Aromaticity, the DaVinci Code and the Golden Section Title.

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Presentation transcript:

Aromaticity, the DaVinci Code and the Golden Section Title

Internal Angles A Regular Pentagon has Internal Angles of 108 o The sum of all supplementary angles in any polygon equals 360 o In a regular pentagon each supplementary angle equals 72 o Thus 180 o - 72 o = 108 o Baeyer’s assumption about cyclopentane Where Baeyer went wrong.

Pentacle A regular pentagon can be inscribed in a circle. Connecting alternate vertices of a pentagon produces the pentacle, a figure imbued with mysticism. The Da Vinci Code

A B C Angles Angles Subtending a Chord (Arc)  Two line segments that subtend the same chord and meet on the circle have the same angle. 

Similar Isosceles Triangles A  D C   The interior angles (108 o ) of the pentagon are trisected into angles  = 36 o Similar Isosceles Triangles  

The Golden Section    A  D C  ACD is similar to  ABC with base angles of 2  and line AC = CD = BD = x If AB = 1, then AD = 1- x x/1-x = 1/x or x 2 + x -1 = 0 x = and 1/x = for positive values. The Golden Section

Cyclopentadienyl anion Aromaticity Meets the Da Vinci Code

Am I Aromatic? Am I Aromatic planar  -system cyclic array 10 double bonds; 20 electrons; 4n No!

A Closer Look The Bee Hive A Closer Look

Am I Aromatic? Am I Aromatic 2 planar  -system cyclic array 11 double bonds; 22 electrons; 4n + 2 Yes!

The bee can enter any cell but it must enter at cell 1 and then to subsequent contiguous cells in ascending numerical order. CellRoutes Cell 4: 1-2-4; 1-3-4; 1,2,3,4 but not 1,3,2,4 The route to a given cell is the sum of the routes to the two previous cells. The Bee Hive

The route to a given cell is the sum of the routes to the two previous cells. Fibonacci Series “0”, 1, 1, 2, 3, 5, 8, 13, 21, 34, 55, 89, 144, 233, 377, 610, 987, 1597, 2584, 4181, 6765, 10946… Leonardo Pisano Fibonacci (~ ) mouse over Fibonacci Series A series of numbers in which each number is the sum of the two preceding numbers.

Fibonacci Series 2 Fibonacci Series a/b = smaller/larger number b/a = larger/smaller number The Golden Section (Phi) is the limit of the ratio b/a.

Fibonacci Spiral Fibonacci Spiral and the Golden Rectangle The sunflower Leonardo’s Mona Lisa

The End