Solid State Chemistry Chapter 3 Atomic Structure and Spectra.

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Presentation transcript:

Solid State Chemistry Chapter 3 Atomic Structure and Spectra

AGENDA The structure and spectra of Hydrogenic atoms 1. Structure of hydrogenic atoms 2. Atomic orbitals and their energies 3. Spectroscopic transitions and selection rules The structure of many-electron atoms The spectra of complex atoms

The Structure and Spectra of Hydrogenic Atoms

Ritz combination principle: wavenumber of any spectral line is the difference between two terms

The Structure of Hydrogenic Atoms

Separation of Internal Motion

Separation of Variables (R, Y)

Radial Solutions

Radial Wavefunctions

Atomic Orbitals and their Energies

Ionization Energy

Shells and Subshells

Atomic Orbitals

Kinetic vs. Potential Argument

Mean Radius of an Orbital

Node Formation in s Orbitals

Radial Distribution Functions

p Orbitals

d Orbitals

Spectroscopic Transitions

Grotrian Diagram

Short Summary Structure and Spectra of Hydrogenic Atoms 1. Hydrogenic Atoms 2. Radial Wavefunctions 3. Ionization Energy 4. Orbitals 5. Radial Distribution Function 6. Spectral Selection Rules

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