Secondary Nanotubes and Fills

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Secondary Nanotubes and Fills in C-NT V3O7 - NR Al2O3 MoO3 RuO2 ZrO2 carbon TiO2 Ga2O3 BaTiO3 PbTiO3 in on Fe TiO2 SiO2 G. Patzke, F. Krumeich, R. Nesper, Angew. Chem. 2002, 114, 2554

Composite Nanotubes Self-assembly in a colloid containing PbS nanoparticles, a polymer (poly(ethylene oxide)), and a surfactant (sodiumdodecylsulfate) tube walls comprise well-developed layers of PbS nanoparticles that are embedded in the organic matrix structure

Silica Nanotubes Pt Hippe, Wark, Lork, Schulz-Ekloff, Microp. Mesop. Mater. 31 (1999) 235 [Pt(NH3)4(HCO3)2 single crystals coated by SiO2 and TiO2 through Si(OEt)4 or Ti(OEt)4 Pt

Template-assisted Synthesis of Nanotubes Rod-like Template Nanotube Coating of anisotopically structured template with a second material Removal of template Caruso, Antonietti, Chem. Mater. 13 (2001) 3272

Template-assisted Synthesis of Nanotubes Next steps Template-assisted Synthesis of Nanotubes Silica nanotubes Wires of V3O7·H2O Intermediate product TEM V map Silica Nanotubes Si map J. Zygmunt, F. Krumeich, R. Nesper, Adv. Mater. 2003, 15, 1538

Topotactic redox reactions of copper(II) and iron(III) salts within VOx Nanotubes Novel Cu- and Fe-containing nanotubes of composition VO1.53-2.1(C12H28N)0.21Cu0.08(H2O)0.56Cl0.01 and VO2.08-2.68 (C12H28N)0.13Fe0.19(H2O)0.33Cl0.01 have been obtained by exchange of the protonated template in dodecylamine-VOx nanotubes with Cu(II) and Fe(III) salts. The exchanged materials have quite different characteristics in respect to the parent nanotubes, namely a wider inner diameter and thinner walls, owing to reduced interlayer spacings in their multiwalled structure.

Multiple Coatings Asbestos - C coated SiO2 tubes – TiO2 coated SiO2 tubes – Fe2O3 coated Triple layer rods 1. VOx fibers 2. SiO2 tubes 3. carbon coating Iron oxide rods- C coated