Errors and uncertainty: instrumental noise: only present in first term of auto-covariance function → error propagation random error: ~ 1 / √ # independent.

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Errors and uncertainty: instrumental noise: only present in first term of auto-covariance function → error propagation random error: ~ 1 / √ # independent observations, Finkelstein & Sims (2001): the statistical variance of a covariance is expressed as function of its auto-covariances and cross-covariance → detrending through high-pass filter before calculation of random error systematic error: the total surface flux is not represented by the covariance in case of large eddies; indirect error definition via energy balance ratio: source area – representativeness: application of footprint model (Kormann & Meixner, 2001) on each averaging interval A new scheme for quality and uncertainty assessment of eddy covariance measurements Mauder M 1, Cuntz M 2, Drüe C 3, Graf A 4, Rebmann C 2, Schmid HP 1, Schmidt M 4, Steinbrecher R 1 1 Institute for Meteorology and Climatology – Atmospheric Environmental Research (IMK-IFU), Karlsruhe Institute of Technology (KIT), Garmisch-Partenkirchen, Germany 2 UFZ – Helmholtz Centre for Environmental Research, Leipzig, Germany 3 Trier University, Environmental Meteorology, Trier, Germany 4 Forschungszentrum Jülich, Institute for Bio- and Geosciences – Agrosphere, Jülich, Germany References Finkelstein PL, Sims PF, 2001: Sampling error in eddy correlation flux measurements. J Geophys Res 106, Foken T, Wichura B, 1996: Tools for quality assessment of surface-based flux measurements. Agr For Met 78, Kormann R, Meixner FX, 2001: An analytical footprint model for non-neutral stratification. Bound Layer Meteor 99, Papale D, Reichstein M, Canfora E, Aubinet M, Bernhofer C, Longdoz B, Kutsch W, Rambal S, Valentini R, Vesala T, Yakir D, 2006: Towards a standardized processing of Net Ecosystem Exchange measured with eddy covariance technique: algorithms and uncertainty estimation. Biogeosciences 3, Acknowledgements We gratefully acknowledge the support by the TERENO project (Terrestrial Environmental Observatories) funded by the Helmholtz-Gemeinschaft and and the support by the SFB/TR 32 “Pattern in Soil-Vegetation-Atmosphere Systems: Monitoring, Modelling, and Data Assimilation” funded by the Deutsche Forschungsgemeinschaft (DFG) Introduction: Eddy-covariance measurements are performed at several hundred sites all over the world on a long-term basis. The increasing demand on standardised and comprehensive quality flagging and uncertainty quantification of these fluxes has led to this review of established quality assessment procedures and the development of a strategy, focusing on automatically applicable tests on high- frequency data, expanding existing tests on statistics, fluxes and corrections, plus quantification of errors which will be used within the Helmholtz-project TERENO. Tests on high-frequency data: usage of internal quality tests and diagnostic flags (e.g. Campbell CSAT3, Li-Cor LI-7500). spike test based on Median Absolute Deviation (MAD) for outlier or spike detection screening of the high-frequency data for instrumental plausibility Tests on statistics: assumptions of the EC method (simplified flagging after FW96): stationarity of the means ITC: well-developed turbulence zero mean vertical wind velocity interdependence of flux conversions and corrections on fluxes Table 2: Results of the MAD-based outlier test (Papale et al. 2006) after application of the proposed flagging scheme: (number of detected values by the Papale et al procedure / number of available data with flag 0 and data records were tested for each site. Results: discarding of momentum flux data due to the quality flagging is less than 10% noise errors typically ≤1% random errors 20-30% highest data quality associated with smallest random errors systematic errors: existance to be known, but difficult to account for Conclusion: Combination of diagnostic flags, robust spike detection, interdependence of fluxes, and footprint analysis improved the quality assessment strategy compared to established ones Figure 2: Relative systematic errors (%) for three test data sets determined from the energy balance ratio FendtGraswangLackenbergSelhausenWetzstein τ 1/12775/13480/10441/13832/1395 H 1/9167/112121/8829/126219/1153 λE 2/8205/8507/76213/112718/1059 FcFc 3/7579/8888/7657/11132/1064 Figure 1: CO 2 -fluxes for Graswang: without quality control (red circles), flagging according to FW96/Spoleto (orange triangles), filtering according to quality assessment scheme proposed for TERENO (green squares) Figure 3: Relative random flux error (%) for the investigated fluxes (median, lower and upper quartiles) as a function of their quality flags (orange: highest quality= flag 0, red: medium quality=flag1). Table 1: Overview of the test data sets