In a galvanic cell, the electrode that acts as a source of electrons to the solution is called the ___________; chemical change that occurs at this electrode.

Slides:



Advertisements
Similar presentations
Electrochemistry Applications of Redox.
Advertisements

Galvanic (= voltaic) Cells Redox reactions which occur spontaneously are called galvanic reactions. Zn will dissolve in a solution of copper(II) sulfate.
Lecture 12: Cell Potentials Reading: Zumdahl 11.2 Outline –What is a cell potential? –SHE, the electrochemical zero. –Using standard reduction potentials.
Chapter 17 Electrochemistry
Galvanic Cells What will happen if a piece of Zn metal is immersed in a CuSO 4 solution? A spontaneous redox reaction occurs: Zn (s) + Cu 2 + (aq) Zn 2.
Galvanic Cell.
Electrochemical Cells (aka – Galvanic or Voltaic Cells) AP Chemistry Unit 10 Electrochemistry Chapter 17.
Standard Cell Notation (line notation)
Chapter 18 Electrochemistry. Redox Reaction Elements change oxidation number  e.g., single displacement, and combustion, some synthesis and decomposition.
Lecture 11: Cell Potentials Reading: Zumdahl 11.2 Outline –What is a cell potential? –SHE, the electrochemical zero. –Using standard reduction potentials.
Chapter 20 Electrochemistry
Lecture 11: Electrochemistry Introduction
Lecture 10: Electrochemistry Introduction Reading: Zumdahl 4.10, 4.11, 11.1 Outline –General Nomenclature –Balancing Redox Reactions (1/2 cell method)
Lecture 244/1/05. Quiz 1) Balance the following redox equation: Ag(s) + NO 3 -  NO 2 (g) + Ag + (aq) 2) What is the oxidation number for Chlorine in.
Electrochemistry 18.1 Balancing Oxidation–Reduction Reactions
Chemistry 1011 Slot 51 Chemistry 1011 TOPIC Electrochemistry TEXT REFERENCE Masterton and Hurley Chapter 18.
Reduction Potential and Cells
Applications of Redox Your last chapter! I know, …… kinda sad.
Electrochemistry Applications of Redox. Review l Oxidation reduction reactions involve a transfer of electrons. l OIL- RIG l Oxidation Involves Loss l.
Chapter 20 – Redox Reactions One of the earliest recognized chemical reactions were with oxygen. Some substances would combine with oxygen, and some would.
Electrochemistry Applications of Redox. Review  Oxidation reduction reactions involve a transfer of electrons.  OIL- RIG  Oxidation Involves Loss 
 17.1 Explain how a non-spontaneous redox reaction can be driven forward during electrolysis  17.1 Relate the movement of charge through an electrolytic.
Electrochemistry Applications of Redox. Review l Oxidation reduction reactions involve a transfer of electrons. l OIL- RIG l Oxidation Involves Loss l.
Section 10.3—Batteries & Redox Reactions
GALVANIC AND ELECTROLYTIC CELLS
Electrical and Chemical Energy Interconversion
Chapter 20 Electrochemistry and Oxidation-Reduction.
14.2a Voltaic Cells Basic Function. Voltaic Cell Basics Electrodes and electrolytes chemically react to form ions that move in or out of solution. Anode.
Electrochemistry Applications of Redox. Review l Oxidation reduction reactions involve a transfer of electrons. l OIL- RIG l Oxidation Involves Loss l.
CHM 112 Summer 2007 M. Prushan Chapter 18 Electrochemistry.
Tutorial schedule (3:30 – 4:50 PM) No. 1 (Chapter 7: Chemical Equilibrium) January 31 at Biology building, room 113 February 1 at Dillion Hall, room 254.
 Learners must be able to define galvanic cell in terms of electrode reaction. e.g. salt bridge.(N.B. anode and cathode)  Learners must be able to do.
Electrochemical Cells (Galvanic, Voltaic, Electric)
Electrochemistry IV The galvanic cell continued. Consider the galvanic cell based On the unbalanced redox reaction: FFe 3+ (aq) + Cu(s)  Cu 2+ (aq)
Copyright©2000 by Houghton Mifflin Company. All rights reserved. 1 Chemistry FIFTH EDITION by Steven S. Zumdahl University of Illinois.
Accuracy of the Debye-Hückel limiting law Example: The mean activity coefficient in a mol kg -1 MnCl 2 (aq) solution is 0.47 at 25 o C. What is the.
Electrochemistry Electrochemical Cells –Galvanic cells –Voltaic cells –Nernst Equation –Free Energy.
Electrochemistry - Section 1 Voltaic Cells
Copyright © Houghton Mifflin Company. All rights reserved.17a–1.
Electrochemistry ZnSO4(aq) CuSO4(aq) Cu Zn Zn
Electric energy Chemical energy Electrolysis Galvanic cell Chapter 8 Electrochemistry.
When a piece of zinc metal is placed in an aqueous CuSO 4 solution: 1743.
Reduction- Oxidation Reactions (1) 213 PHC 9 th lecture Dr. mona alshehri (1) Gary D. Christian, Analytical Chemistry, 6 th edition. 1.
Electrochemical cells - batteries
Chapter 19 Last Unit Electrochemistry: Voltaic Cells and Reduction Potentials.
Galvanic Cell Concept Separating the oxidation and reduction half-reactions will make it so the energy in the electron transfer can be harnessed. A salt.
By: Danielle Salvatore. Luigi Galvani discovered when copper and zinc were connected together and then both touched to different parts of a nerve of.
10.3 Half-reactions and electrodes
1 © 2006 Brooks/Cole - Thomson OXIDATION-REDUCTION REACTIONS Indirect Redox Reaction A battery functions by transferring electrons through an external.
Electrochemistry Sam Pomichter Introduction Oxidation- the loss of electrons Reduction- the gain of electrons We can identify oxidation-reduction.
Chapter 18 Electrochemistry Lesson 1. Electrochemistry 18.1Balancing Oxidation–Reduction Reactions 18.2 Galvanic Cells 18.3 Standard Reduction Potentials.
Warm up 3/17/15 Balance the half reaction. Ch. 17 Electrochemistry.
ELECTROCHEMISTRY Presentation by: P.K. CHOURASIA K.V MANDLA, Jabalpur Region.
In voltaic cells, oxidation takes place at the anode, yielding electrons that flow to the cathode, where reduction occurs. Section 1: Voltaic Cells K What.
ELECTROCHEMISTRY CHEM171 – Lecture Series Four : 2012/01  Redox reactions  Electrochemical cells  Cell potential  Nernst equation  Relationship between.
Electrochemistry. To obtain a useful current, we separate the oxidation and reduction half-reactions so that electron transfer occurs thru an external.
Chapter 20 Electrochemistry
17.1 Galvanic Cells (Batteries)
Cell Potential.
Electrochemistry Applications of Redox.
Chp 17 Electrochemistry.
14.2a Voltaic Cells Basic Function.
Electrochemistry / Redox
Harnessing the changes in oxidation and reduction
Galvanic Cell Concept Separating the oxidation and reduction half-reactions will make it so the energy in the electron transfer can be harnessed. A salt.
Electrochemistry- Balancing Redox Equations
Electrochemistry Applications of Redox.
Galvanic Cell Device in which chemical energy is changed to electrical energy. Uses a spontaneous redox reaction to produce a current that can be used.
3- Oxidation-Reduction (Redox) titration
Galvanic Cells Assignment # 17.1.
Presentation transcript:

In a galvanic cell, the electrode that acts as a source of electrons to the solution is called the ___________; chemical change that occurs at this electrode is called_________. Cathode, oxidation Anode, reduction Anode, oxidation Cathode, reduction

Line Notation Solid│Aqueous││Aqueous │solid Anode on the left ││Cathode on the right Single line different phases Double line porous disk or salt bridge If all the substances on one side are aqueous, a platinum electrode is indicated

For this reaction: Cu(s) + Fe+3(aq) → Cu+2(aq) + Fe+2(aq)

Under standard conditions, which of the following is the net reaction that occurs in the cell? Cd│Cd2+││Cu2+│Cu a. Cu2+ + Cd→ Cu + Cd2+ b. Cu + Cd → Cu2+ + Cd2+ c. Cu2+ + Cd 2+→ Cu + Cd d. Cu + Cd 2+ → Cd + Cu2+

Galvanic Cell The reaction always runs spontaneously in the direction that produced a positive cell potential. Four things for a complete description 1)Cell Potential 2)Direction of flow 3)Designation of anode and cathode 4)Nature of all the components-electrodes and ions

Practice Completely describe the galvanic cell based on the following half-reactions under standard conditions. MnO4-+ 8H++ Se- →Mn2+ + 4H2O E0=1.51V Fe2++ 3e- → Fe(s) E0=.036V

Potential, Work and ΔG emf= potential