctoraatsverdediging met als titel “karakterisatie van barriere eigenschappen en temperatuursresistentie van biogebaseerde plastics voor het verpakken van levensmiddelen” International conference and exhibition on Biopolymers and Bioplastics 10-12/08/2015

Increased use of raw materials Introduction Why use food packaging? Roles of food packaging: Containment Protection Communication Convenience Prevention of food loss! (huge environmental impact) Voorgenoemde nadelen + groter bewustzijn bij de consument leidden tot grotere interesse, MAAR onvoldoende kennis over de prestatie van deze bioplastics verhinderen dat bedrijven de stap durven zetten. Food packaging ↑ Increased use of raw materials

Introduction Interest in bioplastics among stakeholders in the food industry BUT lack of knowledge on their performance hinders succesfull introduction AIM of this research: can biobased plastics replace conventional plastics as a food packaging material? Voorgenoemde nadelen + groter bewustzijn bij de consument leidden tot grotere interesse, MAAR onvoldoende kennis over de prestatie van deze bioplastics verhinderen dat bedrijven de stap durven zetten. Barrier properties

Barrier properties O2 + CO2 barrier: H2O barrier: MAP (modified atmosphere) Delay or inhibit growth microorganisms Delay chemical degradation H2O barrier: Avoid dehydration (fresh products) Water permeation (e.g. loss of crispness) In tegenstelling tot bvb glas of metaal zijn plastic materialen doorlaatbaar. In voedingsindustrie is enerzijds de gasbarriere belangrijk … anderzijds is ook de vochtbarriere belangrijk …

Barrier properties of biobased plastics   Cellulose Starch PLA PHA O2-barrier + - H2O-barrier ± Barrier properties can be improved by: Use of multilayers Use of coatings (e.g. metal layer) Monolayer Multilayer Without coating With coating

Characterization barrier properties (commercial) multilayer biobased plastics Large variations → biobased plastics with barrier properties for different types of food products exist

Storage tests: selection of food products H2O Eerste groep verpakt onder lucht, vochtbarriere het belangrijkst. Tweede groep MAP en dus gasbarriere belangrijkst,

Selection of materials Selection was made by participating (food) companies Selection based on the technical specifications of their current conventional material Good performance No need for testing (expensive and time-consuming) Waarom gebruiken we verpakkingen voor levensmiddelen? Verpakking heeft ten eerste enkele belangrijke functies zoals omhulling, bescherming (o.a. barriere), gebruiksgemak (vb microgolf) en communicatie. Beschermingsfunctie is ook zeer belangrijk om voedselverspilling tegen te gaan. Afgelopen decennia sterke stijging in gebruik en dus ook meer grondstoffen nodig om ze te produceren. Many biobased plastics

Storage tests with lower barrier materials Food Product Selected packaging material Short shelf life (refrigerated storage) Rumsteak (MAP) PLA tray + Cellulose/PLA Medium shelf life Ham sausage (MAP) Cellulose/starch Mcellulose/starch PLA tray + Paper/AlOx/PLA Long shelf life (ambient storage) Tortilla chips (Air) Cellulose/M/PLA Eerste groep verpakt onder lucht, vochtbarriere het belangrijkst. Tweede groep MAP en dus gasbarriere belangrijkst,

Storage tests Packed in biobased package(s) and in conventional package Follow up during shelf-life: Gas headspace (if MAP) Microbial growth Lipid oxidation Color Sensorial evaluation (taste, odor, color,…)

Oxygen barrier Rumpsteak Ham Sausage Material OTR (cc/m².d) Cellulose/PLA 11,0 ± 0,2 (75% RH) PLA tray 46,8 ± 1,1 (50% RH) PET/CPP + PP tray 3 (50% RH) Material OTR (cc/m².d) Cellulose/PLA 11,0 ± 0,2 (75% RH) Paper/Alox/PLA 45,7 ± 2,7 (75% RH) PET/EVOH/PE <8 PLA tray 46,8 ± 1,1 (50% RH) APET/LDPE tray 20,6 ± 0,5

e.g. Ham sausage ------------------------------------------------------------------------ Oxygen concentration never exceeds the maximal limit applied by the industrial partner

Lipid oxidation parameters

Conclusion: rumpsteak and ham sausage In comparison with current conventional packaging: Gas headspace Microbial growth Lipid oxidation Color Sensorial evaluation Taste Odor

Moisture barrier properties: Tortilla chips In comparison with current conventional packaging: Moisture uptake Lipid oxidation Sensorial evaluation → preference biobased packaging

Conclusions Quality of various food products can be guaranteed MAP Light transparency

Conclusions Rice and pasta - Lima Coffee - Bastinpack Mede door resultaten uit het onderzoek hebben een paar bedrijven de stap gezet om over te schakelen naar bioplastics. Meat products – Ter Beke

Conclusions Biobased plastics with lower barrier properties than the current packaging materials can also guarantee the quality during shelf-life (overpacking?) New Project: OptiBarrier (www.pack4food.com) Case-by -ase approach is needed!

Acknowledgements IWT Participating companies Participating research institutes Prof. Dr. Dirk Poelman (LumiLab) Ik zou graag het IWT bedanken om dit onderzoek mogelijk te maken. Ook alle deelnemende bedrijven voor de input en goede samenwerking. Dirk Wens om voorzitter te willen zijn van beide gebruikersgroepen. Alle kennisinstellingen die meegewerkt hebben en Prof. Poelman voor het uitvoeren van de doorlaatbaarheidstesten.

Conclusions Thank you!

Barrier properties: storage tests Goed uitleggen! Groep 1: Parameters zelfde als in conventionele verpakking. FdS, Kaas en Chips zelfs voorkeur bij sensorische analyses. Kwaliteit gewaarborgd tijdens HBH. Groep 2: Meeste parameters OK, enkel verkleuring niet OK. Groep 3: Te veel vocht door verpakking, niet OK.